Use of reverse osmosis as a polish for the cationic surfactant after electro-oxidative treatment: Acute and chronic toxicity assessment.

The main purpose of this work was to evaluate the performance of a commercial reverse osmosis (RO) membrane regarding selectivity (rejection) and productivity (permeate flux) of the treatment of quaternary ammonium compounds (QAC) after electro-Fenton (EF) treatment. Pollutants treated after the EF process should be investigated for ecotoxicity, since excess ions and high conductivity are harmful to aquatic and terrestrial biota. The use of the membrane system after EF treatment acts as final polishing since some electro-oxidative treatments leave the sample with high conductivity. In this study, RO was operated with a constant flow of 1 L min-1 and feed pressures of 1 MPa, 2 MPa and 3 MPa to reject ions (sodium and iron) and to decrease the level of toxicity using representative species from different taxonomic groups: freshwater algae (Pseudokirchneriella subcapitata), microcrustaceans (Daphnia similis) and lettuce seeds (Lactuca sativa). Experiments carried out at different pressures showed that increased pressure caused a rise in rejection and permeate flux. At the applied pressure of 3 MPa, after 180 min, conductivity removal efficiency of 83% was obtained, 85% for sodium and 99% for iron at a flow of 13.87 L/h m2. In all bioassays, the use of the membrane was efficient to decrease the toxicity by rejecting the ions. The microcrustacean tested was the most sensitive organism, while alga was the most tolerant organism. The germination of lettuce seeds and the relative growth rate of the radicle after the combined EF+RO process was satisfactory.

Oilfield water treatment by electrocoagulation-reverse osmosis for agricultural use: effects on germination and early growth characteristics of sunflower.

This study aims to evaluate the effects of oilfield water (OW), treated by a hybrid process of electrocoagulation and reverse osmosis (EC-RO), on seed germination and early growth characteristics of sunflower (Heliantus annus L.). In the EC step, tests were conducted with 28.6 A m-2 current density and 4 min. reaction time. In the RO step, the system was operated with 1 L min-1 constant flow and 2 MPa, 2.5 MPa and 3 MPa feed pressures. In all feed pressures, RO polymeric membranes achieved very high removals of chemical oxygen demand (up to 89%) and oils and greases (100%) from EC-treated effluent. In best feed pressure (2.5 MPa), turbidity, total dissolved salts, electrical conductivity, salinity, toxic ions and sodium adsorption ratio values attained internationally recognized standards for irrigation water. Using EC-RO (feed pressure:2.5 MPa) treated OW, germinated sunflower seeds percentage (86 ± 6%), speed of germination (30 ± 2) and biomass production (49 ± 5 mg) were statistically similar to control (distilled water) results. Vigor index average values obtained using OW treated by EC-RO (3871)were higher than that obtained by OW water treated by EC (3300). The results of this study indicate that EC-RO seems to be a promising alternative for treatment of OW aiming sunflower crops irrigation, since the use of this treated effluent did not affect adversely seed germination and seedling development, and improved seedling vigor. Furthermore, OW treatment by EC-RO reduces sodium levels into acceptable standards values avoiding soil degradation.

Effects of untreated and treated oilfield-produced water on seed germination, seedling development, and biomass production of sunflower (Helianthus annuus L.).

This study aims to evaluate possible toxic effects of oil and other contaminants from oilfield-produced water from oil exploration and production, on seed germination, and seedling development of sunflower (Helianthus annuus L.). In comparison, as treated by electroflocculation, oilfield-produced water, with lower oil and organic matter content, was also used. Electroflocculation treatment of oilfield-produced water achieved significant removals of chemical oxygen demand (COD) (94 %), oil and grease (O&G) (96 %), color (97 %), and turbidity (99 %). Different O&G, COD, and salt levels of untreated and treated oilfield-produced water did not influence germination process and seedling biomass production. Normal seedlings percentage and vigor tended to decrease more intensely in O&G and COD levels, higher than 337.5 mg L(-1) and 1321 mg O2 L(-1), respectively, using untreated oilfield-produced water. These results indicate that this industrial effluent must be treated, in order to not affect adversely seedling development. This way, electroflocculation treatment appears as an interesting alternative to removing oil and soluble organic matter in excess from oilfield-produced water improving sunflower's seedling development and providing a friendly environmental destination for this wastewater, reducing its potential to harm water resources, soil, and biota.