Pilot-scale comparison of sodium silicates, orthophosphate and pH adjustment to reduce lead release from lead service lines.

Sodium silicate is thought to mitigate lead release via two mechanisms: by increasing pH and by forming a protective silica film. A pilot-scale study using an excavated lead service line (LSL) fed with water from a Great Lakes source was undertaken to: (1) clearly distinguish the pH effect and the silica effect; (2) compare sodium silicate to orthophosphate and pH adjustment; (3) determine the nature of silica accumulation in the pipe scale. The LSL was cut into segments and acclimated with water at pH 7.1. Median dissolved lead was 197 µg/L in the last 8 weeks of acclimation and dropped to 16 µg/L, 54 µg/L, and 85 µg/L following treatment with orthophosphate (dose: 2.6 mg-PO4/L, pH: 7.9), pH adjustment (pH: 7.9) and sodium silicate (dose: 20 mg-SiO2/L, pH: 7.9), respectively. When silica dose was increased from 20 mg-SiO2/L to 25 mg-SiO2/L (pH: 8.1), lead release destabilized and increased (median dissolved lead: 141 µg/L) due to formation of colloidal dispersions composed mainly of lead- and aluminum-rich phases as detected by field flow fractionation used with inductively coupled plasma mass spectrometry. Si was present in the scale at a maximum of 2.2 atomic % after 17 weeks of silica dosing at 20 mg- SiO2/L. Under the conditions tested, sodium silicate did not offer any benefits for reducing lead release from this LSL other than increasing pH. However, sodium silicate resulted in lower levels of biofilm accumulation on pipe walls, as measured by heterotrophic plate counts, when compared to orthophosphate.

Effect of sodium silicate on lead release from lead service lines.

The effect of sodium silicate addition on lead release from lead service lines (LSLs) was investigated using laboratory-based pipe loop experiments with LSLs harvested from a water utility that has one of the Great Lakes as its source water. The LSLs were first conditioned with a synthetic water similar to that of Buffalo Water that matched the major water chemistry that the pipes had experienced in the field; the one exception was the absence of dissolved organic carbon in the synthetic water. After conditioning, the LSLs were used in tests with the same synthetic water and with sodium silicate added to the water for half of the LSLs. In one test sodium silicate addition was performed with adjustment of the pH to maintain it at the same value (pH 7.7) as before addition. In this test sodium silicate effectively reduced the dissolved and particulate lead concentrations in the water within six weeks of treatment. Periodic assessments of the corrosion scales in the pipes found that sodium silicate accumulated throughout the scale thickness and gradually decreased the lead release. In the other test the pH was allowed to increase from 7.7 to 8.8 upon addition of 20 mg/L as SiO2 sodium silicates, and parallel control experiments were performed with the same pH increase made using sodium hydroxide addition. In these tests the lead concentrations decreased in both the silicate-treated and control pipes, and the decreases were not significantly different between the silicate-treated and control pipes.

Effect of Aluminum on Lead Release to Drinking Water from Scales of Corrosion Products.

The occurrence of aluminum in scales on lead pipes is common. This study aimed to identify factors that influence Al accumulation on oxidized lead surfaces and to determine whether the presence of Al impacts Pb release from corrosion products to water. Al accumulation and Pb release were monitored both with and without the addition of phosphate as a corrosion inhibitor. Pb coupons with corrosion scales were exposed to chlorinated water for up to 198 days to investigate Al accumulation and Pb release. Al accumulation was facilitated by Pb corrosion products, but its accumulation was inhibited by phosphate addition. During the study period, the formation of Al deposits did not affect Pb release when phosphate was absent. In an Al-free system, the addition of 1.0 mg/L phosphate (as P) lowered the dissolved Pb concentration below 1.0 µg/L. In a system containing 200 µg/L Al, the emergence of phosphate's effect on Pb control was delayed, and the dissolved Pb concentration decreased but stabilized at a higher value (10-12 µg/L) than in the Al-free system. Phosphohedyphane (Ca2Pb3(PO4)3Cl) was formed in all phosphate-containing systems, and PbO2 was formed independent of phosphate addition. The effect of Al on Pb release was probably related to its influence on the composition and morphology of Pb-containing minerals on coupon surfaces. The laboratory study has unavoidable limitations in its ability to simulate all conditions in real lead service lines, but this study still highlights the importance of considering the influence of Al when designing Pb corrosion control strategies.