Infrared surface polaritons on antimony.

The semimetal antimony, with a plasma frequency ~80 times less than that of gold, is potentially useful as a host for infrared surface polaritons (SPs). Relevant IR SP properties, including the frequency-dependent propagation length and penetration depths for fields into the media on either side of the interface, were determined from optical constants measured on optically-thick thermally-evaporated Sb films over the wavelength range 1 to 40 µm. Plasma and carrier relaxation frequencies were determined from Drude-model fits to these data. The real part of the permittivity is negative for wavelengths beyond 11 µm. Distinct resonant decreases in specular reflected intensity were observed for Sb lamellar gratings in the wavelength range of 6 to 11 µm, where the real part of the permittivity is positive. Both resonance angles and the angular reflectance spectral line shapes are in agreement with theory for excitation of bound surface electromagnetic waves (SPs). Finite element method (FEM) electrodynamic simulations indicate the existence of SP modes under conditions matching the experiments. FEM results also show that such waves depend on having a significant imaginary part of the permittivity, as has been noted earlier for the case of surface exciton polaritons.

Long-wave infrared surface plasmon grating coupler.

We present a simplified analytic formula that may be used to design gratings intended to couple long-wave infrared radiation to surface plasmons. It is based on the theory of Hessel and Oliner (1965). The recipe is semiempirical, in that it requires knowledge of a surface-impedance modulation amplitude, which is found here as a function of the grating groove depth and the wavelength for silver lamellar gratings at CO(2) laser wavelengths. The optimum groove depth for photon-to-surface-plasmon energy conversion was found by experiment and calculation to be approximately 10%-15% of the wavelength. This value is about twice what has been reported previously in the visible spectral range for sinusoidal grating profiles.