Assessment of phosphorus loading dynamics in a tropical reservoir with high seasonal water level changes.

Nutrient accumulation in man-made reservoirs has been documented worldwide. Therefore, quantifying phosphorus loading and understanding its temporal dynamics in reservoirs is mandatory for sustainable water management. In this study, the Vollenweider's complete-mix phosphorus budget model was adapted to account for high water level variations, which are a common feature in tropical reservoirs, and for internal phosphorus loads. First- and zero-order kinetics were adopted to simulate phosphorus settling and release from the sediment layer, respectively, considering variable area of phosphorus release according to the height of the anoxic layer. The modeling approach was applied for a 52-months period to a 31-years-old reservoir located in the semiarid region of Brazil with 7.7 hm3 storage capacity. The simulations were supported by hydrological, meteorological and water quality data, as well as analyses of phosphorus partitioning of the reservoir bed sediment. The external phosphorus load was estimated from a relationship adjusted between inflow and phosphorus concentration, revealing an u-shaped pattern. Sedimentary phosphorus linked to iron and aluminum (PFeAl) increased over time and along the reservoir. Such measurements were used to estimate the internal phosphorus load, i.e., the yield from the bed sediments to the water column. The adaptations proposed to the model's structure improved its capacity to simulate phosphorus concentration in the water column, from "not satisfactory" to "good". We estimate that the internal phosphorus load currently accounts for 44% of the total load. It prevailed during the wet period, when reservoir stratification and hypolimnetic hypoxia were more notable, resulting in higher phosphorus concentration in the water column due to the combined effects of internal and external loadings. However, if the reservoir were 70 years older, the internal load would reach 83% of the total and the reservoir would become a source instead of a sink of phosphorus.

Modelling the impact of sediment management on the trophic state of a tropical reservoir with high water storage variations.

Eutrophication of lakes has affected society in many regions, particularly in water scarce environments where: i) low runoff reduces the self-purification potential of water bodies; ii) water supply relies on surface reservoirs, which are susceptible to nutrient enrichment. This work presents an assessment of the impact of the silted sediment management on the trophic status of a tropical surface reservoir with intense temporal variability of water storage. A complete mixing model describing the total phosphorus budget in the water and sediments was used, based on semi-empirical formulations. The sediment reuse as soil fertilizer has been proposed to increase productivity in small scale agriculture, which should also enhance the water quality by removing the nutrient-enriched sediment from lakes. Model application for a 40-years period indicate that sediment management may improve water quality, changing from poor to acceptable trophic state during roughly 10% of the time when the reservoir is not empty.