A novel intensified approach for treating produced water from oil extraction using a multi-tube type falling-film distillation column equipped with a biphasic thermosiphon: a promising feasibility study.

This study has the novel aim of experimentally examining the efficiency of a pilot-scale treatment plant, composed of a multi-tube type falling-film distillation column equipped with a biphasic thermosiphon, for treating a real sample of high-salinity produced water (electrical conductivity of 20,700 µS cm-1). It investigates the influence of operational parameters, including feed temperature and steam chamber temperature of the biphasic thermosiphon, on distillate flow rate and reduction of conductivity. All experimental conditions tested achieved a reduction greater than 98% in terms of electrical conductivity. The production of treated water increased with increasing feed temperature; the flow rate increased from 20.8 L h-1 to 28.2 L h-1 as the feed temperature was increased from 80 °C to 90 °C, when the steam chamber temperature was fixed at 119 °C. Within the temperature range of the steam chamber, the specific energy consumption during the treatment process, with respect to the biphasic thermosiphon, remained practically unchanged between 0.58 kWh L-1 and 0.60 kWh L-1, when the feed temperature was 90 °C. The results proved the potential of the falling-film distillation technology assisted by heat pipes to be a promising proposal for removing salinity from produced water from oil extraction operations.

A Perspective Review on the Application of Polyacrylonitrile-Based Supports for Laccase Immobilization.

The use of laccases applied in bioremediation processes has been increasingly studied, given the urgent need to overcome the environmental problems caused by emerging contaminants. It is known that immobilized enzymes have better operational stability under reaction conditions, allowing for greater applicability. However, given the lack of commercially available immobilized laccases, the search for immobilization materials and methods continues to gain effort. The use of polyacrylonitrile (PAN) to immobilize enzymes has been investigated since it is a low-cost material and can be modified and functionalized to well interact with the enzyme. This polymer can be used with different morphologies such as fibers, beads, and core-shell, presenting as an easily applicable alternative. This review presents the missing link between polymer and enzyme through an overview of PAN's current use as support for laccase immobilization and polymer functionalization methods, considering the importance of immobilized laccases in several industrial sectors.

Chitosan as a matrix of nanocomposites: A review on nanostructures, processes, properties, and applications.

Chitosan is a biopolymer that is natural, biodegradable, and relatively low price. Chitosan has been attracting interest as a matrix of nanocomposites due to new properties for various applications. This study presents a comprehensive overview of common and recent advances using chitosan as a nanocomposite matrix. The focus is to present alternative processes to produce embedded or coated nanoparticles, and the shaping techniques that have been employed (3D printing, electrospinning), as well as the nanocomposites emerging applications in medicine, tissue engineering, wastewater treatment, corrosion inhibition, among others. There are several reviews about single chitosan material and derivatives for diverse applications. However, there is not a study that focuses on chitosan as a nanocomposite matrix, explaining the possibility of nanomaterial additions, the interaction of the attached species, and the applications possibility following the techniques to combine chitosan with nanostructures. Finally, future directions are presented for expanding the applications of chitosan nanocomposites.

Low temperature in situ formation of cobalt in silicon nitride toward functional nitride nanocomposites.

This work highlights the first demonstration of a low-temperature in situ formation of Co nanocrystallites embedded within an amorphous silicon nitride matrix through careful control of the chemistry behind material design using perhydropolysilazane (PHPS) as a Si3N4 precursor further coordinated with CoCl2 and ammonia as a pyrolysis atmosphere. The Co nucleation was allowed to proceed at temperatures as low as 400 °C via thermal decomposition of Co2N pre-formed in situ by the reaction of CoCl2 with the Si centers of PHPS at the early stage of pyrolysis (220-350 °C).

In-Situ Synthesis and Characterization of Nanocomposites in the Si-Ti-N and Si-Ti-C Systems.

The pyrolysis (1000 °C) of a liquid poly(vinylmethyl-co-methyl)silazane modified by tetrakis(dimethylamido)titanium in flowing ammonia, nitrogen and argon followed by the annealing (1000-1800 °C) of as-pyrolyzed ceramic powders have been investigated in detail. We first provide a comprehensive mechanistic study of the polymer-to-ceramic conversion based on TG experiments coupled with in-situ mass spectrometry and ex-situ solid-state NMR and FTIR spectroscopies of both the chemically modified polymer and the pyrolysis intermediates. The pyrolysis leads to X-ray amorphous materials with chemical bonding and ceramic yields controlled by the nature of the atmosphere. Then, the structural evolution of the amorphous network of ammonia-, nitrogen- and argon-treated ceramics has been studied above 1000 °C under nitrogen and argon by X-ray diffraction and electron microscopy. HRTEM images coupled with XRD confirm the formation of nanocomposites after annealing at 1400 °C. Their unique nanostructural feature appears to be the result of both the molecular origin of the materials and the nature of the atmosphere used during pyrolysis. Samples are composed of an amorphous Si-based ceramic matrix in which TiNxCy nanocrystals (x + y = 1) are homogeneously formed "in situ" in the matrix during the process and evolve toward fully crystallized compounds as TiN/Si3N4, TiNxCy (x + y = 1)/SiC and TiC/SiC nanocomposites after annealing to 1800 °C as a function of the atmosphere.

Dye synthetic solution treatment by direct contact membrane distillation using commercial membranes.

The reuse of treated dyeing wastewater has become a viable option to minimizing water scarcity problems and environmental impacts in the textile industry. The potentiality of commercial flat sheet membranes of polytetrafluoroethylene (PTFE) and polypropylene (PP) in direct contact membrane distillation (DCMD) for dye synthetic solution treatment has been explored in this work. DCMD is interesting for the textile industry since a recovery of heat by hot dyeing wastewater for thermal energy is possible. Moreover, DCMD enables water and dye reclamation with possible reuse in the textile process. The commercial availability of membranes may expedite the DCMD commercialization in the textile industry. Experiments were conducted in a laboratory-scale circulating unit with synthetic solutions containing reactive or disperse dye. High mean permeate flux up to 18.8 kg m-2 h-1 with complete colour rejection was obtained. The dyes tested in this study are not able to completely wet the membranes and the increase of the permeate flux when compared to distilled water is attributed to electrostatic interactions between the dyes and the membranes. Moreover, a partial wetting reduced vapour diffusion path and the permeate flux was increased. PP membrane showed higher performance due to higher porosity when compared to the PTFE membrane. In addition, an influence of dye class on permeability was observed. The results were promising when compared to other studies, which used commercial or lab-scale membranes.

Influence of dye class on the comparison of direct contact and vacuum membrane distillation applied to remediation of dyeing wastewater.

This work investigated the influence of dye class on permeate flux and color rejection by comparing direct contact membrane distillation (DCMD) and vacuum membrane distillation (VMD) applied to remediation of dyeing wastewater. The same operating system at the feed side was used and the driving force of each configuration was determined. Reactive and disperse dye solutions were considered, and a commercial membrane was employed. Final color rejection > 90.79% was obtained, and water was recovered at the permeate side (final normalized permeate flux up to 38.92 kg m-2day-1kPa-1). VMD showed higher normalized permeate flux when compared to DCMD. However, the performance according to dye class depended on MD configuration. Reactive dye resulted in higher permeate flux than the disperse dye solution in DCMD. Contrarily, disperse dye solution showed higher permeate flux in VMD. The formation of a concentration boundary layer at the permeate membrane interface was suggested with disperse dye solution in DCMD, decreasing thus the driving force. In VMD, the boundary effect is negligible with disperse dye solution. This result implies that the VMD performance in the textile industry may depend more on driving force rather than the dye class of the dyeing bath.

Dissolution of adhesive resins present in plastic waste to recover polyolefin by sink-float separation processes.

This study investigated the dissolution of adhesive resins present in polyolefin films that cause plastic materials to adhere to each other. The process of dissolution was made by the use of ethyl acetate and followed by separation through the sink-float process. The objective was to separate and characterize polyolefin films from plastic solid waste derived from recycled post-consumer paper. Through these procedures, 6% polyethylene of high-density (HDPE), 14% polyethylene of low-density (LDPE) and 39% polypropylene (PP) were separated and recovered from plastic waste. Fourier transform infrared spectroscopy (FTIR), thermal gravimetric analyzes (TGA), differential scanning calorimetry (DSC), and dynamic mechanical analysis (DMA) were conducted to determine the chemical, thermal and mechanical properties of the recovered polymers and to establish a comparison with standard commercial polymers. It demonstrated that recovered material kept their chemical, thermal, and mechanical properties. This process indicates possible economic viability considering the demand, the market value of the PP, and the required investment to be implemented in the recycling process that could be amortized in a short period of time. Moreover, the organic solvent used in the dissolution process can be easily recovered by distillation.

Influence of different textile fibers on characterization of dyeing wastewater and final effluent.

Textile industry needs to recover and reuse its wastewater as to fulfil the demand of increasingly strict regulations. The characterization of dyeing wastewater samples according to textile fiber and final textile effluent enables the application of different treatment methods. This study aims to characterize dyeing wastewater in black color of polyamide, polyester, and viscose fibers and final textile effluent. Samples were collected and characterized completely for major pollution indicator parameters. Dyeing wastewater of polyester showed higher values for some parameters, e.g., 4994.44% (49,944,400 mg L-1 and 917 NTU) of turbidity and 4100.00% of phenol when compared to dyeing wastewater of other fibers. Other parameters such as pH, alkalinity, color, phosphorus, nitrogen, sulfides, chlorides, oil and grease, dissolved solids, and chemical and biochemical oxygen demand were also assessed. In addition to individual characterization, this study also presents a correlation of the contribution of each parameter to the final textile effluent. Although dyeing wastewater of polyamide contributes the most in terms of quantity for the final effluent, this study revealed that dyeing wastewater of polyester influenced the most on the final composition of the textile wastewater when evaluating color, turbidity, total iron, biochemical oxygen demand, chemical oxygen demand, phenol, mercury, oil and grease, and total phosphorus. The present study is focused on bringing new insights to provide future research with other strategies to improve the treatment of dyeing wastewater. In addition, some suggestions are also given for wastewater treatments according to type of textile fiber.

Direct contact membrane distillation for textile wastewater treatment: a state of the art review.

To meet surging water demands, water reuse is being sought as an alternative to traditional water resources. Direct contact membrane distillation (DCMD) has been increasingly studied in the past decade for its potential as an emerging cost effective wastewater treatment process and subsequent water reuse. This review presents a comprehensive overview of the current progress in the application of DCMD for textile wastewater treatment based on the available state of the art. There are already published review papers about the membrane distillation process, but the difference in the present work is that it focuses on the textile area, which consumes a lot of water and generates large amounts of wastewater, and still needs innovations in the sector. A review focused on the textile sector draws the attention of professionals to the problem and, consequently, to a solution. Current issues such as the influences of feed solution, membrane characteristics and membrane fouling and new insights are discussed. The main performance operating conditions and their effects on the separation process are given. Likewise, challenges associated with the influence of different dyes on the DCMD results are explained. This review also highlights the future research directions for DCMD to achieve successful implementation in the textile industry.

Adsorption of natural dyes on clay fixed on polymers

The main purpose of this work was to produce a pellet to minimize undesirable effects in fixed beds, such as colmatation, through clay fixation on the surface of polymeric particles. Preliminary experiments were carried out by heating the clay, namely Tonsil Terrana 580FF, in order to observe variations on its capacity to adsorb anthocyanins derived from red cabbage. Clays was fixed on five samples of high density polyethylene (HDPE) at 180°C -210°C for two hours. The morphological analyses of the resulting particles were accomplished through Scanning Electron Microscopy (SEM). The experiments demonstrated an increase on clay's adsorptive capacity of 15.65 percent at 120°C for 30 hours and 16.80 percent at 170°C for two hours. The SEM analysis showed that the clay particles adhered on the external surface of the pellets .These results show that it is possible to obtain polymeric pellets using HDPE coated with clay.