Towards maximizing the In2O3/m-ZrO2 interfaces for CO2-to-methanol hydrogenation.

Through chelating-assisted impregnation with diethylenetriamine-pentaacetic acid (DTPA), we developed an efficient and durable CO2 hydrogenation catalyst, In15/m-ZrO2-DTPA, featuring improved In2O3 reducibility and interfacial Zr-O-In structures. Benefiting from its distinct CO2 activation and hydrogenation ability, In15/m-ZrO2-DTPA exhibited remarkable CO2-to-methanol catalytic activity, achieving up to 91% selectivity at 260 °C and 5.0 MPa, with consistent conversion maintained over 400 hours.

Oxygen vacancy promoted carbon dioxide activation over Cu/ZrO2 for CO2-to-methanol conversion.

Oxygen vacancy-enriched ultrafine tetragonal ZrO2 was introduced as a support for copper nanoparticles to enhance the energy efficiency of CO2 hydrogenation for methanol synthesis. In situ spectroscopic techniques confirmed the oxygen vacancy-mediated single-electron CO2 activation. The resulting highly efficient catalyst yielded a methanol production rate of 550 mg gcat-1 h-1 at 200 °C, outperforming state-of-the-art Cu-based catalysts.