Fabrication of magnesium oxide-calcium alginate hydrogel for scaffolding yttrium and neodymium from aqueous solutions.

In this research, the possibility of using sustainable nano-MgO/Ca-alginate beads for efficient sorption of some rare earth metal ions such as neodymium(III) and yttrium(III) from an aqueous acidic solution was explored. The nano-MgO/Ca-alginate beads adsorbent was characterized before and after sorption of Nd(III) and Y(III) using scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FT-IR), energy dispersive X-ray analysis (EDX), and X-ray diffraction (XRD) techniques. Batch sorption parameters were investigated, such as contact time, initial metal ion concentration, and adsorbent dose (V/m). The calculated experimental results showed that the suitable selected sorption conditions were carried out using 100 mg/L of Nd(III) and Y(III) with nano MgO/Ca-alginate beads (contact time = 90 min, pH = 2, V/m = 0.05 L/g). The maximum sorption capacity of 0.1 g of nano MgO/Ca-alginate was found to be 7.85 mg/g and 5.60 mg/g for Nd(III) and Y(III), respectively. The desorption of Nd(III) and Y(III) from the loaded nano MgO/Ca-alginate was achieved with 1.0 M sulfamic acid and found to be 51.0% and 44.2%, respectively. The calculated thermodynamic parameters for the nano MgO/Ca-alginate/Nd/Y system show that the positive charge of ΔHo confirmed the endothermic nature of the sorption process, ΔSo (positive) indicates an increase in reaction system disordering, and ΔGo (negative) indicates a spontaneous process. These kinetic results indicate that the sorption process of Nd(III) and Y(III) on nano MgO/Ca-alginate beads is performed by the chemisorption process.

Modeling and equilibrium studies on the recovery of praseodymium (III), dysprosium (III) and yttrium (III) using acidic cation exchange resin.

In this research, the possibility of using hydrogenated Dowex 50WX8 resin for the recovery and separation of Pr(III), Dy(III) and Y(III) from aqueous nitrate solutions were carried out. Dowex 50WX8 adsorbent was characterized before and after sorption of metal ions using Fourier-transform infrared spectroscopy (FT-IR), Scanning Electron Microscope (SEM) and Energy Dispersive X-Ray Analysis (EDX) techniques. Sorption parameters were studied which included contact time, initial metal ion concentration, nitric acid concentration and adsorbent dose. The equilibrium time has been set at about 15.0 min. The experimental results showed that the sorption efficiency of metal ions under the investigated conditions decreased with increasing nitric acid concentration from 0.50 to 3.0 M. The maximum sorption capacity was found to be 30.0, 50.0 and 60.0 mg/g for Pr(III), DY(III) and Y(III), respectively. The desorption of Pr(III) from the loaded resin was achieved with 1.0 M citric acid at pH = 3 and found to be 58.0%. On the other hand, the maximum desorption of Dy(III) and Y(III) were achieved with 1.0 M nitric acid and 1.0 M ammonium carbonate, respectively. The sorption isotherm results indicated that Pr(III) and Y(II) fitted with nonlinear Langmuir isotherm model with regression factors 0.995 and 0.978, respectively; while, Dy(III) fitted with nonlinear Toth isotherm model with R2 = 0.966. A Flow sheet which summarizes the sorption and desorption processes of Pr(III), DY(III) and Y(III) using Dowex 50WX8 from nitric acid solution under the optimum conditions is also given.