Facile synthesis of Fe-modified lignin-based biochar for ultra-fast adsorption of methylene blue: Selective adsorption and mechanism studies.

A novel Fe-modified lignin-based biochar (Fe-LB) was fabricated via a facile one-step carbonization method for methylene blue (MB) removal from wastewater. Fe-LB exhibited a high specific surface area (885.97 m2/g) and micropore volume (0.3203 m3/g), and demonstrated high affinity for MB with the maximum adsorption capacity of 2.7-fold by Fe-LB than LB. It was found that quick adsorption could be achieved in 15 min with the MB removal efficiency of 100% and adsorption capacity reached 200 mg/g. Selective adsorption studies indicated that Fe-LB preferentially adsorbed MB in high salt and multiple dye systems (binary, ternary, and quaternary) over a wide pH range from 2 to 12. The removal efficiency of CR was greatly improved due to the synergistic effect between MB and CR in the binary system. This work demonstrated that Fe-LB can effectively remove dye contaminants and possessed great potential in the treatment of MB polluted dye wastewater.

The catalytic activity of Ag2S-montmorillonites as peroxidase mimetic toward colorimetric detection of H2O2.

Nanocomposites based on silver sulfide (Ag2S) and Ca-montmorillonite (Ca(2+)-MMT) were synthesized by a simple hydrothermal method. The nanocomposites were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and Fourier transform infrared spectra (FTIR). The as-prepared Ag2S-MMT nanocomposites were firstly demonstrated to possess intrinsic peroxidase-like activity and could rapidly catalytically oxidize the substrate 3,3',5,5'-tetramethylbenzidine (TMB) in the presence of H2O2 to produce a blue product which can be seen by the naked eye in only one minute. The experimental results revealed that the Ag2S-MMT nanocomposites exhibit higher thermal durance. Based on the TMB-H2O2 catalyzed color reaction, the Ag2S-MMT nanocomposites were exploited as a new type of biosensor for detection and estimation of H2O2 through a simple, cheap and selective colorimetric method.