Thermodynamics of Tower-Block Infernos: Effects of Water on Aluminum Fires.

We review the thermodynamics of combustion reactions involved in aluminum fires in the light of the spate of recent high-profile tower-block disasters, such as the Grenfell fire in London 2017, the Dubai fires between 2010 and 2016, and the fires and explosions that resulted in the 9/11 collapse of the World Trade Center twin towers in New York. These fires are class B, i.e., burning metallic materials, yet water was applied in all cases as an extinguisher. Here, we highlight the scientific thermochemical reasons why water should never be used on aluminum fires, not least because a mixture of aluminum and water is a highly exothermic fuel. When the plastic materials initially catch fire and burn with limited oxygen (O2 in air) to carbon (C), which is seen as an aerosol (black smoke) and black residue, the heat of the reaction melts the aluminum (Al) and increases its fluidity and volatility. Hence, this process also increases its reactivity, whence it rapidly reacts with the carbon product of polymer combustion to form aluminum carbide (Al4C3). The heat of formation of Al4Cl3 is so great that it becomes white-hot sparks that are similar to fireworks. At very high temperatures, both molten Al and Al4C3 aerosol react violently with water to give alumina fine dust aerosol (Al2O3) + hydrogen (H2) gas and methane (CH4) gas, respectively, with white smoke and residues. These highly inflammable gases, with low spontaneous combustion temperatures, instantaneously react with the oxygen in the air, accelerating the fire out of control. Adding water to an aluminum fire is similar to adding "rocket fuel" to the existing flames. A CO2-foam/powder extinguisher, as deployed in the aircraft industry against aluminum and plastic fires by smothering, is required to contain aluminum fires at an early stage. Automatic sprinkler extinguisher systems should not be installed in tower blocks that are at risk of aluminum fires.

Failure to detect meaning in RSVP at 27 ms per picture.

The human visual system has the remarkable ability to rapidly detect meaning from visual stimuli. Potter, Wyble, Hagmann, and McCourt (Attention, Perception, & Psychophysics, 76, 270-279, 2014) tested the minimum viewing time required to obtain meaning from a stream of pictures shown in a rapid serial visual presentation (RSVP) sequence containing either six or 12 pictures. They reported that observers could detect the presence of a target picture specified by name (e.g., smiling couple) even when the pictures in the sequence were presented for just 13 ms each. Potter et al. claimed that this was insufficient time for feedback processing to occur, so feedforward processing alone must be able to generate conscious awareness of the target pictures. A potential confound in their study is that the pictures in the RSVP sequence sometime contained areas with no high-contrast edges, and so may not have adequately masked each other. Consequently, iconic memories of portions of the target pictures may have persisted in the visual system, thereby increasing the effective presentation time. Our study addressed this issue by redoing the Potter et al. study, but using four different types of masks. We found that when adequate masking was used, no evidence emerged that observers could detect the presence of a specific target picture, even when each picture in the RSVP sequence was presented for 27 ms. On the basis of these findings, we cannot rule out the possibility that feedback processing is necessary for individual pictures to be recognized.

Single-drug sedation with fentanyl for prehospital postintubation sedation in trauma patients.

BACKGROUND: A fentanyl-only (FO) regimen for prehospital postintubation sedation in trauma patients was compared with the standard protocol (SP) of fentanyl + benzodiazepine. METHODS: Intubated patients transported to a Level I trauma center from December 1, 2005, to April 30, 2009, were retrospectively reviewed. Before 2007, only SP was used; afterward both regimens were used. Groups were compared for hemodynamic and neurologic parameters in the prehospital setting and trauma bay, fluid volumes, time until general or neurosurgical intervention (NSI), and other outcomes. RESULTS: Groups were comparable with respect to age, sex, mechanism, alcohol level, intensive care unit length of stay, and hospital length of stay. Comorbidities were similar except hypertension (p = 0.019), and stroke (p = 0.029) were more frequent in FO patients. Prehospital heart rate and Glasgow Coma Scale (GCS) were similar. Trauma bay hemodynamic parameters and fluid resuscitation volumes were comparable, but pupil nonreactivity was more frequent in the FO group both overall (p = 0.032) and when comparing only patients with traumatic brain injury (TBI; p = 0.014). The incidence of TBI was comparable. Although the frequency of craniotomy (13% FO vs. 7% SP) and mortality (17% FO vs. 11% SP) were not statistically different overall, in patients with TBI, there was a higher incidence of NSI (28% vs. 14%, p = 0.015), craniotomy (14% vs. 3%, p = 0.02), and time to initial NSI (446 minutes vs. 193 minutes, p = 0.042) in the FO patients. CONCLUSIONS: In this study, an FO regimen was associated with similar hemodynamic but worse neurologic variables compared with the SP regimen. Prospective evaluation is warranted before adoption of this regimen, especially in TBI patients.

Role of solvent selectivity in the equilibrium surface composition of monolayers formed from a solution containing mixtures of organic thiols.

We have developed a simple model to quantify the effect of solvent selectivity on the surface composition of two-component self-assembled monolayers formed from solutions containing mixtures of organic thiols. The coarse-grained molecular model incorporates the relevant intermolecular interactions in the solution and monolayer to yield an expression for the free energy of monolayer formation. Minimization of the free energy results in a simple and analytically tractable expression for the monolayer composition as a function of solvent selectivity (defined as the difference in the Flory-type interaction parameters of the two organic thiols in the solution) and the degree of incompatibility between the adsorbate molecules. A comparison of our theory to experiments on the formation of two-component self-assembled monolayers from solution indicates that the coarse-grained molecular model captures the trends in the experimental data quite well.

On the development of a confocal Rayleigh-Brillouin microscope.

This Note illustrates how a confocal microscope may be modified to conduct Rayleigh-Brillouin mapping experiments that yield very useful information on the mechanical properties of interfacial materials in small volume elements. While the modifications to the microscope are quite straightforward, they do entail significant changes in the optical design. The instrument described herein consists of an argon ion laser equipped with an actively stabilized intercavity etalon that serves as the excitation source for a modified Zeiss LSM 310 confocal laser scan microscope. The optics of the microscope were reconfigured to enable interfacing of the microscope with a tandem triple-pass Fabry-Perot interferometer. This instrument enables three-dimensional Rayleigh-Brillouin spectral mapping of samples at micron spatial resolution. The performance of the instrument and its ability to perform both lateral and depth scans of the acoustic phonon velocity and, hence, the longitudinal modulus across bonded polymer/polymer and polymer/ceramic interfaces are illustrated and discussed.

Study of the hydrostatic pressure dependence of the Raman spectrum of single-walled carbon nanotubes and nanospheres.

We have investigated the behavior of single-walled carbon nanotubes and nanospheres (C(60)) under high hydrostatic pressure using Raman spectroscopy over the pressure range 0.2-10 GPa using a diamond anvil cell. Different liquid mixtures were used as pressure transmission fluids (PTF). Comparing the pressure dependence of the Raman peak positions for the nanotubes and the nanospheres in different PTF leads to the observation of a number of new phenomena. The observed shift in Raman peak position of both radial and tangential modes as a function of applied pressure and their dependence on the PTF chemical composition can be rationalized in terms of adsorption of molecular species from the of PTF on to the surface of the carbon nanotubes and/or nanospheres. The peak shifts are fully reversible and take place at a comparatively modest pressure (2-3 GPa) that is far below pressures that might be required to collapse the nanoparticles. Surface adsorption of molecular species on the nanotube or nanospheres provides a far more plausible rational for the observed phenomena than ideas based on the notion of tube collapse that have been put forward in the recent literature.