NiO/g-C3N4 composite for enhanced photocatalytic properties in the wastewater treatment.

The massive discharge of colored wastewater has seriously harmed the environment and people's health. Photocatalysis technology is an effective method to purify colored wastewater and has been widely concerned in colored wastewater treatment. In this study, based on the obtained nickel oxide (NiO) nanospheres by solvothermal method and graphite phase carbon nitride (g-C3N4) nanosheets by thermal polymerization method, the p-n heterojunction composed of NiO nanospheres and g-C3N4 nanosheets was successfully constructed by heat treatment for the photocatalytic degradation of methyl orange (MO). The morphology, crystallinity, surface features, and optical properties of the NiO/g-C3N4 composites were investigated by various characterization methods such as scanning electron microscope (SEM), transmission electron microscope (TEM), X-ray diffractometer (XRD), Fourier transform infrared spectrometer (FT-IR), X-ray photoelectron spectroscopy (XPS), UV-vis spectrophotometer, and fluorescence spectrometer (PL), which provided the evidence for the formation of the heterojunction between NiO and g-C3N4. Compared with the g-C3N4 nanosheets and NiO nanospheres, the NiO/g-C3N4 composites showed the improved photocatalytic activity for the degradation of MO under visible light irradiation. And the NiO/g-C3N4 composite with the mole ratio of NiO and g-C3N4 of 2:8 displayed the best photocatalytic activity of MO, and more than 90% of MO can be degraded under the illumination of 100 min. The high photocatalytic properties over the NiO/g-C3N4 composite may be due to high specific surface area, the perfect band matching, and the formation of the p-n heterojunction, which helps to promote interfacial charge transfer and hinder the recombination of photo-generated electrons and holes. Moreover, the NiO/g-C3N4 composite exhibits the universality and cyclic stability, which is expected to have broad application prospects in the treatment of colored wastewater.

Shear Behavior of Recycled Fine Aggregate Reinforced by Nano-MgO Modified Cement.

In order to study the mechanical modification effect of nano-MgO on cement-reinforced recycled fine aggregate (CRA), direct shear tests and triaxial shear tests were carried out. In the test of recycled fine aggregate reinforced by nano-MgO modified cement (MCRA), the cement content was fixed at 2%, and the nano-MgO content varied between 0%, 0.5%, 1.0%, 1.5% and 2.0%. The test results showed that adding nano-MgO can greatly increase both the direct shear strength and triaxial shear strength of MCRA. This increase in direct shear strength was mainly attributed to the increase in cohesion. However, this increase in triaxial shear strength was attributed to the simultaneous increase in the cohesion and friction angle.

Mechanical Characteristics of Lime-Treated Subgrade Soil Improved by Polypropylene Fiber and Class F Fly Ash.

To improve the limitations of lime-treated subgrade soil (LS), a series of unconsolidated and undrained triaxial tests were conducted to investigate the improvement effect of fiber modified lime-treated soil (PLS) and fly ash modified lime-treated soil (FLS). The test results showed that (1) The deviatoric stress-strain curves of LS, PLS, and FLS were basically of the softening type. (2) The addition of fiber and fly ash improved the ductility and stiffness of LS. The ductility of PLS increased by 134% compared with LS, while the mechanical strength of FLS increased by 53%. (3) The microscopic tests showed that a denser skeleton structure was generated inside LS with the addition of fiber and fly ash. (4) The deviatoric stress-strain curves of LS, PLS, and FLS under different confining pressures were better characterized with the CES curve model. The above results indicate that fiber and fly ash can effectively improve the mechanical characteristics of lime-treated subgrade soil.

Triaxial Mechanical Properties and Mechanism of Waterborne Polyurethane-Reinforced Road Demolition Waste as Road Bases.

The recycling and reuse of construction waste have not only effectively protected natural resources but also promoted the sustainable development of the environment. Therefore, in this article, waterborne polyurethane (WPU) as a promising new polymer reinforcement material was proposed to reinforce the road demolition waste (RDW), and the mechanical performance of WPU-reinforced RDW (named PURD) was investigated using triaxial unconsolidated and undrained shear (UU) and Scanning Electron Microscope (SEM) tests. The results showed that under the same curing time and confining pressure, the shear strength of PURD increased with the increase in WPU content. When the WPU content was 6%, the WPU presented the best reinforcement effect on RA. The failure strain of PURD increased with the increase in confining pressure, but increased first and then reduced with the increase in WPU content. The specimens with 5% WPU content showed the best ductility. At the curing time of 7 and 28 days, the internal friction angle and cohesion of PURD increased with the increase in WPU content, and they reached a maximum when the WPU content was 6%. The internal friction angle barely budged, but the cohesion increased obviously. The enhancement effect of WPU was attributed to the spatial reticular membrane structure produced by wrapping and bonding particles with the WPU film. Microscopic analysis showed that with the increase in WPU content, the internal pore and crack size of PURD gradually decreased. As the WPU content increased, the WPU film became increasingly thicker, which increased the adhesion between WPU and RA particles and made the structure of PURD become increasingly denser.

Adsorption Behavior of Magnetic Carbon-Supported Metal Nickel for the Efficient Dye Removal from Water.

Magnetic carbon-supported metal nickel has been successfully synthesized by solvothermal method and heat treatment for highly effective adsorption of various reactive dyes. Structure characterization and composition analysis demonstrated that the metal nickel nanoparticles with the size of 1-2 nm were embedded into the pore of carbon spheres. It is helpful to prevent the agglomeration and falling off of metal nickel nanoparticles on the surface of carbon spheres. The adsorption performance of the carbon-supported metal nickel nanospheres for reactive brilliant yellow R-4GLN was studied by changing the pH value and initial concentration of the solution, adsorption time, adsorption temperature, and the amount of adsorbent. The carbon-supported metal nickel showed fast and efficient adsorption activity. After 5 min of adsorption, the removal efficiency of 10 mL 25 mg·mL-1 reactive brilliant yellow R-4GLN was close to 100%. The carbon-supported metal nickel composite was reused 20 times, and the removal efficiency of dye remained above 98%. It also showed good adsorption performance on various reactive dyes with wide universality, which has a certain adsorption effect on most dyes with a high utilization value in wastewater treatment.