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Nano Lett ; 10(5): 1589-94, 2010 May 12.
Artigo em Inglês | MEDLINE | ID: mdl-20405819

RESUMO

We report on light emission from biased metallic single-wall carbon nanotube (SWNT), multiwall carbon nanotube (MWNT) and few-layer graphene (FLG) devices. SWNT devices were assembled from tubes with different diameters in the range 0.7-1.5 nm. They emit light in the visible spectrum with peaks at 1.4 and 1.8 eV. Similar peaks are observed for MWNT and FLG devices. We propose that this light emission is due to phonon-assisted radiative decay from populated pi* band states at the M point to the Fermi level at the K point. Since for most carbon nanotubes as well as for graphene the energy of unoccupied states at the M point is close to 1.6 eV, the observation of two emission peaks at approximately 1.6 +/- approximately 0.2 eV could indicate radiative decay under emission or absorption of optical phonons, respectively.


Assuntos
Cristalização/métodos , Eletroquímica/métodos , Grafite/química , Medições Luminescentes/métodos , Nanotecnologia/métodos , Nanotubos de Carbono/química , Substâncias Macromoleculares/química , Teste de Materiais , Metais/química , Conformação Molecular , Tamanho da Partícula , Fótons , Propriedades de Superfície
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