1.
J Org Chem
; 88(19): 14131-14139, 2023 Oct 06.
Artigo
em Inglês
| MEDLINE
| ID: mdl-37721789
RESUMO
An efficient methodology to form 4-alkoxy- and 4-aryloxybenzo[d][1,2,3]triazines via an intramolecular heterocyclization of 1-azido-2-[isocyano(p-tosyl)methyl]benzenes under basic conditions has been developed. DFT calculations have been performed to further understand the mechanism of this heterocyclization, which occurs in good to excellent yields with a broad scope.