1.
Org Lett
; 24(1): 441-445, 2022 01 14.
Artigo
em Inglês
| MEDLINE
| ID: mdl-34905364
RESUMO
Robust air-stable cyclometalated π-allyliridium C,O-benzoates modified by (S)-tol-BINAP catalyze the reaction of secondary aliphatic amines with racemic alkyl-substituted allylic acetates to furnish products of allylic amination with high levels of enantioselectivity. Complete branched regioselectivities were observed despite the formation of more highly substituted C-N bonds.