Dynamic assessment of dust hazard risk in the reconstruction of old industrial buildings: coupling effects of dust distribution and personnel trajectories.

Since the old industrial buildings bear many functions of industrial production and storage in the service stage, the dust generated by the regeneration construction is often accompanied by industrial pollutants, causing irreversible damage to the personal safety of construction workers. However, little consideration has been given to the uncertainty of dust emissions and the dynamics of construction personnel movement. Therefore, reducing the risk of dust hazards during the regeneration of old industrial buildings is imperative. This study draws on the trace intersecting theory to analyse the cause of the hazard risk associated with reconstruction dust and explore the impact of the spatiotemporal distribution characteristics of reconstruction dust and its coupling effect with construction on-site personnel activity trajectories and uses the risk matrix method to assess the dust hazard risk in the reconstruction of old industrial buildings. Finally, the renovation and reinforcement process of the first floor of a printing building in Xi'an was considered as an example for verification. The results indicate that the risk assessment model results were highly consistent with the actual situation and risk value for the entire area was 6.05, indicating a risk level of IV. Immediate measures should be implemented to reduce dust concentrations or the frequency of construction personnel activity, thereby minimising potential harm.

Efficient polymer-mediated delivery system for thiocyclam: Nanometerization remarkably improves the bioactivity toward green peach aphids.

The unscientific application of synthetic pesticides has brought various negative effects on the environment, hindering the sustainable development of agriculture. Nanoparticles can be applied as carriers to improve pesticide delivery, showing great potential in the development of pesticide formulation in recent years. Herein, a star polymer (SPc) was constructed as an efficient pesticide nanocarrier/adjuvant that could spontaneously assemble with thiocyclam or monosultap into a complex, through hydrophobic association and hydrogen bonding, respectively, with the pesticide-loading contents of 42.54% and 19.3%. This complexation reduced the particle sizes of thiocyclam from 543.54 to 52.74 nm for pure thiocyclam, and 3 814.16 to 1 185.89 nm for commercial preparation (cp) of thiocyclam. Interestingly, the introduction of SPc decreased the contact angles of both pure and cp thiocyclam on plant leaves, and increased the plant uptake of cp thiocyclam to 2.4-1.9 times of that without SPc. Meanwhile, the SPc could promote the bioactivity of pure/cp thiocyclam against green peach aphids through leaf dipping method and root application. For leaf dipping method, the 50% lethal concentration decreased from 0.532 to 0.221 g/L after the complexation of pure thiocyclam with SPc, and that decreased from 0.390 to 0.251 g/L for cp thiocyclam. SPc seems a promising adjuvant for nanometerization of both pure and cp insecticides, which is beneficial for improving the delivery efficiency and utilization rate of pesticides.

A facile design of thio-perylenediimides with controllable fluorescent, photodynamic and photothermal effects towards cancer theranostics.

A series of thionated perylenediimides with modulating phototheranostic modalities have been synthesized by a one-pot method for multiple anti-cancer applications. Compared to the initial and 4-tert-butyl phenol-substituted fluorescent perylenediimide, the obtained monothionated perylenediimide became photodynamic. With the increase of thionation degree, tetrathionated perylenediimide changed into an optimal photothermal agent.