Sustainable nano-sodium silicate and silver nitrate impregnated locally made ceramic filters for point-of-use water treatments in sub-Sahara African households.

The poor access to water quality for Nigerians has pushed for the designing of new trend silver nitrate impregnated locally made Point-Of-Use (POU) ceramic filters to enhance water purification efficiency for household use. This study utilized silver nitrate-molded ceramic filters prepared with Kaolin from Owode, silt soil, sodium silicate, sawdust, and distilled water in three varying proportions to ascertain pollution removal efficiencies. Heating was carried out by firing the filters at 900 °C and further preheating at 400 °C after dipping in silver nitrate solution. Silver nanoparticle and dissociated particle discharge from filter pot painted with 0.03 mg/g casein-covered nAg or AgNO3 were estimated as an element of pH (5-9), ionic strength (1-50mM), and cation species (Na+, Ca2+, Mg2+). Silver delivery was constrained by disintegration as Ag+ and resulting cation exchange measures, paying little heed to silver structure applied. Water analysis for both heavy metals (Pb and Cd) and microbial load (E. coli) evaluated, corroborate the maximum removal efficiency. It was observed that kaolin-sawdust with the Silver nitrate filters showed a constant and effective removal of both heavy metals and disinfection of microbial loads. The minimum flow rates observed were 4.97 mL/min for batch filter used for Iju River water sample one (AF1) and 4.98 mL/min for batch filter used for Iju River water sample two (AF2) having porosity 49.05% and 50.00%, whereas the 5 mL/min higher flow rate was used for batch filter from borehole water sample one (BF1) and batch filter used for well water sample two (CF2) with porosity of 50.00%. Significantly, the results obtained show that the filters are suitable for point-of-use application in both the urban and rural areas of developing countries such as Nigeria.

MEASUREMENTS OF SEASONAL VARIATIONS OF RADIOACTIVITY DISTRIBUTIONS IN RIVERINE SOIL SEDIMENT OF ADO-ODO OTA, SOUTH-WEST NIGERIA: PROBABILISTIC APPROACH USING MONTE CARLO.

The radioactivity levels were measured using a hand-held gamma-ray survey meter and NaI (Tl) based gamma spectroscopy to evaluate the seasonal variation of radioactivity levels in the riverine area of Ado-Odo Ota. The measured iso-dose map reported higher gamma dose rate of 79 nGy/h, approximately 34% higher than the world average of 59 nGy/h. The values for U-238, Th-232 and K-40 activity levels ranged between 29.9 and 21.6; 103.2 and 31.2; 802.2 and 233.5 with mean values of 26.1, 55.6 and 499.3 Bq/kg, respectively. According to the mean, 5th and 95th percentiles of the probabilities using the Monte Carlo simulation, the Radium equivalent activities and the absorbed dose rates are within their respective recommended limits of 370 Bq/kg and 84 nGy/h. This study could be used to monitor dose rates and radiological risks for the areas covering the small area (Ado-Odo Ota) to the larger area (West African Region) as baseline data.

Spatial distribution of gamma radiation dose rates from natural radionuclides and its radiological hazards in sediments along river Iju, Ogun state Nigeria.

This study assessed the radioactivity level of Iju River sediments and its associated radiological risks exposure to human. Gamma absorbed dose rates were measured using a portable gamma spectrometer at an interval of 50 m between each point (Model No:RS-125 manufactured by Canadian Geophysical Institute). The measured absorbed gamma dose rates range from 22 to 59 nGy/h with the highest value noted in site 13. The mean activity concentrations of U-238, Th-232 and K-40 from Iju river sediments were 24.1 ± 0.4 Bq/kg, 35.2 ± 1.1 Bq/kg and 501.0 ± 11.1 Bq/kg, which were lower than the world average values of 32 and 45 for U-238 and Th-232 by 25% and 21% and higher than 412 Bq/kg for K-40 by a factor of 0.22 (22%).•This highest value of K-40 found in site 6 may be due to the presence of feldspartic minerals buried in the sediments.•Consequently, the radiological hazard indices were below the permissible limits except the mean value of 28 × 10-2 for excess lifetime cancer risk (ELCR) for the samples collected in site 6, which is higher than the average world value of 0.29 × 10-3 by a factor of 0.03.•The regression model indicates that Th-232 attributes more radioactivity impacts on the soil sediments than the contributions of U-232 and K-40, as such, presumed to be the radionuclide parameter controlling the depositional process in the region.

A STUDY OF NATURAL RADIOACTIVITY IN SOME BUILDING MATERIALS IN NIGERIA.

Building materials of different brands were assessed for the concentrations of 226Ra, 232Th and 40K using HPGe detector. The activity concentrations in the measured samples ranged from 27 ± 8 to 82 ± 8 Bq kg-1 for 226Ra, 41 ± 4 to 101 ± 8 Bq kg-1 for 232Th and 140 ± 8 to 940 ± 19 Bq kg-1 for 40K, respectively. The Radium equivalent (Raeq) activity from the samples was found to be <370 Bq kg-1 as the recommended value for construction materials. This study will set a baseline data for significant standards on radiation exposure of the measured radionuclides in the selected building materials used in Nigeria.

Measurement of ²³8U,²³²Th and 4°K in boreholes at Gosa and Lugbe, Abuja, north central Nigeria.

The purpose of this project is to evaluate the suitability of different sites as locations for obtaining underground water for consumption. The analysis of ²³8U, ²³²Th and 4°K from rock samples from each layer of borehole at a depth of ∼50 m at Site A borehole, S3L1-S3L6 in Gosa and 40 m at Site B borehole, S4L1-S4L5 in Lugbe, Abuja, north central Nigeria is presented. The gamma-ray spectrometry was carried out using a high-purity germanium detector coupled to a computer-based high-resolution multichannel analyzer. The activity concentrations at Site A borehole for ²³8U have a mean value of 26 ± 3, ranging from 23 ± 2 to 30 ± 3 Bq kg⁻¹, ²³²Th a mean value of 63 ± 5, ranging from 48 ± 4 to 76 ± 6 Bq kg⁻¹ and 4°K a mean value of 573 ± 72, ranging from 437 ± 56 to 821 ± 60 Bq kg⁻¹. The activity concentrations at Site B borehole for ²³8U have a mean value of 20 ± 2, ranging from 16 ± 2 to 23 ± 2 Bq kg⁻¹, ²³²Th a mean value of 46 ± 4, ranging from 43 ± 4 to 49 ± 4 Bq kg⁻¹, 4°K a mean value of 915 ± 116 and ranging from 817 ± 103 Bq kg⁻¹ to 1011 ± 128 Bq kg⁻¹. It is noted that the higher activity concentrations of ²³²Th and ²³8U are found in Site A at Gosa. Site B has lower radioactivity, and it is recommended that both sites are suitable for underground water consumption.