1.
Chem Commun (Camb)
; 60(38): 5022-5025, 2024 May 07.
Artigo
em Inglês
| MEDLINE
| ID: mdl-38629464
RESUMO
We present two novel cobalt pyridyldiimine complexes functionalized with pyrene. Initially modest in homogeneous acetonitrile solution, their electrocatalytic CO2 reduction performance significantly improves upon immobilization on MWCNTs in an aqueous carbonate buffer. The complexes exhibit outstanding stability, with CO selectivity exceeding 97%, and TON and TOF values reaching up to 104 and above 1.2 s-1, respectively.