The impact of particle size, relative humidity, and sulfur dioxide on iron solubility in simulated atmospheric marine aerosols.

Iron is a limiting nutrient in about half of the world's oceans, and its most significant source is atmospheric deposition. To understand the pathways of iron solubilization during atmospheric transport, we exposed size segregated simulated marine aerosols to 5 ppm sulfur dioxide at arid (23 ± 1% relative humidity, RH) and marine (98 ± 1% RH) conditions. Relative iron solubility increased as the particle size decreased for goethite and hematite, while for magnetite, the relative solubility was similar for all of the fine size fractions (2.5-0.25 µm) investigated but higher than the coarse size fraction (10-2.5 µm). Goethite and hematite showed increased solubility at arid RH, but no difference (p > 0.05) was observed between the two humidity levels for magnetite. There was no correlation between iron solubility and exposure to SO2 in any mineral for any size fraction. X-ray absorption near edge structure (XANES) measurements showed no change in iron speciation [Fe(II) and Fe(III)] in any minerals following SO2 exposure. SEM-EDS measurements of SO2-exposed goethite revealed small amounts of sulfur uptake on the samples; however, the incorporated sulfur did not affect iron solubility. Our results show that although sulfur is incorporated into particles via gas-phase processes, changes in iron solubility also depend on other species in the aerosol.

Respirable antimony and other trace-elements inside and outside an elementary school in Flagstaff, AZ, USA.

Because people spend almost 90% of their time indoors, ambient air monitors may severely underestimate actual exposure to atmospheric particulate matter (PM). Therefore, it becomes increasingly important to better understand the microenvironments where people are spending their time. For preadolescent children, the best estimates of exposure may be inside of their school. In this study, 11 size fractions of PM were collected inside and outside of an elementary school in Flagstaff, AZ, USA. In particles<1 µm (PM1), the total mass indoors was similar to the mass outdoors (indoor:outdoor, I:O, ratio=0.92 ± 0.16). In the PM1-10 fraction, however, the mass concentration inside the school was highly elevated relative to outside the school (I:O ratios=13 ± 3). Mass concentrations of 27 elements were analyzed by ICP-MS. For all metals except for antimony (Sb), the PM1 and PM1-10 I:O ratios are found to be similar to the overall PM mass (near 1 and 13, respectively). In addition, indoor and outdoor particle size distributions reveal a crustal character for every element except Cu, Zn, Pb, and Sb. Therefore, we hypothesize that most of the PM mass inside the school is a result of transport from outside the school followed by resuspension from floors and clothing. In the PM1 fraction, the indoor mass of Sb was 86 times greater than the outdoor mass and had an air concentration of 17 ngm(-3) - greater than many urban areas around the world. Cu:Sb ratios and size distribution functions suggest that the excess source of PM1 indoor Sb results from the suspension of embedded Sb (used as a flame retardant) in the carpeting. This is the first study to observe elevated submicron Sb in schools and further studies are required to determine if this is a widespread health risk.