1.
Angew Chem Int Ed Engl
; 57(37): 12146-12150, 2018 09 10.
Artigo
em Inglês
| MEDLINE
| ID: mdl-29738630
RESUMO
Within this work, a novel acylstannane-based photoinitiator (PI) is presented. Tetrakis(2,4,6-trimethylbenzoyl)stannane (1) displays outstanding properties compared to state-of-the-art acylgermane-based initiators. Most importantly, the initiator shows absorption up to 550â nm, which allows higher penetration depths, especially in highly filled photopolymers. Besides that, 1 shows extremely high photoinitiating activity towards (meth)acrylic double bonds, as well as very fast photobleaching. Furthermore, unlike many organotin compounds, 1 shows surprisingly low cytotoxicity.