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1.
Acta Biochim Pol ; 54(4): 727-32, 2007.
Artigo em Inglês | MEDLINE | ID: mdl-18066396

RESUMO

The occurrence of polyprenols in leaves of over 340 species of dendroflora in natural habitats in the regions of Hanoi and Hue in Vietnam was studied. Plant material was collected in the late autumn (October/November) during the end of a vegetation season. Leaves of about 200 plant species did not contain detectable amounts of polyprenols in contrast to few systematic families, e.g. Moraceae, Euphorbiaceae, where polyprenols were highly abundant and their pattern could be used as a chemotaxonomic criterion. Most often dominating polyprenols were prenol-11 and prenol-12. In several angiosperm species prenol-13 and detectable amounts of prenol-14 were also found. The incidence of prenol-13 and -14 was not restricted to a specific taxonomic group since species exhibiting domination of such longer chain polyprenols belonged to various systematic families. In some plants (e.g. Ceiba pentandra) alpha-cis polyprenols were accompanied by alpha-trans counterparts. This report describes several new plant species that may serve as natural sources of long chain polyprenols.


Assuntos
Pentanóis/isolamento & purificação , Folhas de Planta/química , Hemiterpenos , Vietnã
2.
Chem Phys Lipids ; 147(2): 103-12, 2007 Jun.
Artigo em Inglês | MEDLINE | ID: mdl-17507003

RESUMO

A novel type of polyprenols, alloprenols, with an alpha-trans-isoprenoid unit was found in the leaves of Allophylus caudatus (Sapindaceae) besides typical alpha-cis-polyprenols. The polyprenol family (Prenol-11-13, Prenol-12 dominating) was accompanied by traces of dolichols of the same chain-length. Prenol alpha-cis- and alpha-trans-isomers were chromatographically separated and their structure was analyzed by HPLC/ESI-MS, HR-ESI-MS and 1H and 13C NMR spectroscopy. Model compounds, semi-synthetic alpha-isomers of all-trans-Pren-9 and mainly-cis-Pren-11, were obtained using an oxidation-reduction procedure. Comparison of their NMR spectra confirmed the structure of the newly identified polyprenols. The observed pattern of NMR signal shifts may be applied for elucidation of isoprenoid structure.


Assuntos
Pentanóis/química , Sapindaceae/química , Cromatografia Líquida de Alta Pressão , Cromatografia em Camada Fina , Hemiterpenos , Espectroscopia de Ressonância Magnética , Estrutura Molecular , Espectrometria de Massas por Ionização por Electrospray
3.
Acta Biochim Pol ; 52(1): 233-41, 2005.
Artigo em Inglês | MEDLINE | ID: mdl-15827620

RESUMO

In many plants belonging to angiosperms and gymnosperms the accumulation in leaves of long chain polyprenols and polyprenyl esters during growth in natural habitats depends on the light intensity. The amount of polyprenols in leaves is also positively correlated with the thickness of the leaf blade (SLA, specific leaf area). The polyprenol content of leaves shows seasonal changes with a maximum in autumn and a minimum in early summer with the difference between poorly and well illuminated plants persisting throughout the vegetation season.


Assuntos
Luz , Pentanóis/metabolismo , Folhas de Planta/metabolismo , Árvores/metabolismo , Cromatografia Líquida de Alta Pressão , Hemiterpenos , Estrutura Molecular , Pentanóis/química , Estações do Ano
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