Emission of volatile organic compounds (VOCs) from application of commercial pesticides in China.

Applying pesticides can result in emissions of volatile organic compounds (VOCs), but little is known about VOC emission characteristics and the quantities in particular regions. We investigated the use of pesticides in China based on a large-scale survey of 330 counties in 31 provinces and evaluated the national pesticide VOC emission potentials based on thermogravimetric analysis of 1930 commercial pesticides. The results showed that herbicides were the most extensively used pesticide category in China, accounting for 43.47%; emulsifiable concentrate (EC), suspension concentrate, and wettable powder were the dominant pesticide formulations, with proportions of 26.75%, 17.68%, and 17.31%, respectively. The VOC emission potential coefficient (EP) of the liquid formulations was higher than the solid formulations, and the maximum mean EP was 45.59% for EC and the minimum was 0.76% for WP. Among 437 high-VOC pesticide products used in China, EC accounted for 83.52%, and 16.93% of those contained abamectin. The total VOC emissions derived from commercial pesticides in China were 280 kt (kilotons) in 2018, and 65.35% of the contribution was derived from EC. Shandong, Hunan, and Henan were the three provinces with the highest pesticide VOC emissions (>21 kt/y). The emission rate of VOCs from pesticides was 24.80 t/d in China, which was higher than in San Joaquin Valley, California. These findings suggest that some comprehensive measures (e.g., perfecting pesticide management policy, strict supervision for pesticide production and use, and strengthening pesticide reduction publicity) should be taken to reduce VOC emissions from pesticide applications.

Modified granulation of red mud by weak gelling and its application to stabilization of Pb.

This study presents a novel modification of red mud (RM) with cementitious materials by rotary drum granulation under partial hydration. Admixtures and surfactants were applied to improve the microspore structure of red mud-based granules in order to stabilize Pb steadily. Through XRD and SEM-EDS analyses, it was demonstrated that calcite, the main alkali in RM, was partially concreted and coated. Compared to pH 12.47 for RM, the lowest pH of the granules was 10.66 implying that the release of OH(-) from hydrolysis and decomposition was decreased. Based on stabilization of Pb, influence on soil properties and forming qualities, composition of the optimum granule PSP was determined as 5% cement, 5% gypsum, 1% rice straw, and 0.1% emulsifier OP-10. Within a 90 d remediation, immobilization of ionic Pb in a 500 mg kg(-1) Pb-contaminated artificial soil was 9.85 mg kg(-1) at day 30 with 5% PSP2 as substitute. Furthermore, the reverse increase diminished as the final concentration was 11.13 mg kg(-1) while it was 14.25 mg kg(-1) by RM. The increase of residual Pb was 122.61%, which was better than the 83.92% of RM. Particularly, the highest pH in mine soil was 11.09 at day 1 with RM, but the decrease of ionic Pb was 46.26%. Meanwhile, a significant deviation from the control soil zeta-potential lasted longer and the recovery was more difficult, as compared to the granules. Therefore, a granulated modification of RM is shown to be very important when aiming at steady release of OH(-) to improve the later stabilization of Pb.