Biogas production from the landfilled easily degradable fraction of municipal solid waste: mining strategy for energy recovery.

The growing demand for space and financial resources to manage current and new municipal solid waste (MSW) landfills has become a massive challenge for several countries. Additionally, landfills contribute to adverse environmental impacts such as pollution and CO2 (carbon dioxide) and CH4 (methane) emissions. This paper has analyzed the possibility of producing biogas from landfilled MSW. An easily degradable fraction of landfilled MSW with 8 years of landfilling was mined and subjected to chemical characterization and elemental composition analysis. The abbreviation for the study sample was called ED8 - Mined. The low values of lignin (24.5%) and nitrogen content (0.7%) and high values of holocellulose (75.9%) and C/N (46.1%) on dry basis were obtained resulting in materials with the potential to be used for biogas generation. Recalcitrant materials were found in greater amounts than easily biodegradable fresh MSW fractions. The reuse of energy from landfilled MSW can contribute positively to the country's environment and economy, reducing environmental liabilities and generating energy in a controlled way. In Delta A Sanitary Landfill, Southeastern Brazil, the recovery of the ED8 - Mined would reflect a significant recovery of about 100,000 tonnes of landfilled materials for annual MSW cells of about 450,000 tonnes, allowing recovery of materials and space expansion for rejects. Graphical abstract: fx1.

Study of a tropical soil in order to use it to retain aluminum, iron, manganese and fluoride from acid mine drainage.

The Ore Treatment Unit (UTM-Caldas), in the city of Caldas, Minas Gerais, Brazil, nowadays in decommissioning stage, was the first uranium extraction mine in Brazil. Several negative environmental impacts in the area have occurred, because of mining, treatment and beneficiation processes. Waste rock pile 4 (WRP-4) generates acid mine drainage (AMD), which is discharged in the Nestor Figueiredo retention pond (NFP). However, leakage of acid water by the NFP dam foundation has been constantly observed. Therefore, this research aimed to investigate a typical tropical soil, in order to use it as mineral liner for the NFP to minimize the leakage of acid water through the dam foundation and to retain predominant chemical species. Geotechnical, chemical and mineralogical tests were performed to characterize the soil and a column test was carried out using the acid mine drainage as contaminant, which contained aluminum (Al), manganese (Mn), iron (Fe) and fluoride (F-). The soil presented micro aggregation, acid pH, and low values of organic matter content and cation exchange capacity, which are characteristics of highly weathered soils. Diffusion was the predominant transport mechanism in the column test. Effluent solutions with pH less than 6.0 indicated the formation of insoluble Al-F complexes in the soil and desorption of iron and manganese at concentrations above those allowed by the Brazilian legislation. At pH greater than 6.0, the desorption of iron and manganese and release of aluminum and fluoride in the free form occurred, with concentrations also higher than the allowed by the Brazilian legislation.