1.
Molecules
; 23(8)2018 Aug 01.
Artigo
em Inglês
| MEDLINE
| ID: mdl-30071657
RESUMO
An efficient direct C(sp3)â»H oxidation of diarylmethanes has been demonstrated by this study. This method employs environment-friendly O2 as an oxidant and is promoted by commercially available MN(SiMe3)2 [M = K, Na or Li], which provides a facile method for the synthesis of various diaryl ketones in excellent yields. This protocol is metal-free, mild and compatible with a number of functional groups on substrates.