Removal of lead ions (Pb2+) from water and wastewater: a review on the low-cost adsorbents.

The presence of lead compounds in the environment is an issue. In particular, supply water consumption has been reported to be a significant source of human exposure to lead compounds, which can pose an elevated risk to humans. Due to its toxicity, the International Agency for Research on Cancer and the US Environmental Protection Agency (USEPA) have classified lead (Pb) and its compounds as probable human carcinogens. The European Community Directive and World Health Organization have set the maximum acceptable lead limits in tap water as 10 µg/L. The USEPA has a guideline value of 15 µg/L in drinking water. Removal of lead ions from water and wastewater is of great importance from regulatory and health perspectives. To date, several hundred publications have been reported on the removal of lead ions from an aqueous solution. This study reviewed the research findings on the low-cost removal of lead ions using different types of adsorbents. The research achievements to date and the limitations were investigated. Different types of adsorbents were compared with respect to adsorption capacity, removal performances, sorbent dose, optimum pH, temperature, initial concentration, and contact time. The best adsorbents and the scopes of improvements were identified. The adsorption capacity of natural materials, industrial byproducts, agricultural waste, forest waste, and biotechnology-based adsorbents were in the ranges of 0.8-333.3 mg/g, 2.5-524.0 mg/g, 0.7-2079 mg/g, 0.4-769.2 mg/g, and 7.6-526.0 mg/g, respectively. The removal efficiency for these adsorbents was in the range of 13.6-100%. Future research to improve these adsorbents might assist in developing low-cost adsorbents for mass-scale applications.

Removal of Pb2+ from water using the carbon nanotube-g-poly[(sodium methacrylate)-co- 2-(methacryloyloxy)ethyl acetoacetate]: experimental investigation and modeling.

A solid polymer, poly[(sodium methacrylate)-co-2-(methacryloyloxy)ethyl acetoacetate], p(MAA-co-MEAA) was synthesized and then grafted onto carbon nanotubes to prepare poly(MAA-co-MEAA)-grafted carbon nanotubes [CNT-g-p(MAA-co-MEAA)]. NMR, TGA, and FT-IR characterized the synthesized polymers and adsorbents. SEM-EDX was used to investigate the surface characteristics of the adsorbents. Pb2+ was removed from the aqueous solution using the CNT-g-p(MAA-co-MEAA). A batch adsorption experiment was performed at different Pb2+ concentrations (1, 10, 25, 50 mg/L), pH (4 and 6.75), temperature (25 and 35 °C), and contact periods (1, 5, 20, 60, and 1440 min) to study the adsorption kinetics and isotherm. The adsorbent dose of 2.5 g/L could effectively lower the initial Pb2+ concentration of 1000 to 2 ppb. The maximum adsorption capacity of the adsorbent was found to be 1178 mg/g. In addition, the adsorbents have been shown to effectively reduce the coexisting metal ion concentrations from industrial wastewater, which indicated the potential of the proposed adsorbent in removing metal ions from coexisting metals containing wastewater. To predict the adsorption efficiency of Pb2+, various linear, non-linear, and neural network models were established. An additional data set, not incorporated in model training, was used to validate the models. A number of models showed excellent performance with R2 in the range of 0.89-0.98. In model validation studies, the correlation coefficients (r) ranged from 0.94 to 0.99. The novel adsorbent and models will most likely aid in the development of a robust treatment technique for removing Pb2+ ions from water and wastewater.

Thermal energy storage and thermal conductivity properties of fatty acid/fatty acid-grafted-CNTs and fatty acid/CNTs as novel composite phase change materials.

In recent year, fatty acids (FAs) are heavily studied for heat storage applications and they have shown promising advantages over other organic phase change materials (PCMs). Among the FAs; capric, palmitic and stearic acids are the most studied PCMs. Several researchers have investigated these FAs and tried to improve their thermal properties, mainly by adding different high conducting fillers, such as graphite, metal foams, CNTs, graphene etc. In most cases, these fillers improved the thermal conductivity and heat transfer property but reduce the heat storage capacity considerably. These composites also lose the mixing uniformity during the charging and discharging process. To overcome these issues, selected FAs were grafted on the functionalized CNT surfaces and used as conductive fillers to prepare FA based composite PCMs. This process significantly contributed to prevent the drastic reduction of the overall heat storage capacity and also showed better dispersion in both solid and liquid state. Thermal cycling test showed the variations in the thermal energy storage values of all composite PCMs, however, within the tolerable grade and they had appreciable phase change stability and good chemical stability even after 2,000 cycles.

Predicting risk and loss of disability-adjusted life years (DALY) from selected disinfection byproducts in multiple water supply sources in Saudi Arabia.

Disinfection byproducts (DBPs) in drinking water is an issue in many countries. Many DBPs are possible or probable human carcinogens while few DBPs pose cyto- and genotoxic effects to the mammalian cells. The populations are likely to consume DBPs with drinking water throughout their lifetimes. A number of DBPs are regulated in many countries to protect humans. In this study, human exposure, risk and disability-adjusted life years (DALY) were predicted from DBPs in multiple water supply systems, including groundwater (GW), desalinated water (DW) and blend water (BW). The averages of lifetime excess cancer risks from GW, DW and BW were 4.15 × 10-6, 1.75 × 10-5 and 2.59 × 10-5 respectively. The populations in age groups of 0 - <2, 2-16 and >16 years contributed 25.4-25.7%, 28.6-29.6% and 45.0-45.7% to the total risks respectively. The DALY from GW, DW and BW were estimated to be 5.8, 27.0 and 39.9 years, respectively while the corresponding financial burdens were US$ 0.63, 2.93 and 4.34 million respectively. The findings are likely to assist in selecting the supply water sources to better control human exposure and risk from DBPs.

Thermal energy storage and thermal conductivity properties of Octadecanol-MWCNT composite PCMs as promising organic heat storage materials.

Fatty alcohols have been identified as promising organic phase change materials (PCMs) for thermal energy storage, because of their suitable temperature range, nontoxicity and can be obtained from both natural and synthetic sources. Like all other organic PCMs, octadecanol (OD) as PCM suffers from low thermal conductivity (TC). In this work, to enhance its TC, it was grafted on the functionalized MWCNT and were used as a conductive filler to enhance overall thermal properties of OD in a composite PCM (CPCMs) structure. The OD/OD-g-MWCNT sample showed better dispersion within the composites and the presence of additional OD boosted the overall heat storage enthalpy compared to that of plane composite sample with OD/MWCNT. In a non-quantitative approach, it was observed that, any increase in grafting ratio of OD increases the heat storage enthalpy of the composites. The heat storage enthalpy of (267.7 J/g) OD/OD-g-MWCNT(4:1)-5wt% composite PCM had reached very close to the heat storage enthalpy value of pure OD (269.3 J/g), and much higher than that of OD/MWCNT-5wt% (234.5 J/g). Champion sample i.e. OD/OD-g-MWCNT (4:1)-5wt%, showed good heat storage enthalpy, cycling performance, thermal stability and TC enhancement by 262.5%.

Water-Erodible Xanthan-Acrylate-Polyurethane Antifouling Coating.

Biopolymer xanthan (Xn) and its functionalized polymer xanthan acrylate (XnAc) were used to improve the antifouling properties of synthesized waterborne polyurethane (WBPU) coatings, namely, WBPU-Xn and WBPU-XnAc. XnAc was synthesized by functionalization of xanthan (Xn) using polyacrylic acid. Coating hydrophilicity, adhesive strength, and erosion all varied with the Xn and XnAc contents. A moderate erosion rate was recorded only for the WBPU-XnAc coating. A good antifouling property for longer time was found in the WBPU-XnAc coating using zinc pyrithione as a biocide in the field test.

Reduction of DBPs in synthetic water by indoor techniques and its implications on exposure and health risk.

Disinfection byproducts (DBPs) in municipal supply water have been a concern. Many DBPs have been characterized as possible and probable human carcinogens, which can pose elevated cancer risks through lifetime exposure to municipal supply water. Few DBPs are regulated in many countries to control human exposure and risk from DBPs. In risk assessment studies, concentration of DBPs in water distribution systems is often used, whereas populations are typically exposed to indoor tap water. Through employing several techniques, DBPs can be reduced prior to water consumption, which is likely to reduce human exposure and risk of DBPs. This study investigated six indoor techniques in reducing trihalomethanes (THMs) and haloacetic acids (HAAs) in synthetic water and the effects of these techniques on exposure and risk. The techniques are: S1, S2: storing water in a refrigerator with and without lids respectively; S3, S4: boiling water for 1 min followed by storing in a refrigerator with and without lids respectively; S5, S6: filtering water using new and used granular activated carbon (GAC) filters and storing in a refrigerator without lids. Storing of water (S1, S2) reduced THMs in the range of 14.8-47.2% while boiling (S3, S4) and filtration (S5, S6) reduced THMs in the range of 77.3-92.8%. In S1-S4 techniques, HAAs were not reduced significantly while in S5 - S6 techniques, HAAs were reduced in the range of 64.7-69.8%. In S3-S6 techniques, overall cancer and non-cancer risks were reduced by 45.5-82.6% and 26.3-80.0% respectively. The findings might prove useful in understanding DBPs exposure, associated risks, strategies to minimize exposure to these contaminants and updating regulatory guidelines for better protection of health risks from DBPs.

Highly porous carboxylated activated carbon from jute stick for removal of Pb2+ from aqueous solution.

Drinking water is a potential source of human exposure to lead (Pb2+), which can induce several health effects upon exposure to low dose for a long period. In particular, the children and young populations are the vulnerable groups. Removal of Pb2+ from drinking water using an inexpensive adsorbent is a challenge. In this research, activated carbon adsorbent was developed using jute stick, an agricultural by-product. Following carboxylic acid functionalization, the jute stick activated carbon (JSAC) was applied for Pb2+ removal from aqueous solution. The carboxylated JSAC (JSAC-COO-) was characterized using several techniques. The surface area of the JSAC-COO- was 615.3 m2/g. The JSAC-COO- was tested for variable concentrations of Pb2+ (10 and 25 mg/L) at different pH (4.0 and 7.0), temperature (15 °C and 27 °C), and contact periods (1, 5, 10, 15, 30, and 60 min). Up to 99.8% removal of Pb2+ was achieved for these concentrations of Pb2+ within 15 min of contact time. The adsorption process followed standard kinetics, and the adsorption capacity was > 25.0 mg Pb2+/g of JSAC-COO-. The JSAC-COO- can be used for fast and easy removal of Pb2+ from aqueous solution, which has the potential for domestic and industrial applications.

Modeling lead concentration in drinking water of residential plumbing pipes and hot water tanks.

Drinking water is a potential source of exposure to lead (Pb), which can pose risk to humans. The regulatory agencies often monitor Pb in water treatment plants (WTP) and/or water distribution systems (WDS). However, people are exposed to tap water inside the house while water may stay in the plumbing premise for several hours prior to reaching the tap. Depending on stagnation period and plumbing premise, concentrations of Pb in tap water can be significantly higher than the WDS leading to higher intake of Pb than the values from WDS or WTP. In this study, concentrations of Pb and water quality parameters were investigated in WDS, plumbing pipe (PP) and hot water tanks (HWT) for 7months. The samples were collected and analyzed on bi-weekly basis for 7 times a day. Several linear, non-linear and neural network models were developed for predicting Pb in PP and HWT. The models were validated using the additional data, which were not used for model development. The concentrations of Pb in PP and HWT were 1-1.17 and 1-1.21 times the Pb in WDS respectively. Concentrations of Pb were higher in summer than winter. The models showed moderate to excellent performance (R2=0.85-0.99) in predicting Pb in PP and HWT. The correlation coefficients (r) with the validation data were in the ranges of 0.76-0.90 and 0.97-0.99 for PP and HWT respectively. The models can be used for predicting Pb in tap water, which can assist to better protect the humans.

Andrographolide engineered gold nanoparticle to overcome drug resistant visceral leishmaniasis.

Visceral leishmaniasis (VL) is World Health Organization designated most serious leishmaniasis with an annual mortality rate of 50,000. Even after country specific eradication programs, the disease continues to multiply with added complexities like resistance development, drug hypersensitivity and associated infections. Newer therapeutic interventions are urgently warranted to control the spread. Present study aims to arrive at terpenoid andrographolide engineered gold nanoparticle (AGAunps) facile synthesis and its efficacy evaluations against wild and drug resistant VL strains for the first time. Molecular bio-organic conjugation of AGAunp was confirmed in FT-IR and EDAX studies. Nano-gold plasmon response was recorded at 543 nm and the average size in TEM was 14 nm. SAED pattern and XRD observations proved fcc crystalline structure of nano-gold. AGAunp recorded spherical geometry in AFM and TEM. PDI value of 0.137 revealed the monodisperse nature of the nano-scale population. AGAunp exhibited strong antileishmanicidal effect both against wild type (IC50 19 ± 1.7 µM) and sodium stibogluconate (IC50 55 ± 7.3 µM)/paromomycin (IC50 41 ± 6 µM) resistant strains. Complete macrophage uptake AGAunp's occured within two hours exposure. AGAunp macrophage cytotoxicity was significantly lower as compared to Amphotericin-B. Low toxic Andrographolide engineered gold nanoparticle emerged as promising alternatives in the control of wild and drug resistant VL.