1.
Acta Crystallogr Sect E Struct Rep Online
; 64(Pt 2): m276-7, 2008 Jan 04.
Artigo
em Inglês
| MEDLINE
| ID: mdl-21201259
RESUMO
In the title compound, [Zn(C(14)H(8)N(2)O(6))(H(2)O)(4)](n), the 2,2'-dihydr-oxy-5,5'-diazenediyldibenzoate ligand acts as a carboxyl-ate bridge, leading to the formation of a polymeric chain running along the [10] direction. The Zn(II) atom is hexa-coordinated in a distorted octa-hedral geometry by six O atoms [Zn-O = 2.055â (4)-2.132â (3)â Å] from two carboxylate ligands and four water mol-ecules. The crystal packing is stabilized by inter-molecular O-Hâ¯O, O-Hâ¯N and C-Hâ¯O hydrogen bonds, and two π-π inter-actions. The centroid-centroid distances are 3.803â (16) and 3.804â (17)â Å.