Geochemical evaluation, ecological and human health risk assessment of potentially toxic elements in urban soil, Southern India.

Roadside soil contamination is mostly caused by human-caused pollutant deposition. PTEs are among the many substances that are harmful for both humans and the environment. PTE concentrations in roadside soil in Chennai, southern India, have been determined in this study. To evaluate the seriousness of the threats, more environmental and geochemical indices have been applied. 83 soil samples have been obtained from the study regions and focusing on important roads. Elemental analysis has been analyzed with ED-XRF and sieve-filtered samples focused on PTEs such as arsenic, barium, cobalt, chromium, copper, iron, potassium, nickel, lead, thorium, titanium, zinc, and uranium. Significant metallic variations have been found in soil samples around roads by the investigation. The elements this study examined section ascending in the following sequence: Fe > Ti > Zn > Cr > Pb > Cu > Ni > Th > As > U > K. In the research area, the CD classification denotes high contamination, whereas the CF indices show mild to significant pollution. PLI indicates moderate to high pollution, whereas EF suggests excessive enrichment. Igeo demonstrates a range from uncontaminated to highly contaminated. PERI showed high levels in the northern study region, whereas GUFI shows several hot spots indicating moderate to severe pollution. The Hazard Index (HI) values for all metals were less than one, demonstrating the absence of non-carcinogenic risks for both adults and children. Multivariate data show natural and anthropogenic PTEs in roadside soil. In addition, a soil quality monitoring system is needed to mitigate continual contamination risks.

Adsorption behavior of fluoroquinolone(ciprofloxacin) using zinc oxide impregnated activated carbon prepared from jack fruit peel: Kinetics and isotherm studies.

Ciprofloxacin is a pharmaceutical component used for treating various tract infections. This is considered as an emerging contaminant due to the release of unreacted components getting disposed into the water bodies. This component is effectively treated using renewable biomass, which is converted into a useful renewable low-cost adsorbent material. Discarded Jack Fruit Peel (JFP) is used as an activated carbon incorporated with zinc oxide nanocomposite. The prepared activated carbon in this experiment was characterized by determining their functional groups, morphological characters, and nature of the adsorbent material by analyzing the Fourier Transform InfraRed (FTIR), Field Emission Scanning Electron Microscopy (FESEM), and X-ray Diffraction (XRD) characterization. Further, the prepared composite's correlation coefficients and equilibrium sorption of the adsorption process were calculated using Ultra Violet (UV)-Visible Spectroscopy and analyzed with isotherm models (Langmuir model, Freundlich model, and Temkin model) and kinetic models (Pseudo-first-order kinetics, Pseudo-second-order kinetics, Intraparticle diffusion model, and Elovich model). Among the different models, the Zinc oxide impregnated activated carbon show Freundlich Isotherm and Pseudo Second order equation having a maximum correlation with experimental studies indicating double-layer adsorption, which suggests that the process is chemisorption. The operational parameters, including the effect of pH, dosage of activated carbon, and contact time of adsorption was calculated to identify the optimal condition for maximum adsorption.

Hydrogeochemical processes controlling the groundwater salinity in the coastal aquifers of Southern Tamil Nadu, India.

The current study identifies groundwater quality issues and investigates the most important geochemical processes that control seawater intrusion using various ionic ratios, hydrochemical facies evolution, and geochemical modelling. Cl-/Br ratio is an important indicator to identify the origin of groundwater salinity in coastal aquifers. Nineteen percent of the groundwater samples with Cl-/Br- ratio similar to that of Standard Mean Ocean Water (SMOW) are affected by seawater intrusion in the study area. Particularly, nine groundwater samples have high chloride values and are similar to SMOW, and it may derived salinity from seawater sources from the Bay of Bengal due to the over-pumping of production wells in the Uvari zone. Five samples are similar to SMOW, which is due to the presence of salt pan activities. The bivariate plots such as Ca2+ + Mg2+ vs Cl-, EC vs Cl-, and Na+/Cl- ratio indicate that seawater intrusion is the primary source for groundwater salinisation. Evaporation is the dominant process controlling groundwater chemistry, rather than rock-water interaction and precipitation, according to mechanisms controlling groundwater chemistry. Direct ion exchange and converse ion exchange are the critical controlling factors for groundwater salinisation, according to the hydrochemical facies evolution diagram (HFED). The water quality index (WQI) shows that most groundwater belongs to the poor to the marginal category. The saturation indices show that the groundwater samples are saturated with minerals such as dolomite, calcite, aragonite and magnesite. Therefore, these minerals are susceptible to precipitation due to the effective leaching of calcareous minerals from the bedrocks. Compiled hydrogeochemical analysis and multivariate statistical analysis revealed that the Tiruchendur and Uvari zone was affected by the seawater intrusion and led to an increase in the salinity of the groundwater.

Microplastic contamination in edible sea salt from the largest salt-producing states of India.

The presence of microplastics in all ecological and environmental conditions has been identified as a global problem. This article aimed to study edible salt-associated microplastics from the major salt-producing states of India. The crystal and powder salt from Tamil Nadu and Gujarat (five samples of powder salt and three samples of crystal salt from each state) were collected and analyzed for their microplastic content. The total microplastic content in the salts ranged from 46 to 115 particles per 200 g in Gujarat salt and 23 to 101 particles per 200 g in Tamil Nadu salt. The microplastics are dominated by red and blue color fibrous-shaped materials. The most common microplastics identified in the edible salts were polyethylene, polyester, and polyvinyl chloride derived from marine and salt-processing units.

Effect of a tropical cyclone on the distribution of heavy metals in the marine sediments off Kameswaram, Southeast coast of India.

Cyclones and heavy rainfalls are the main reasons for incessant environmental aggravation in the coastal regions and the distribution of pollutants from the contaminated terrestrial areas to the offshore regions. Twenty-five surface sediment samples were collected off Kameswaram, SE coast of India, and assessed for their geochemical and sedimentological characteristics post Cyclone Gaja. Sediment texture and various geochemical analyses were carried out to assess the metal distribution in the study area. Environmental impacts caused by heavy metal contamination in the marine sediments were assessed using different sediment pollution indices and it was found that metals such as Cu, Zn, Ni, and Co were moderately contaminated. Fe and Cr were uncontaminated to moderately contaminated, and Mn fall under the uncontaminated category. Multivariate statistical analyses revealed that the enrichment of organic-rich mud helps in entrapping the heavy metals, thus polluting the environment. Moreover, these metals were mainly derived from anthropogenic activities.

Hazardous heavy metals in the pristine lacustrine systems of Antarctica: Insights from PMF model and ERA techniques.

A comprehensive study was presented on the ecological risk, distribution, and quantitative source apportionment of heavy metals in the selected lacustrine systems of Schirmacher Hills using various environmental indices and methods. A total of 25 sediment samples from 16 lakes were collected around scientific research stations and analyzed for metals. Geochemical approaches and ecological risk assessment methods were implemented to characterize and evaluate the contamination level and associated risk in the lacustrine systems. Moreover, statistical techniques and a positive matrix factorization (PMF) model were indorsed to understand metals' association and apportion their probable sources. Results revealed that most of the heavy metals (mean concentration in ppm) such as Al (77,504.09), Cd (1.36), Co (29.52), Cr (102.75), Cu (65.19), Fe (57,632.87), Mn (679.05), Ni (49.13), Pb (10.11), and Zn (253.78) are originated from natural weathering of source rocks (78.53%) followed by human-induced actions/ station activities coupled with atmospheric deposition (21.47%). Environmental risk assessment (ERA) techniques suggest that the lakes in the study area are under minimal to moderate enrichment/ contamination category and experienced minimal to adverse biological effects where metal toxicity risk is minimal.

Bioaccumulation of heavy metals in water, sediment, and tissues of major fisheries from Adyar estuary, southeast coast of India: An ecotoxicological impact of a metropolitan city.

Heavy metal content in water, sediment, and tissues of six commonly used edible fishes from Adyar estuary, southeast coast of India, was assessed for metal bioaccumulation. The enrichment of metals in estuarine sediment is due to the discharge of contaminated water from the Chennai Metropolis. The enrichment factor indicated that metals such as Cr (EF=30.9) and Cu (EF=31.9) are highly enriched and fall under the very severe category. Bioaccumulation factor (BAF) revealed that the concentration of heavy metals viz. Ni, Cr, Pb, Cu, Co, Zn, Fe, and Mn in different tissues of fishes was several times higher than their concentrations in water. Moreover, high concentration of heavy metals, especially Cu and Cr was noticed in the muscle and liver tissues of the fishes which are higher than the WHO standards. Among the studied fishes, Arius parkii and Gerres oyena showed higher levels of bioaccumulation in terms of toxic metals.

Trace metal contamination in the marine sediments off Point Calimere, Southeast coast of India.

Twenty-five offshore sediment samples were collected after the Gaja cyclone to evaluate the sediment quality in terms of its metal concentration. The samples were examined for organic matter, textural characteristics, calcium carbonate, and trace metals (Fe, Mn, Ni, Co, Cu, and Cr). The geo-accumulation index, enrichment factor, contamination factor, and pollution load index revealed that the study area was highly contaminated with Cu, Zn, and Co. Reasonable to extensive contamination was observed for Fe, Cr, and Ni, whereas Mn was under the uncontaminated category. Statistical analyses revealed that the contamination of Cu, Zn, and Ni are mainly originated from human activities such as boat navigation, fuel combustion, and tourism. Cyclones such as Gaja cause ecological disturbances of the terrestrial and transitional environments and also increase the level of offshore contamination by flooding the contaminated coastal landforms and transporting the contaminants to the sea.

Trace element concentrations and their potential ecological risk in the reef sediments of coral islands, Vembar group of islands, Gulf of Mannar, India.

The present work was undertaken to assess the impact of trace element concentration and the status of potential ecological risk in the reef sediments of the Vembar group of islands, Gulf of Mannar Marine National Park, India. Totally, 114 reef sediments (surface) were collected from the Vembar group of islands (Nallathanni Island - 36 samples; Upputhanni Island - 48 samples; Puluvinichalli Island-30 samples). The reef sediments are enriched with sand-sized calcareous particles. The calcium carbonate percentage (CaCO3) was primarily controlled by the distribution of coral colonies and available lithogenic grains. The pollution load index (PLI) reveals that the majority of the sediments fall under the unpolluted category. Moreover, the potential ecological risk (PERI) and sediment pollution index (SPI) reveals that the Vembar group of islands fall under the low ecological risk category.

Bioavailable trace metals and their ecological risks in the tourist beaches of the Southeast coast of India.

The concentration of Acid Leachable Trace Metals (ALTMs) was assessed in urbanized tourist beaches (96 samples from Marina beach, 34 samples from Edward Elliot's beach, and 28 samples from Silver beach) of southeast coast of India. The concentration of metals accumulated in the beach sediment was less than the Upper Continental Crust (UCC) background reference values. The mean enrichment of ALTMs in the studied urban tourist beaches showed the following descending order: Marina beach - Cr > Pb > Ni > Zn > Cu > Mn > Co; Edward Elliot's beach - Cr > Pb > Ni > Mn > Co > Zn > Cu; Silver beach - Cr > Pb > Ni > Co > Mn > Cu > Zn. The ALTMs such as Fe, Mn, Co, Cu, and Zn were probably derived from natural weathering and mild anthropogenic influences whereas other metals were derived from anthropogenic induced factors.

Characterization and distribution of microplastics and plastic debris along Silver Beach, Southern India.

Microplastics are causing serious environmental threats worldwide. To evaluate the current state of microplastics pollution, 28 sediment samples were examined for microplastics and plastic debris contamination along Silver Beach, Southern India. Visual identification followed by FT-IR spectroscopy was used to estimate the overall distribution and characterization of plastic debris. The results reveal that white-colored (44%) and irregularly-shaped (82%) plastics are prevalent in the study area. Moreover, the dominant polymer in the study area is polyvinyl chloride (79%) followed by polyethylene (14%) and nylon (7%). Based on size fractions, mesoplastics are widely distributed in the beach sediments (65%), followed by microplastics (18%) and macroplastics (17%). The regional sources of plastic debris are tourism and fishing activities followed by storm water runoff through the Gadilam river and wave-induced deposition through high tides. Strict policy measures need to be implemented in recreational beaches like Silver beach to reduce plastic pollution.

Metal concentration and its ecological risk assessment in the beach sediments of Coromandel Coast, Southern India.

The present study investigates the concentration of acid leachable trace metals (ALTMs) and their ecological risk in the beach sediments of Coromandel Coast, Southern India. In total, thirty-six beach sediments (eighteen samples from low tide and eighteen samples from high tide) were collected from the study area. The results of the study of the ALTMs suggest that the sediments are enriched by natural processes with significant anthropogenic influences. The distribution of ALTMs in beach sediments is in the following descending order: Fe > Cr > Mn > Pb > Ni > Cu > Co > Zn. The statistical results indicate that the metal concentrations were chiefly originated from natural processes such as leaching, weathering, and fluvial action. In addition, the textural characteristics, organic matter, and calcium carbonate percentage play an important role in the distribution of metals in the beach sediments.

Hydrogeochemistry of the deglaciated lacustrine systems in Antarctica: Potential impact of marine aerosols and rock-water interactions.

The deglaciated lacustrine systems in Grovnes, Larsemann Hills, East Antarctica was assessed for its solute dynamics and hydrogeochemical interactions. These pristine high latitude lacustrine systems serve as a natural laboratory to understand the interaction between hydrosphere, lithosphere and atmosphere thus providing valuable insights on the functioning of major biogeochemical cycles. A total of 14 fresh water lakes were identified and the water samples were analysed for its physico-chemical characteristics. The abundance of anions and cations in the lake water samples were in the following order of Cl- > HCO3- > SO42- > NO3- and Na+ > Mg2+ > Ca2+ > K+ respectively. Moreover, the lakes exhibit slightly alkaline condition due to dissolution of alkaline earth metals and atmospheric fallout. Na+-Cl--HCO3- and Na+-Cl- are the commonly noticed water type in the study area and higher concentration of Na+-Cl- were due to the effect of sea spray through marine aerosols. Reverse ion exchange is noticed in most of the lakes due to saline influence. Three major mechanisms such as rock dominance, precipitation/snow and evaporation/sea spray controls the lake water geochemistry in the study area. Silicate weathering and evaporite dissolution also contribute ionic load to the lake water. Significant positive correlations (p < .01) among major ions reveal sources from bedrock weathering along with marine aerosols. Trace element chemistry shows that rock-water interaction is the primary source for dissolved metals in the lake water followed by long range atmospheric transport in the form of aeolian dust. Mineral groups such as evaporites, sulphates, carbonates, metal oxides and hydroxides are responsible for the dissolution of metal complexes in the lake water. Furthermore, lakes falling within a micro basin have shown higher Na+-Cl- content which is due to the catchment effect where snow enriched with sea spray melts during the austral summer feeding these lakes.

Trace element contamination in marine sediments along the southeast Indian shelf following Cyclone Gaja.

In this study, twenty seven surface sediments were collected off Pushpavanam, Nagapattinam coast, southeast coast of India for understanding the sedimentological and geochemical behaviour after the Cyclone Gaja. The sediment samples were analysed for texture, organic matter (OM), carbonates, and trace metals such as Cr, Cu, Zn, Ni, Co including Fe and Mn. The Geoaccumulation index, contamination factor, enrichment factor and pollution load index revealed that Cu, Zn, Ni and Co is highly contaminated in the study area. Fe and Cr are moderately to considerably contaminated, while Mn shows uncontaminated. The principal component analysis also confirms the concentration of Cu, Zn, Ni and Co were mainly derived from the anthropogenic sources and related activities. Since Cyclones like Gaja often causes frequent ecological disturbance to the coastal environments and it distributes pollutants such as trace elements from localized area of contamination to offshore.

Macrodebris and microplastic distribution in the beaches of Rameswaram Coral Island, Gulf of Mannar, Southeast coast of India: A first report.

This is the first study on the distribution and characteristics of plastic debris found in the sediments of Rameswaram Island, Gulf of Mannar, India. Studies on the distribution of plastics and microplastic content in highly populated coral islands and their impact on the coral ecosystem are very scarce. For this purpose, marine sediment samples were collected from 20 locations along the coastal areas of the study region. The distribution and characterization study was carried out by visual examination followed by FTIR spectroscopy. The results showed abundance of white-colored and irregular-shaped plastic debris in this study area. Polypropylene was identified as a dominant polymer variety, followed by polyethylene, polystyrene, nylon, and polyvinyl chloride. Tourist activities and fishing practices were found to be the possible sources of the microplastic debris. Additionally, the distribution of the plastics was found to be dominantly controlled by the aeolian process and the nature of the coast.

Elemental concentration based potential ecological risk (PER) status of the surface sediments, Pulicat lagoon, Southeast coast of India.

Eighty-three surface sediments were collected to investigate the element concentration based sediment pollution and potential ecological risk status of the Pulicat lagoon, southeast coast of India. The textural characteristics, Fe and Mn concentration in the surface sediments are chiefly controlled by the confluence of riverine inputs and vicinity of the marine environment. The varied distribution of CaCO3 concentration is due to the depth of the lagoon followed by the sand and silty sand characteristics of the substratum. The surface sediments are derived from riverine sources. Sediment Pollution Index (SPI), Potential Ecological Risk Index of the sediments suggests that they are falling under less polluted and low potential ecological risk category.

A baseline study on trace element based sediment pollution and potential ecological risk of reef sediments of Musal, Manoli and Manoli putti Islands, Gulf of Mannar, India.

The aim of the present study is to assess the baseline level of the trace element, sediment pollution and potential ecological risk of reef associated sediments of Musal, Manoli and Manoli putti Islands, Gulf of Mannar, India. The grain size distribution of the sediments is chiefly controlled by corals and broken shell debris. The distribution of lithoclastic fractions and element concentration are most probably derived from longshore sediment transport and fluvial process from nearby mainland. The enrichment of organic matter is chiefly controlled by mangrove litters and sea grasses. The concentration of lead in the marine sediments is subjected to sediment matrix, vicinity of the local pollutant sources and distance from the mainland coast. The ecological risk assessment clearly reveals that the sediments belong to the low risk category.

A preliminary study on coastal debris in Nallathanni Island, Gulf of Mannar Biosphere Reserve, Southeast coast of India.

Nine sampling stations were fixed to carry out the preliminary investigation on coastal debris from Nallathanni island, Gulf of Mannar Biosphere Reserve, Southeast coast of India. The coastal debris were separated and identified using hand picking, visual identification and microscopic studies. The coastal areas of the study region were less dominated by micro plastic contamination. The coastal debris was dominated by polyethylene bottles and fibrous fishnet materials. The distribution of the coastal debris along the coastal region is chiefly controlled by winnowing action of sea waves and Aeolian action along the berm region.

Water quality of the Uppanar estuary, Southern India: Implications on the level of dissolved nutrients and trace elements.

The current status of the water quality in terms of nutrients and trace elements were assessed in the Uppanar river estuary, Southern India. Twenty-five sampling stations were monitored in the study area, which is dominated by anthropogenic activities such as agriculture, settlements and fishing harbour in the downstream. Whereas, the upstream and midstream is dominated by barren lands and industrial hub respectively. Nutrients and trace elements such as nitrate, phosphate, iron and lead exceed the permissible limit of WHO drinking water guidelines. The water quality index derived from WHO permissible limits reveal that most of the samples fall under fair to good category. The marginal to fair water quality is noticed in the midstream to downstream region, where anthropogenic activities are high. The multivariate statistical analysis divulges that the overall water quality is controlled by two major sources such as natural weathering of soil/bedrock and agricultural and industrial activities.

Seasonal variations and environmental risk assessment of trace elements in the sediments of Uppanar River estuary, southern India.

Twenty four surface sediments were gathered from the Uppanar river estuary, southern India to evaluate the trace element contamination risk in the sediments. The circulation of organic matter and calcium carbonate were controlled by algal blooms and shell fragments. Moreover, the concentrations of iron and manganese in the estuarine sediments were possibly contributed by riverine sources and geogenic processes. The geoaccumulation index, enrichment factor and contamination factor reveals that the sediments were contaminated by copper and chromium. The pollution load index recommends that the estuarine sediments have the risk of pollution. The sediment pollution index highlights that the majority of the sediments are low polluted sediments. The potential ecological risk index discloses that the Uppanar river estuary is under moderate risk. The statistical analysis reveals that the organic matter content is managed by fine fractions and the majority of the trace elements are associated with each other having similar origin.