Development of sustainable strontium ferrite graphene nanocomposite for highly effective catalysis and antimicrobial activity.

Graphene oxide (GO) has layered structure with carbon atoms that are highly coated with oxygen-containing groups, increasing the interlayer distance while simultaneously making hydrophilic atomic-thick layers. It is exfoliated sheets that only have one or a few layers of carbon atoms. In our work, Strontium Ferrite Graphene Composite (SF@GOC) has been synthesized and thoroughly characterized by physico-chemical methods like XRD, FTIR, SEM-EDX, TEM, AFM, TGA and Nitrogen adsorption desorption analysis. A very few catalysts have been manufactured so far that are capable of degrading Eosin-Y and Orange (II) dyes in water by heterogeneous catalytic method. The current study offers an overview of the recyclable nanocomposite SF@GOC used in mild reaction conditions to breakdown the hazardous water pollutant dyes Eosin-Y (96.2%) and Orange (II) (98.7%). The leaching experiment has demonstrated that the use of the transition metals strontium and iron have not result in any secondary contamination. Moreover, antibacterial and antifungal assay have been investigated. SF@GOC has shown greater activity with bacterial and fungal species while compared with GO. FESEM analysis shows that the bactericidal mechanism for SF@GOC is same in both gram-negative bacteria. The difference in the antifungal activity among the candida strains can be correlated with the movement of ions release (slower and faster) of synthesized nanoscrolls in SF@GOC. In comparison to previous reports, this new environmentally safe and novel catalyst showed substantial degrading activity. It can also be applied to new multifunctional processes such as in the fields of composite materials, solar energy, heterogeneous catalysis and biomedical applications.

Development of a Sustainable Tungsten and Iron Bimetal-Immobilized SBA-15 Composite for Enhanced Wet Catalytic Oxidation of Dye Capacity.

In this study, wet catalytic decomposition of Orange (II) dye was carried out with tungsten and iron bimetal-incorporated mesoporous SBA-15 (W-Fe@SBA-15) under visible light. The synthesized hybrid composite material was characterized by physicochemical methods, powder X-ray diffraction (PXRD) spectroscopy, scanning electron microscopy combined with energy-dispersive X-ray (SEM-EDX) spectroscopy studies, Fourier transform infrared (FT-IR) spectroscopy, transmission electron microscopy (TEM), atomic force microscopy (AFM), thermogravimetric analysis (TGA), and surface property studies to understand the nature of the dye degradation process and for catalytic studies. The maximum degradation of Orange (II) dye measured by a UV-visible spectrophotometer was 99% at a contaminant volume of 2.7 × 10-4 mol/L and a catalyst quantity of 2 g/L in 140 min reaction time. Using gas chromatography-mass spectrometry (GC-MS), the final products were chemically identified. The mechanistic steps of the process were carried out through a series of experiments. The recyclability of the catalyst added a novel feature for such a heterogeneous catalysis that can reduce secondary pollutants in water with no leaching effect observed.

A Sustainable Nanocomposite Au(Salen)@CC for Catalytic Degradation of Eosin Y and Chromotrope 2R Dyes.

Up to now, a very few catalysts have been developed approaching the heterogeneous catalytic degradation of Eosin Y and Chromotrope 2R dyes (Acid Red 29). The present study provides a complete perspective of recyclable nanocomposite Au(Salen)@CC for catalytic degradation of hazardous water pollutant dyes viz., Eosin Y & Chromotrope 2R using mild reaction conditions. New gold Salen complex doped carbon nanocomposite Au(Salen)@CC was developed by easy methodology using nano carbon cage (CC) prepared from low-priced Pyrolysis fuel oil (PFO) residue based Pitch. The UV-Vis adsorption spectroscopy results of Eosin Y and Chromotrope 2R dyes indicated complete degradation into acidic compounds which can be further mineralized to CO2 and H2O under mild reaction conditions. The heterogeneous catalyst recycled and reused successfully for four repeated experiments without loss in its adequate performance. This new sustainable and eco-friendly catalyst delivered significant degradation activity compared to existing reports and it can be further utilized for new multifunctional applications such as, radiopharmaceutical activities, heterogeneous catalysis and chiral resolution.

Enantiomer self-disproportionation and chiral stationary phase based selective chiral separation of organic compounds.

In modern chromatography, chiral stationary phase (CSP) and enantiomer self-disproportionation (ESD) are new inventions of packing material offer a guarantee for a successful enantiomeric separation. All CSPs were synthesized by chemical bonding of the relevant organic moieties onto a porous parent silica material for the separation of various racemic mixtures whereas achiral silica matrix was used for separation of non-racemic mixtures in ESD. Our present study provides to establish an understanding on the entire enantio-selective profile of amino alcohol based CSP as well as ESD and their precise utilization for high success rates for selective enantiomer separation with its appropriateness.