1.
Inorg Chem
; 43(3): 840-2, 2004 Feb 09.
Artigo
em Inglês
| MEDLINE
| ID: mdl-14753799
RESUMO
A rare asymmetric end-on double azido-bridged copper(II) complex has been synthesized and characterized structurally and magnetically. The Cu-N(azide)-Cu angle in this complex is calculated to be 89.1 degrees. This is unusually low in comparison to the same angle in other end-on azido-bridged binuclear complexes reported so far. Though a strong ferromagnetic interaction between the metal centers is expected in the complex, the coupling has actually been found to be antiferromagnetic, instead.