1.
Chem Commun (Camb)
; 48(32): 3860-2, 2012 Apr 21.
Artigo
em Inglês
| MEDLINE
| ID: mdl-22398874
RESUMO
A chiral gelator, RR- or SS-N,N'-diperfluorooctanoyl-1,2-diaminocyclohexane, gelated racemic 2-butanol. The gel was most stable at the racemic mixture, its stability lowered with the increase in the optical purity of the gelator. Notably, characteristic helically coiled fibrils were formed in the narrow region of enantiomer excess (ee = 0.2-0.4). Promotion effects of the antipodal enantiomers are proposed.