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1.
Environ Sci Pollut Res Int ; 29(1): 1364-1374, 2022 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-34350580

RESUMO

The main objective of this research is to separate virgin polymers (PA, PC, PP, HDPE; PS, and ABS) and post-consumer plastic waste from municipal solid waste (MSW) using the sinking-flotation technique. Separation was carried out on a pilot scale in an 800-l useful volume container with 160 rpm agitation for one hour. Tap water, ethanol solutions, and sodium chloride at different concentrations were used as densification medium. Virgin polymers were separated into two groups: low-density (HDPE and PP) and high-density polymers groups (PS, ABS, PA, and PC). Polymers whose density was less than that of the medium solution floated to the surface, while those whose density was greater than those of the medium solution sank to the bottom. The experimental results showed that complete separation of HDPE from PP achieved 23% ethanol v/v, whereas high-density polymers separated up to 40% w/v sodium chloride. Polymer recovery ranged from 70 to 99.70%. In post-consumer recycled plastic waste, fractions of 29.6% polyolefins, 37.54% PS, 11% ABS, 8% PA, 12% PC PET, and PVC were obtained. Finally, cast plates were made of the post-consumer waste to properly identify the polymer type present in the separated fractions.


Assuntos
Plásticos , Eliminação de Resíduos , Polímeros , Reciclagem , Resíduos Sólidos
2.
Environ Sci Pollut Res Int ; 29(2): 2227-2243, 2022 Jan.
Artigo em Inglês | MEDLINE | ID: mdl-34363173

RESUMO

The objective of this research was to evaluate anaerobic co-digestion of guinea pig manure (GP) with Andean agricultural residues such as amaranth (AM), quinoa (QU) and wheat (TR) in batch biodigesters under mesophilic conditions (37 0C) for 40 days. As microbial inoculum, sewage treatment sludge was used in two inoculum/substrate ratios (ISR of 1 and 2). In terms of methane production, the best results occurred in treatments containing AM and QU as co-substrate and an ISR of 2. Thus, the highest methane production yield in the GP:AM biodigesters (25:75) and GP:QU (25:75) with 341.86 mlCH4/g VS added and 341.05 mlCH4/g VS added, respectively. On the other hand, the results showed that methane production with an ISR of 2 generated higher yields for guinea pig waste and the methane fraction of the biogas generated was in a range from 57 to 69%. Methane production kinetics from these raw materials was studied using five kinetic models: modified Gompertz, logistic equation, transfer, cone and Richards. The cone model adjusted best to the experimental values ​​with those observed with r2 of 0.999 and RMSE of 1.16 mlCH4/g VS added. Finally, the highest biodegradability (experimental yield/theoretical yield) was obtained in the GP-AM biodigesters (25:75) with 67.92%.


Assuntos
Reatores Biológicos , Esterco , Anaerobiose , Animais , Biocombustíveis/análise , Digestão , Cobaias , Lignina , Metano , Esgotos
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