Enhanced Electrocatalytic Conversion of Nitrates to Ammonia: Fuel from Waste.

Ammonia (NH3) is globally one of the most produced chemicals. Despite being known for its use as a fuel and as a precursor of multiple chemicals, during its production, it is responsible for more than 1.2 % of the total global CO2 emission and consumes a large amount of energy. In this work, we studied a flow-through membrane-free electrocatalytic device (CMED) to produce continuous stream of NH3 from a common water contaminant, nitrate (NO3 -). Indium-palladium (In-Pd) nanoparticles were impregnated in activated carbon cloth (ACC) and used as a cathode in the electrochemical device. It is found that in the counter electrode, adding oxygen evolution reaction (OER) active catalysts like platinum (Pt) for the regeneration of hydrogen ions enhances the rate of ammonia conversion to 7.28 µmol min-1 cm-2, eliminate the production of toxic nitrite by-products, as well as provide a platform for a stable energy consumption over long periods of time. This method for the conversion of NO3 - into NH3 promises a way forward for sustainable resource utilization while generating fuel from waste and contributing to future circular economies, and managing the nitrogen cycle in water that is a major challenge of the 21st century society.

ZnO Nanorods Coated Single-Mode-Multimode-Single-Mode Optical Fiber Sensor for VOC Biomarker Detection.

This work demonstrated a ZnO-coated optical fiber sensor for the detection of a volatile organic compound (VOC) biomarker for diabetes for detecting isopropanol (IPA) markers. A coreless silica fiber (CSF) was connected to a single-mode fiber (SMF) at both ends to achieve a SMF-CSF-SMF structure. CSF is the sensing region where multimode interference (MMI) generates higher light interaction at the interface between the fiber and sensing medium, leading to enhanced sensitivity. Optimization of the CSF length was conducted numerically to attain the highest possible coupling efficiency at the output. Surface functionalization was achieved via hydrothermal growth of ZnO nanorods directly onto the CSF at low temperatures. The optical fiber-based sensor was successfully fabricated and tested with 20%, 40%, 60%, 80%, and 100% of IPA. The sensor response was recorded using an optical spectrometer and analyzed for sensor sensitivity. The fabricated sensor shows the potential to detect isopropanol with the sensitivity of 0.053 nm/%IPA vapor. Further improvement of the sensor sensitivity and selectivity is also proposed for future work.