RESUMO
The block ratio of SBS is an important factor influencing the swelling effect of modified asphalt, but the effect of the block ratio in the swelling process cannot be accurately studied by macro testing. In order to solve this problem and screen out the optimal SBS block ratio, molecular models of asphalt and SBS with different block ratios were established by molecular simulation technology at the microscopic level, and an asphalt-SBS interaction layer system was established on this basis. The diffusion and adhesion effects of SBS with different block ratios were evaluated by calculating the immersion depth, diffusion coefficient, and adhesion work of SBS in asphalt. The results show that SBS has a physical cross-linking reaction with asphalt during swelling, and SBS with a higher butadiene block ratio exhibits a deeper immersion depth; thus, SBS with a 3/7 block ratio has the best performance in the modification process, which is superior to SBS with other block ratios, in terms of both the diffusion and adhesion effect. The performance of asphalt modified by SBS with different block ratios was tested using penetration, softening point, and ductility, and the results were consistent with the simulation results, which proved the reliability of the microscopic conclusions from a macro perspective.
