Contamination, ecological risk and source identification of metals by multivariate analysis in surface sediments of the khouran Straits, the Persian Gulf.

Sediments are important hosts for metals and such should be incorporated in aquatic environment monitoring programs. In the present study, the concentrations of metals, multiple geochemical indices and guidelines along with multivariate statistical analysis were applied to identify the accumulation, sources and pollution levels of metals in the surface sediment. The mean metal concentrations in the sediments were ranked as follows: Fe > Cr > Ni > V > Zn > Cu > Pb > Cd. Based on the geo-accumulation index and multiple pollution indices the overall pattern of environmental quality status of the khouran Straits were uncontaminated to slightly polluted. Pearson correlation matrix combined with multivariate principal component analysis and cluster analysis suggest that Cd and Pb originated from anthropogenic sources, whereas Fe, Cu, Zn, Ni, V and Cr mostly originated both from natural processes and human activities with predominant anthropogenic influence in the investigated ecosystem.

Source identification of polycyclic aromatic hydrocarbons (PAHs) in sediment samples from the northern part of the Persian Gulf, Iran.

Samples of surface sediments from the Iranian coast of the Persian Gulf were examined to determine the levels and sources of 15 polycyclic aromatic hydrocarbons (PAHs). Samples were collected from 30 sampling sites and analyzed for PAHs by gas chromatography-mass spectrometry (GC-MS). Total concentrations of PAHs ranged from 93 to 4,077 ng g(-1) dry weight. The PAH composition from 30 sampling sites was dominated by four-ring PAH compounds. Molecular indices based on the ratios of PAH concentrations were used to differentiate PAHs from pyrolitic to petrogenic and mixed origins. The results suggested that the main sources of PAHs in sediments from the studied region were mixed pyrolitic and petrogenic. Furthermore, benthic organisms in most of the investigated areas were not at ecotoxicological risk, according to the results from the effects range low (ERL)/effects range median (ERM) techniques suggested by the US Sediment Quality Guidelines (SQGs).