RESUMO
We report a K2CaPO4F:Eu2+ phosphor with a new crystal structure. This phosphor has a large Stokes shift and converts near-ultraviolet light to red luminescence without absorption of other visible light. The mechanism was elucidated by applying a constrained density functional theory to the solved crystal structure.
RESUMO
The 1111-type iron-based superconductor LnFeAsO(1-x)Fx (Ln stands for lanthanide) is the first material with a Tc above 50 K, other than cuprate superconductors. Electron doping into LaFeAsO by H, rather than F, revealed a double-dome-shaped Tc-x diagram, with a first dome (SC1, 0.05
RESUMO
We studied double superconducting (SC) domes in LaFeAsO(1-x)H(x) by using 75As and 1H nuclear-magnetic-resonance techniques and unexpectedly discovered that a new antiferromagnetic (AF) phase follows the double SC domes on further H doping, forming a symmetric alignment of AF and SC phases in the electronic phase diagram. We demonstrated that the new AF ordering originates from the nesting between electron pockets, unlike the nesting between electron and hole pockets, as seen in the majority of undoped pnictides. The new AF ordering is derived from the features common to high-Tc pnictides; however, it has not been reported so far for other high-Tc pnictides because of their poor electron doping capability.
RESUMO
The presence of a macroscopic phase separation between the superconducting and magnetic phases in CaFe1-xCoxAsF is demonstrated by muon spin rotation measurements conducted across their phase boundaries (x=0.05-0.15). The magnetic phase tends to retain the high transition temperature (Tm>Tc), while Co doping induces strong randomness. The volumetric fraction of the superconducting phase is nearly proportional to the Co content x with a constant superfluid density. These observations suggest the formation of superconducting "islands" (or domains) associated with Co ions in the Fe2As2 layers, indicating a very short coherence length.
