RESUMO
We propose a method for high-speed terahertz spectroscopic imaging that is based on electro-optic sampling with a noncollinear geometry of the THz beam and probe laser beam and has a multistep mirror in the path of the probe beam. We made an imaging system that operates in the over 2.0-THz range and enables the sample region corresponding to a (28 × 28)-pixel area on the sensor to be imaged with a spatial resolution of 1.07 mm and a frequency resolution of 0.079 THz. We also show how the proposed method might be extended for faster THz spectroscopic imaging.
RESUMO
Gaseous monochlorobenzene was irradiated with KrF excimer laser (248 nm) under reduced pressure. The photodecomposition was an apparent first order reaction. When the system contained no additive gas, the photolysis was found to give benzene (conversion yield: 49%) in the gas phase and many unidentified products in the solid phase. On the other hand, in the presence of oxygen, carbon dioxide (10%), carbon monoxide (16%), hydrogen chloride (52%) and acetylene (2%) are produced and the peaks shown on the gas chromatogram of the solid phase were effectively suppressed.
