On the Use of Polymer Inclusion Membranes for the Selective Separation of Pb(II), Cd(II), and Zn(II) from Seawater.

The synthesis and optimization of polymeric inclusion membranes (PIMs) for the transport of Cd(II) and Pb(II) and their separation from Zn(II) in aqueous saline media are presented. The effects of NaCl concentrations, pH, matrix nature, and metal ion concentrations in the feed phase are additionally analyzed. Experimental design strategies were used for the optimization of PIM composition and evaluating competitive transport. Synthetic seawater with 35% salinity, commercial seawater collected from the Gulf of California (Panakos®), and seawater collected from the beach of Tecolutla, Veracruz, Mexico, were employed. The results show an excellent separation behavior in a three-compartment setup using two different PIMs (Aliquat 336 and D2EHPA as carriers, respectively), with the feed phase placed in the central compartment and two different stripping phases placed on both sides: one solution with 0.1 mol/dm3 HCl + 0.1 mol/dm3 NaCl and the other with 0.1 mol/dm3 HNO3. The selective separation of Pb(II), Cd(II), and Zn(II) from seawater shows separation factors whose values depend on the composition of the seawater media (metal ion concentrations and matrix composition). The PIM system allows S(Cd) and S(Pb)~1000 and 10 < S(Zn) < 1000, depending on the nature of the sample. However, values as high as 10,000 were observed in some experiments, allowing an adequate separation of the metal ions. Analyses of the separation factors in the different compartments in terms of the pertraction mechanism of the metal ions, PIMs stabilities, and preconcentration characteristics of the system are performed as well. A satisfactory preconcentration of the metal ions was observed after each recycling cycle.

Appraisal on the role of passive sampling for more integrative frameworks on the environmental risk assessment of contaminants.

Over time multiple lines of research have been integrated as important components of evidence for assessing the ecological quality status of water bodies within the framework of Environmental Risk Assessment (ERA) approaches. One of the most used integrative approaches is the triad which combines, based on the weight-of-evidence, three lines of research, the chemical (to identify what is causing the effect), the ecological (to identify the effects at the ecosystem level) and the ecotoxicological (to ascertain the causes of ecological damage), with the agreement between the different lines of risk evidence increasing the confidence in the management decisions. Although the triad approach has proven greatly strategic in ERA processes, new assessment (and monitoring) integrative and effective tools are most welcome. In this regard, the present study is an appraisal on the boost that passive sampling, by allowing to increase information reliability, can give within each of the triad lines of evidence, for more integrative ERA frameworks. In parallel to this appraisal, examples of works that used passive samplers within the triad are presented providing support for the use of these devices in a complementary form to generate holistic information for ERA and ease the process of decision-making.