Pore Structure Characteristics and Affecting Factors of Shale in the First Member of the Qingshankou Formation in the Gulong Sag, Songliao Basin.

A major historical breakthrough has been made in the exploration of the GK (the first member of the Qingshankou Formation (K2qn1), Gulong Sag) shale oil of the Songliao Basin. However, few reports have been reported on the pore structure characteristics of this large-scale lacustrine medium-high maturity shale. In addition, the difference between the pore structure characteristics of the GK shale and medium-low maturity marine/continental shale is unknown, and the affecting factors of pore development are still unclear. Therefore, in order to clarify the pore structure characteristics of the GK shale and its affecting factors, this study characterized them experimentally and revealed the law of pore evolution using the mineral composition and geochemical analysis, microscopic observations, and pore quantification techniques. Results indicate that (1) the pore system of GK shale reservoirs is divided into micropores (pore diameter < 10 nm), mesopores (10 nm < pore diameter < 50 nm), and macropores (pore diameter > 50 nm); (2) the pore structure of the GK shale is mainly affected by the clay content, siliceous mineral content, and thermal maturity; and (3) when the content of clay minerals and siliceous minerals in the GK shale reservoir is high, and ∼0.8% < R o < ∼1.4%, the storage capacity and oil content of the GK shale show high values, and it can be considered as a strong candidate for further exploration and development. This research can push the shale oil revolution to a new height and is significant to promote the development of the petroleum industry.

Generation of late Mesozoic felsic volcanic rocks in the Hailar Basin, northeastern China in response to overprinting of multiple tectonic regimes.

We performed zircon U-Pb age dating and geochemical analyses of late Mesozoic felsic volcanic rocks in the Hailar Basin, NE China, with the aim of eclucidating their emplacement ages, origin and geodynamic significance. The volcanic rocks consist of dacites, rhyolites and rhyolitic tuffs. Laser ablation-inductively coupled plasma-mass spectrometry zircon U-Pb dating results suggest that the rocks were erupted during the Late Jurassic-Early Cretaceous (161-117 Ma). They belong to the high-K calc-alkaline series and can be divided into two groups. Group I rocks are metaluminous to weakly peraluminous, contain low concentrations of heavy rare earth elements (HREEs) and high field strength elements (HFSEs), and have low zircon saturation temperatures (average 786 °C), all of which indicate an I-type affinity. In contrast, Group II rocks have higher HREE and HFSE concentrations and zircon saturation temperatures (average 918 °C), suggesting an A-type affinity. All the felsic volcanic rocks have positive εHf(t) values of 1.43-12.32 with two-stage model ages of 1110-401 Ma. Our data indicate that the I-type felsic volcanic rocks formed from magmas generated by partial melting of a dominantly juvenile mica-bearing K-rich basaltic lower crust, whereas the A-type felsic volcanic rocks originated from the partial melting of a dry mafic-intermediate middle-lower crust that was dehydrated but not melt depleted. Based on the present results and previous research, we propose that the Late Jurassic I- and A-type felsic volcanic rocks in the Hailar Basin were formed in a post-collisional environment related to break-off of the subducted oceanic slab of the Mongol-Okhotsk Ocean and the subsequent gravitational collapse of the orogenically-thickened crust after closure of the ocean. In contrast, the Early Cretaceous I- and A-type felsic volcanic rocks were erupted in an extensional setting related to rollback of the subducted Paleo-Pacific Plate.

A new sesquiterpene glycoside from Osmanthus fragrans var. aurantiacus / 药学学报

The chemical constituents were isolated and purified by column chromatography and semi-preparative reversed-phase high performance liquid chromatography with silica gel, MCI and polyamide in order to study the chemical constituents of dried flowers of Osmanthus fragrans var. aurantiacus. Their structures were identified by the physical and chemical properties and one-dimensional nuclear magnetic resonance (1H-, 13C-NMR, DEPT), two-dimensional nuclear magnetic resonance (1H-1H COSY, non-decoupled HSQC, HSQC, HMBC), UV, IR and high resolution mass spectrometry data. One new compound (1) and five known compounds (2-6) were isolated from 95% ethanol extract of dried broccoli. They were identified as (9S)-9-hydroxymengastigm-5-en-4-one-9-O-primeveroside (1), oleanolic acid (2), forsythiaside (3), 2-(4-hydroxyphenethyl)-ethanol-(6-acetyl)-β-D-glucopyranoside (4), salidroside (5), and acteoside (6). Compounds (2-6) were isolated from this plant for the first time.