hcp-Co Nanowires Grown on Metallic Foams as Catalysts for Fischer-Tropsch Synthesis.

The Fischer-Tropsch synthesis (FTS) is a structure-sensitive exothermic reaction that enables catalytic transformation of syngas to high quality liquid fuels. Now, monolithic cobalt-based heterogeneous catalysts were elaborated through a wet chemistry approach that allows control over nanocrystal shape and crystallographic phase, while at the same time enables heat management. Copper and nickel foams have been employed as supports for the epitaxial growth of hcp-Co nanowires directly from a solution containing a coordination compound of cobalt and stabilizing ligands. The Co/Cufoam catalyst was tested for Fischer-Tropsch synthesis in a fixed-bed reactor, showing stability and significantly superior activity and selectivity towards C5+ compared to a Co/SiO2 -Al2 O3 reference catalyst under the same conditions.

Isopropanol Dehydration on Amorphous Silica-Alumina: Synergy of Brønsted and Lewis Acidities at Pseudo-Bridging Silanols.

The mechanism of isopropanol dehydration on amorphous silica-alumina (ASA) was unraveled by a combination of experimental kinetic measurements and periodic density functional theory (DFT) calculations. We show that pseudo-bridging silanols (PBS-Al) are the most likely active sites owing to the synergy between the Brønsted and Lewis acidic properties of these sites, which facilitates the activation of alcohol hydroxy groups as leaving groups. Isopropanol dehydration was used to specifically investigate these PBS-Al sites, whose density was estimated to be about 10-1  site nm-2 on the silica-doped alumina surface under investigation, by combining information from experiments and theoretical calculations.