Bioavailability and health risk of pollutants around a controlled landfill in Morocco: Synergistic effects of landfilling and intensive agriculture.

Toxic contamination of agricultural soils by trace metal(oid)s can pose detrimental effects on human health and agroecological systems. In this view, the current research explored total and available metal(oid)s in surface soils and assessed the associated hazards using pollution indices, PMF modeling, PCA, and Montecarlo probabilistic human risk assessment with 10,000 repetitions. The mean concentrations of Cd, Pb, As, Cr, Ni, Cu, Zn, and Fe were 0.89, 24.86, 1.81, 19.10, 25.44, 7.98, 49.12 and 6183.32 mg kg-1 dry weight, respectively. These findings highlighted that the concentration of pollutants exceeded the values measured in the geochemical background. Soil enrichment by heavy metal (oid)s was confirmed by analyzing available fractions using DTPA ,CaCl2 and enrichment factor (EF). Additionally, pollution indicators (Igeo, PLI, and PERI) displayed significant contamination levels, with a higher ecological risk. Matrix Factorization (PMF) receptor and multivariate statistical analysis reflected that anthropogenic activities, particularly landfilling and agricultural practices were the main causes of the contamination. Furthermore, probabilistic and deterministic human risk assessments showed that carcinogenic risks exceeded the threshold values (10-4) set by the USEPA. Consequently, it is crucial to implement continuous monitoring and supervision of landfill sites to prevent additional pollution. These measures should be integrated into the management plans for waste management.

Determination of properties and environmental impact due to the inclusion of cigarette fibers in mortar: a new solution to mitigate the CB pollution.

Cigarette butts generated are one of the major sources of total solid waste production and lead to environmental issues. This article has the objective of evaluating the effects of cellulose acetate microfibers (CAFs) sourced from discarded cigarette filters (CFs) as fiber reinforcement on the physico-mechanical properties and thermal conductivity of cementitious materials. To do so, mortar samples were prepared using different incorporated quantities of fibers (0.5, 1, 1.5, 2, 2.5, and 5% compared to the quantity of sand added to the mixture) and subjected to different tests to characterize the influence of CAFs on the microstructure of elaborated materials, considering the changes in workability time, compressive strength, flexural strength, density, water absorption, and microstructural analysis. Furthermore, the life cycle assessment (LCA) of mortar mixes in terms of CO2 emissions is made. The results revealed that the increasing percentages of CAFs reduced the dry density and compressive strength, by approximately 1.62-51% and 37-69.64%, respectively, and a notable enhancement of insulation characteristics by about 5-47.5% was achieved. Microstructure analysis confirmed the experimental investigation and revealed that adding more than 1% of fibers resulted in a significantly low unit weight with greater entrapped air content. The studies prove the possibility of recycling cigarette butts for insulating cementitious matrix. In addition, applying mortar containing acetate cellulose fibers is recognized as a more environmentally friendly mixture in terms of reducing CO2 emissions and could participate significantly in the achievement of SDGs.

BaTiO3 Functional Perovskite as Photocathode in Microbial Fuel Cells for Energy Production and Wastewater Treatment.

Microbial fuel cells (MFCs) provide new opportunities for the sustainable production of energy, converting organic matter into electricity through microorganisms. Moreover, MFCs play an important role in remediation of environmental pollutants from wastewater with power generation. This work focuses on the evaluation of ferroelectric perovskite materials as a new class of non-precious photocatalysts for MFC cathode construction. Nanoparticles of BaTiO3 (BT) were prepared and tested in a microbial fuel cell (MFC) as photocathode catalytic components. The catalyst phases were synthesized, identified and characterized by XRD, SEM, UV-Vis absorption spectroscopy, P-E hysteresis and dielectric measurements. The maximum absorption of BT nanoparticles was recorded at 285 nm and the energy gap (Eg) was estimated to be 3.77 eV. Photocatalytic performance of cathodes coated with BaTiO3 was measured in a dark environment and then in the presence of a UV-visible (UV-Vis) light source, using a mixture of dairy industry and domestic wastewater as a feedstock for the MFCs. The performance of the BT cathodic component is strongly dependent on the presence of UV-Vis irradiation. The BT-based cathode functioning under UV-visible light improves the maximum power densities and the open circuit voltage (OCV) of the MFC system. The values increased from 64 mW m-2 to 498 mW m-2 and from 280 mV to 387 mV, respectively, showing that the presence of light effectively improved the photocatalytic activity of this ceramic. Furthermore, the MFCs operating under optimal conditions were able to reduce the chemical oxygen demand load in wastewater by 90% (initial COD = 2500 mg L-1).

ZrP2O7 as a Cathodic Material in Single-Chamber MFC for Bioenergy Production.

The present work is the first investigation of the electrocatalytic performances of ZrP2O7 as a cathode in a single-chamber Microbial Fuel Cell (MFC) for the conversion of chemical energy from wastewater to bioelectricity. This catalyst was prepared by a coprecipitation method, then characterized by X-ray diffraction analysis (XRD), Fourier transform infrared spectroscopy (FTIR), scanning electron microscopy (SEM), energy dispersive X-ray analysis (EDX), ultraviolet-visible-near-infrared spectrophotometry (UV-Vis-NIR), and cyclic voltammetry analyses. The acid-basic characteristics of the surface were probed by using 2-butanol decomposition. The conversion of 2-butanol occurs essentially through the dehydrating reaction, indicating the predominantly acidic character of the solid. The electrochemical test shows that the studied cathode material is electroactive. In addition, the ZrP2O7 in the MFC configuration exhibited high performance in terms of bioelectricity generation, giving a maximum output power density of around 449 mW m-2; moreover, it was active for wastewater treatment, reducing the chemical oxygen demand (COD) charge to 50% after three days of reaction.

Primary urachal adenocarcinoma treated effectively with surgery and post operative chemoradiation therapy: Case Report with review of the literature.

Urachal carcinomas is a rare and aggressive tumor, accounting for less than 1% of all bladder cancers. We report a case of a 32-year-old man, with no past medical history, complaining of a total hematuria. The abdominal computed tomography scan revealed an exophytic mass of 3 cm on the dome of the bladder, extending to the urachus. The computed tomography scan of chest, abdomen and pelvis did not show neither regional or distant metastasis. Partial Cystectomy with umbilectomy was performed. Histopathology was in favor of urachal adenocarcinoma, classed pT3a, based on Sheldon's staging system, pT2b based on Mayo system, and pT2 based on Ontario system.

Hematological and biochemical abnormalities associated with severe forms of COVID-19: A retrospective single-center study from Morocco.

Since December 2019, the coronavirus disease (COVID-19) pandemic has catapulted the world into a marked health crisis, with over 29 million cases and >930,000 deaths. To better detect affected individuals at an early stage and stop disease progression to an advanced stage, several studies have been conducted to identify the clinical, biological, and radiological characteristics of COVID-19. This study aimed to enrich the literature by critically analyzing the clinical and biological characteristics of 134 patients from the North African Mediterranean region, including numerous genetic, epigenetic, and environmental factors that may influence disease evolution. This single-center retrospective study included all patients older than 18 years confirmed to have COVID-19 and hospitalized at the Cheikh Khalifa University Hospital affiliated with Mohammed VI University of Health Sciences, Casablanca, Morocco. Clinical, demographic, and biological data were analyzed in a cohort of severe and non-severe patients. Univariate analysis was performed to identify factors predictive of severity. There were 134 patients: the median age was 53 years, and 54.5% were male. Of these, 89 had mild to moderate disease; 45 had severe to critical disease, of which 14 died and 31 survived. Advanced age, presence of comorbidities, male sex, and infection in ethnic or family groups were risk factors for progression to severe disease. The presence of abnormalities in the following parameters were strongly associated with progression to severe disease: white blood cells (WBC), neutrophils, lymphocytes, C-reactive protein (CRP), procalcitonin, D-dimers, lactate dehydrogenase (LDH), ferritin, creatinine, aspartate aminotransferase (ASAT), and alanine aminotransferase (ALAT) during both admission and hospitalization. Based on these results and an extensive literature review, we recommend that clinicians closely monitor the biological parameters identified herein and perform immunological and genetic studies.

Gastric bronchogenic cyst presenting as a submucosal mass: a case report.

INTRODUCTION: Bronchogenic cysts are developmental anomalies of the primitive foregut which mostly occur in the lung. Gastric bronchogenic cysts are extremely rare; few cases have been reported in the literature and the diagnosis was often made following surgical resection. CASE PRESENTATION: A 40-year-old North African man was admitted to our hospital with a gastric submucosal mass. An endoscopic ultrasound revealed a unilocular cystic mass located in the muscular layer. Its content was echogenic suggestive of mucus. Magnetic resonance imaging confirmed the liquid nature of the cyst and showed a high ratio of proteins. Based on these observations, the diagnosis of bronchogenic cyst was confirmed. An endoscopic monitoring was decided rather than surgery because of the small size of the cyst and the absence of symptoms. CONCLUSION: Although gastric bronchogenic cysts are rare, they should be well known and considered in all differential diagnoses of gastric tumors. We report a new case of gastric bronchogenic cyst and highlight the contribution of morphological tests that currently allow a non-invasive diagnosis.

Chronic pelvic pain reveals sacral osteomyelitis three years after abdominal hysterectomy.

BACKGROUND: Deep pelvic abscess is a well-known infective complication in gynecologic practice. However, sacral osteomyelitis has been reported rarely. We describe sacral infection presenting three years after abdominal hysterectomy and point out the difficulty in management. METHODS: Case report and review of the pertinent literature. RESULTS: A 46-year-old woman who had undergone abdominal hysterectomy three years before presented with an 8-month history of abdominopelvic pain recently intensifying in the sitting position without fever. Gynecologic, urinary, and rectal examination did not yield positive findings. An abdominopelvic computed tomography (CT) scan was normal except for sacral osteolysis. A neoplasm was suspected, but magnetic resonance imaging revealed an S2-S4 cystic collection with presacral extension. Neurologic examination did not show any focal deficits. A posterior CT-guided biopsy-aspiration yielded purulent fluid. Pathologic examination revealed inflammatory granulations without any malignant tumor. Abscess cultures grew three microorganisms. The patient's symptoms resolved completely after 3 months of antibiotic therapy. CONCLUSIONS: Sacral osteomyelitis has not been reported previously after abdominal hysterectomy. Early diagnosis was made difficult by the absence of neurologic findings. Such postoperative infection should be considered after pelvic surgery. Minimally invasive needle aspiration may confirm the diagnosis and reduce the necessary extent of surgical intervention.