Influence of Meteorological Variables and Forest Fires Events on Air Quality in an Urban Area (Córdoba, Argentina).

Extreme environmental events, such as forest fires, are a major emission source of aerosols into the atmosphere. Thus, to investigate the contribution of local forest fires to urban particulate matter, we selected several forest fire indicators, such as number of heat sources, fire events, and burnt area, and collected particles smaller than 2.5 µm (PM2.5) during a 2.5-year period in Cordoba City (Argentina). Temporal variation of PM2.5 concentration and composition was described considering fire and nonfire periods, and the influence of meteorological variables was estimated as well. On average, PM2.5 levels registered in Córdoba city during the study period were lower than values reported for other similar cities in Latin America, despite the fact that during wintertime an increase in PM2.5 levels was observed due to the occurrence of thermal inversions. Several fire events taking place in the nearby hills around the city during winter and spring 2013 suggest that biomass burning was a strong contribution to urban particles levels, which is consistent with the significant correlation between PM2.5 concentration and heat sources number. During fire periods, levels of Fe, Ca, and K, were significantly higher than in the nonfire periods, suggesting that these elements can be reliable forest fire markers.

Effect of UV-B radiation on the content of UV-B absorbing compounds and photosynthetic parameters in Parmotrema austrosinense from two contrasting habitats.

We studied the resistance of Parmotrema austrosinense to UV-B stress. We focused on the effects of a high dose UV-B radiation on the content of chlorophylls, carotenoids and UV-B screening compounds. Photosynthetic parameters were measured by chlorophyll fluorescence (potential and effective quantum yields, photochemical and non-photochemical quenching) and evaluated in control and UV-B-treated lichens. Lichens from two different locations in Cordoba, Argentina, were selected: (i) high altitude and dry plots at (Los Gigantes) and (ii) lowland high salinity plots (Salinas Grandes). UV-B treatment led to a decrease in the content of photosynthetic pigments and UV-B screens (absorbance decrease in 220-350 nm) in the samples from Salinas Grandes, while in Los Gigantes samples, an increase in UV-B screen content was observed. Chlorophyll fluorescence parameters showed a UV-B-induced decline in FV /FM , ΦPSII and qP indicating limitation of primary photosynthetic processes in photosystem II (PSII) of symbiotic alga, more pronounced in Salinas Grandes samples. Protective mechanism of PSII were activated by the UV-B treatment to a higher extent in samples from Salinas Grandes (NPQ 0.48) than in Los Gigantes samples (NPQ 0.26). We concluded that site-related characteristics, and in particular different UV-B radiation regimen, had a strong effect on resistance of the photosynthetic apparatus of P. austrosinense to UV-B radiation.

Land use and air quality in urban environments: Human health risk assessment due to inhalation of airborne particles.

Particle matter (PM) and its associated compounds are a serious problem for urban air quality and a threat to human health. In the present study, we assessed the intraurban variation of PM, and characterized the human health risk associated to the inhalation of particles measured on PM filters, considering different land use areas in the urban area of Cordoba city (Argentina) and different age groups. To assess the intraurban variation of PM, a biomonitoring network of T. capillaris was established in 15 sampling sites with different land use and the bioaccumulation of Co, Cu, Fe, Mn, Ni, Pb and Zn was quantified. After that, particles were collected by instrumental monitors placed at the most representative sampling sites of each land use category and an inhalation risk was calculated. A remarkable intraurban difference in the heavy metals content measured in the biomonitors was observed, in relation with the sampling site land use. The higher content was detected at industrial areas as well as in sites with intense vehicular traffic. Mean PM10 levels exceeded the standard suggested by the U.S. EPA in all land use areas, except for the downtown. Hazard Index values were below EPA's safe limit in all land use areas and in the different age groups. In contrast, the carcinogenic risk analysis showed that all urban areas exceeded the acceptable limit (1 × 10-6), while the industrial sampling sites and the elder group presented a carcinogenic risk higher that the unacceptable limit. These findings validate the use of T. capillaris to assess intraurban air quality and also show there is an important intraurban variation in human health risk associated to different land use.