Ab initio study of the enantio-selective magnetic-field-induced second harmonic generation in chiral molecules.

We present a systematic ab initio study of enantio-selective magnetic-field-induced second harmonic generation (MFISHG) on a set of chiral systems ((l)-alanine, (l)-arginine and (l)-cysteine; 3,4-dehydro-(l)-proline; (S)-α-phellandrene; (R,S)- and (S,S)-cystine disulphide; N-(4-nitrophenyl)-(S)-prolinol, N-(4-(2-nitrovinyl)-phenyl)-(S)-prolinol, N-(4-tricyanovinyl-phenyl)-(S)-prolinol, (R)-BINOL, (S)-BINAM and 6-(M)-helicene). The needed electronic frequency dependent cubic response calculations are performed within a density functional theory (DFT) approach. A study of the dependence of the property on the choice of electron correlation, on one-electron basis set extension and on the choice of magnetic gauge origin is carried out on a prototype system (twisted oxygen peroxide). The magnetic gauge dependence analysis is extended also to the molecules of the set. An attempt to analyze the structure-property relationships is also made, based on the results obtained for biphenyl (in a frozen twisted conformation), for prolinol and for some of their derivatives. The strength of the effect is discussed, in order to establish its measurability with a proposed experimental setup.

Realization of a distributed Bragg reflector for propagating guided matter waves.

We report on the experimental study of a Bragg reflector for guided, propagating Bose-Einstein condensates. A one-dimensional attractive optical lattice of finite length created by red-detuned laser beams selectively reflects some velocity components of the incident matter wave packet. We find quantitative agreement between the experimental data and one-dimensional numerical simulations and show that the Gaussian envelope of the optical lattice has a major influence on the properties of the reflector. In particular, it gives rise to multiple reflections of the wave packet between two symmetric locations where Bragg reflection occurs. Our results are a further step towards integrated atom-optics setups for quasi-cw matter waves.

A Zeeman slower design with permanent magnets in a Halbach configuration.

We describe a simple Zeeman slower design using permanent magnets. Contrary to common wire-wound setups, no electric power and water cooling are required. In addition, the whole system can be assembled and disassembled at will. The magnetic field is however transverse to the atomic motion and an extra repumper laser is necessary. A Halbach configuration of the magnets produces a high quality magnetic field and no further adjustment is needed. After optimization of the laser parameters, the apparatus produces an intense beam of slow and cold (87)Rb atoms. With typical fluxes of (1-5) × 10(10) atoms/s at 30 m s(-1), our apparatus efficiently loads a large magneto-optical trap with more than 10(10) atoms in 1 s, which is an ideal starting point for degenerate quantum gas experiments.

All-optical atom surface traps implemented with one-dimensional planar diffractive microstructures.

We characterize the loading, containment and optical properties of all-optical atom traps implemented by diffractive focusing with one-dimensional (1D) microstructures milled on gold films. These on-chip Fresnel lenses with focal lengths of the order of a few hundred microns produce optical-gradient-dipole traps. Cold atoms are loaded from a mirror magneto-optical trap (MMOT) centered a few hundred microns above the gold mirror surface. Details of loading optimization are reported and perspectives for future development of these structures are discussed.