Metallic phase in stoichiometric CeOBiS2 revealed by space-resolved ARPES.

Recently CeOBiS2 system without any fluorine doping is found to show superconductivity posing question on its origin. Using space resolved ARPES we have found a metallic phase embedded in the morphological defects and at the sample edges of stoichiometric CeOBiS2. While bulk of the sample is semiconducting, the embedded metallic phase is characterized by the usual electron pocket at X point, similar to the Fermi surface of doped BiS2-based superconductors. Typical size of the observed metallic domain is larger than the superconducting correlation length of the system suggesting that the observed superconductivity in undoped CeOBiS2 might be due to this embedded metallic phase at the defects. The results also suggest a possible way to develop new systems by manipulation of the defects in these chalcogenides with structural instability.

Evidence for Spin Singlet Pairing with Strong Uniaxial Anisotropy in URu_{2}Si_{2} Using Nuclear Magnetic Resonance.

In order to identify the spin contribution to superconducting pairing compatible with the so-called "hidden order", ^{29}Si nuclear magnetic resonance measurements have been performed using a high-quality single crystal of URu_{2}Si_{2}. A clear reduction of the ^{29}Si Knight shift in the superconducting state has been observed under a magnetic field applied along the crystalline c axis, corresponding to the magnetic easy axis. These results provide direct evidence for the formation of spin-singlet Cooper pairs. Consequently, results indicating a very tiny change of the in-plane Knight shift reported previously demonstrate extreme uniaxial anisotropy for the spin susceptibility in the hidden order state.

Thermal Conductivity through the Quantum Critical Point in YbRh_{2}Si_{2} at Very Low Temperature.

The thermal conductivity of YbRh_{2}Si_{2} has been measured down to very low temperatures under field in the basal plane. An additional channel for heat transport appears below 30 mK, both in the antiferromagnetic and paramagnetic states, respectively, below and above the critical field suppressing the magnetic order. This excludes antiferromagnetic magnons as the origin of this additional contribution to thermal conductivity. Moreover, this low temperature contribution prevails a definite conclusion on the validity or violation of the Wiedemann-Franz law at the field-induced quantum critical point.

Direct observation of lattice symmetry breaking at the hidden-order transition in URu2Si2.

Since the 1985 discovery of the phase transition at THO=17.5 K in the heavy-fermion metal URu2Si2, neither symmetry change in the crystal structure nor large magnetic moment that can account for the entropy change has been observed, which makes this hidden order enigmatic. Recent high-field experiments have suggested electronic nematicity that breaks fourfold rotational symmetry, but direct evidence has been lacking for its ground state in the absence of magnetic field. Here we report on the observation of lattice symmetry breaking from the fourfold tetragonal to twofold orthorhombic structure by high-resolution synchrotron X-ray diffraction measurements at zero field, which pins down the space symmetry of the order. Small orthorhombic symmetry-breaking distortion sets in at THO with a jump, uncovering the weakly first-order nature of the hidden-order transition. This distortion is observed only in ultrapure samples, implying a highly unusual coupling nature between the electronic nematicity and underlying lattice.

NMR study of in-plane twofold ordering in URu(2)Si(2).

We report (29)Si NMR spectra and Knight shift measurements as a function of applied field orientation in the (001) basal plane of URu(2)Si(2). Observed linewidth oscillations confirm the in-plane twofold ordered domain state observed in recent magnetic susceptibility measurements. Analysis of our linewidth data leads to estimate ∼ 0.4% for the twofold intrinsic (monodomain) susceptibility anisotropy in the basal plane, a value ∼ 15 times smaller than that obtained from recent susceptibility measurements.

Cyclotron resonance in the hidden-order phase of URu2Si2.

We report the first observation of cyclotron resonance in the hidden-order phase of ultraclean URu2Si2 crystals, which allows the full determination of angle-dependent electron-mass structure of the main Fermi-surface sheets. We find an anomalous splitting of the sharpest resonance line under in-plane magnetic-field rotation. This is most naturally explained by the domain formation, which breaks the fourfold rotational symmetry of the underlying tetragonal lattice. The results reveal the emergence of an in-plane mass anisotropy with hot spots along the [110] direction, which can account for the anisotropic in-plane magnetic susceptibility reported recently. This is consistent with the "nematic" Fermi liquid state, in which itinerant electrons have unidirectional correlations.

Rotational symmetry breaking in the hidden-order phase of URu2Si2.

A second-order phase transition is characterized by spontaneous symmetry breaking. The nature of the broken symmetry in the so-called "hidden-order" phase transition in the heavy-fermion compound URu(2)Si(2), at transition temperature T(h) = 17.5 K, has posed a long-standing mystery. We report the emergence of an in-plane anisotropy of the magnetic susceptibility below T(h), which breaks the four-fold rotational symmetry of the tetragonal URu(2)Si(2). Two-fold oscillations in the magnetic torque under in-plane field rotation were sensitively detected in small pure crystals. Our findings suggest that the hidden-order phase is an electronic "nematic" phase, a translationally invariant metallic phase with spontaneous breaking of rotational symmetry.

Similarity of the Fermi surface in the hidden order state and in the antiferromagnetic state of URu2Si2.

Shubnikov-de Haas measurements of high quality URu2Si2 single crystals reveal two previously unobserved Fermi surface branches in the so-called hidden order phase. Therefore, about 55% of the enhanced mass is now detected. Under pressure in the antiferromagnetic state, the Shubnikov-de Haas frequencies for magnetic fields applied along the crystalline c axis show little change compared with the zero pressure data. This implies a similar Fermi surface in both the hidden order and antiferromagnetic states, which strongly suggests that the lattice doubling in the antiferromagnetic phase due to the ordering vector Q(AF)=(001) already occurs in the hidden order. These measurements provide a good test for existing or future theories of the hidden order parameter.

Possible phase transition deep inside the hidden order phase of ultraclean URu2Si2.

To elucidate the underlying nature of the hidden order (HO) state in heavy-fermion compound URu(2)Si(2), we measure electrical transport properties of ultraclean crystals in a high field, low temperature regime. Unlike previous studies, the present system with much less impurity scattering resolves a distinct anomaly of the Hall resistivity at H;{*} = 22.5 T, well below the destruction field of the HO phase = or approximately 36 T. In addition, a novel quantum oscillation appears above a magnetic field slightly below H;{*}. These results indicate an abrupt reconstruction of the Fermi surface, which implies a possible phase transition well within the HO phase caused by a band-dependent destruction of the HO parameter.

Crossover from the quantum critical to overdamped regime in the heavy-fermion system USn3.

We report measurements of the 119Sn nuclear spin-echo decay rate 1/T2G in the heavy-fermion compound USn3. From 1/T2G, the magnetic spin-spin correlation length xi is found to vary as xi approximately T(-3/4) above approximately 100 K, which is expected for a quantum critical regime at high temperatures. Combined with the spin-lattice relaxation rate 1/T1, T1T/T2G2 is found to be temperature independent in the heavy-fermion state below T* approximately 30 K. This indicates that the heavy-fermion state of USn3 is categorized in the overdamped regime with a dynamical critical exponent z=2. These observations are consistent with a spin density wave magnetic instability at the quantum critical point.

Unconventional superconductivity of NpPd(5)Al(2).

The high quality single crystals of NpPd(5)Al(2) with the body-centered tetragonal structure were grown by the Pb flux method. NpPd(5)Al(2) was found to be the first Np-based heavy fermion superconductor with the relatively high critical temperature T(sc) = 4.9 K. The upper critical field H(c2) is large and highly anisotropic. Corresponding to the heavy electronic state, the initial slope of H(c2) is large, but H(c2) at low temperatures is suppressed by the magnetic field, indicating a strong Pauli paramagnetic effect and the first-order transition at H(c2). These results imply that NpPd(5)Al(2) is located at the proximity of the antiferromagnetic ordering, which might be hidden by the superconductivity. The d-wave superconductivity with a spin singlet state is most likely realized in NpPd(5)Al(2).

Flux line lattice melting and the formation of a coherent quasiparticle Bloch state in the ultraclean URu2Si2 superconductor.

We find that in the ultraclean heavy-fermion superconductor URu(2)Si(2) (T_{c0}=1.45 K) a distinct flux line lattice melting transition with outstanding characters occurs well below the mean-field upper critical fields. We show that a very small number of carriers with heavy mass in this system results in exceptionally large thermal fluctuations even at sub-Kelvin temperatures, which are witnessed by a sizable region of the flux line liquid phase. The uniqueness is further highlighted by an enhancement of the quasiparticle mean free path below the melting transition, implying a possible formation of a quasiparticle Bloch state in the periodic flux line lattice.

Exotic superconducting properties in the electron-hole-compensated heavy-fermion "Semimetal" URu2Si2.

We show that the charge and thermal transport measurements on ultraclean crystals of URu2Si2 reveal a number of unprecedented superconducting properties. The uniqueness is best highlighted by the peculiar field dependence of thermal conductivity including the first-order transition at Hc2 with a reduction of entropy flow. This is a consequence of multiband superconductivity with compensated electronic structure in the hidden order state of this system. We provide strong evidence for a new type of unconventional superconductivity with two distinct gaps having different nodal topology.

Evidence for a novel state of superconductivity in noncentrosymmetric CePt3Si: a 195Pt-NMR study.

We report on novel antiferromagnetic (AFM) and superconducting (SC) properties of noncentrosymmetric CePt3Si through measurements of the 195Pt nuclear spin-lattice relaxation rate 1/T(1). In the normal state, the temperature (T) dependence of 1/T(1) unraveled the existence of low-lying levels in crystal-electric-field multiplets and the formation of a heavy-fermion (HF) state. The coexistence of AFM and SC phases that emerge at T(N)=2.2 K and T(c)=0.75 K, respectively, takes place on a microscopic level. CePt3Si is the first HF superconductor that reveals a peak in 1/T(1) just below T(c) and, additionally, does not follow the T3 law that used to be reported for most unconventional HF superconductors. We remark that this unexpected SC characteristic may be related to the lack of an inversion center in its crystal structure.