Probing the ultimate limits of plasmonic enhancement.

Metals support surface plasmons at optical wavelengths and have the ability to localize light to subwavelength regions. The field enhancements that occur in these regions set the ultimate limitations on a wide range of nonlinear and quantum optical phenomena. We found that the dominant limiting factor is not the resistive loss of the metal, but rather the intrinsic nonlocality of its dielectric response. A semiclassical model of the electronic response of a metal places strict bounds on the ultimate field enhancement. To demonstrate the accuracy of this model, we studied optical scattering from gold nanoparticles spaced a few angstroms from a gold film. The bounds derived from the models and experiments impose limitations on all nanophotonic systems.

Broadband ground-plane cloak.

The possibility of cloaking an object from detection by electromagnetic waves has recently become a topic of considerable interest. The design of a cloak uses transformation optics, in which a conformal coordinate transformation is applied to Maxwell's equations to obtain a spatially distributed set of constitutive parameters that define the cloak. Here, we present an experimental realization of a cloak design that conceals a perturbation on a flat conducting plane, under which an object can be hidden. To match the complex spatial distribution of the required constitutive parameters, we constructed a metamaterial consisting of thousands of elements, the geometry of each element determined by an automated design process. The ground-plane cloak can be realized with the use of nonresonant metamaterial elements, resulting in a structure having a broad operational bandwidth (covering the range of 13 to 16 gigahertz in our experiment) and exhibiting extremely low loss. Our experimental results indicate that this type of cloak should scale well toward optical wavelengths.

Perfect metamaterial absorber.

We present the design for an absorbing metamaterial (MM) with near unity absorbance A(omega). Our structure consists of two MM resonators that couple separately to electric and magnetic fields so as to absorb all incident radiation within a single unit cell layer. We fabricate, characterize, and analyze a MM absorber with a slightly lower predicted A(omega) of 96%. Unlike conventional absorbers, our MM consists solely of metallic elements. The substrate can therefore be optimized for other parameters of interest. We experimentally demonstrate a peak A(omega) greater than 88% at 11.5 GHz.

Characterization of a planar artificial magnetic metamaterial surface.

We explore the electromagnetic characterization of a planar artificial magnetic metamaterial. Because the composite structure is two- rather than three-dimensional, it does not form a medium with assignable bulk properties, such as the electric permittivity and magnetic permeability. However, we find that it is possible to characterize the expected bulk response of a structure composed of repeated layers of metamaterial planes, from a reflectance measurement of a single metamaterial surface made at an oblique angle. We present an analytical theory that relates the reflectance of a single plane to the expected bulk permeability and permeability of the composite, as well as supporting experiments and numerical simulations. Our results show that the recent use of reflectance measurements to characterize planar split ring resonator samples can reveal the presence of circulating currents in a sample--the precursor to artificial magnetism--but are insufficient to provide quantitative results unless the symmetry of the underlying metamaterial elements is carefully specified.

Metamaterial electromagnetic cloak at microwave frequencies.

A recently published theory has suggested that a cloak of invisibility is in principle possible, at least over a narrow frequency band. We describe here the first practical realization of such a cloak; in our demonstration, a copper cylinder was "hidden" inside a cloak constructed according to the previous theoretical prescription. The cloak was constructed with the use of artificially structured metamaterials, designed for operation over a band of microwave frequencies. The cloak decreased scattering from the hidden object while at the same time reducing its shadow, so that the cloak and object combined began to resemble empty space.

Gradient index metamaterials.

Metamaterials--artificially structured materials with tailored electromagnetic response--can be designed to have properties difficult or impossible to achieve with traditional materials fabrication methods. Here we present a structured metamaterial, based on conducting split ring resonators (SRRs), which has an effective index of refraction with a constant spatial gradient. We experimentally confirm the gradient by measuring the deflection of a microwave beam by a planar slab of the composite metamaterial over a range of microwave frequencies. The gradient index metamaterial may prove an advantageous alternative approach to the development of gradient index lenses and similar optics, especially at higher frequencies. In particular, the gradient index metamaterial we propose may be suited for terahertz applications, where the magnetic resonant response of SRRs has recently been demonstrated.

Enhanced diffraction from a grating on the surface of a negative-index metamaterial.

We show by numerical simulation as well as by measurements on negative-index metamaterial wedge samples, that the unavoidable stepping of the refraction interface-due to the finite unit-cell size inherent to metamaterials-can give rise to a well-defined diffracted beam in addition to the negatively refracted beam. The direction of the diffracted beam is consistent with elementary diffraction theory; however, the coupling to this higher order beam is much larger than would be the case for a positive index material. The results confirm recent theoretical predictions of enhanced diffraction for negative-index grating surfaces.

Single-target molecule detection with nonbleaching multicolor optical immunolabels.

We introduce and demonstrate the use of colloidal silver plasmon-resonant particles (PRPs) as optical reporters in typical biological assays. PRPs are ultrabright, nanosized optical scatterers, which scatter light elastically and can be prepared with a scattering peak at any color in the visible spectrum. PRPs are readily observed individually with a microscope configured for dark-field microscopy, with white-light illumination of typical power. Here we illustrate the use of PRPs, surface coated with standard ligands, as target-specific labels in an in situ hybridization and an immunocytology assay. We propose that PRPs can replace or complement established labels, such as those based on radioactivity, fluorescence, chemiluminescence, or enzymatic/colorimetric detection that are used routinely in biochemistry, cell biology, and medical diagnostic applications. Moreover, because PRP labels are nonbleaching and bright enough to be rapidly identified and counted, an ultrasensitive assay format based on single-target molecule detection is now practical. We also present the results of a model sandwich immunoassay for goat anti-biotin antibody, in which the number of PRP labels counted in an image constitutes the measured signal.

Genetics of tassel branch number in maize and its implications for a selection program for small tassel size.

Tassel branch numbers of six crosses of maize (Zea mays L.) were analyzed to determine inheritance of this trait. Generation mean analyses were used to estimate genetic effects, and additive and nonadditive components of variance were calculated and evaluated for bias due to linkage. Both narrow-sense and broad-sense heritabilities were estimated. Additive genetic variance estimates were significant in five of the six crosses, whereas estimates of variance due to nonadditive components were significant in only three crosses. Additionally, estimates of additive variance components usually were larger than corresponding nonadditive components. There was no evidence for linkage bias in these estimates. Estimates of additive genetic effects were significant in four of six crosses, but significant dominance, additive × additive and additive × dominance effects also were detected. Additive, dominance, and epistatic gene action, therefore, all influenced the inheritance of tassel branch number, but additive gene action was most important. Both narrow-sense and broadsense heritability estimates were larger than those reported for other physiological traits of maize and corroborated conclusions concerning the importance of additive gene action inferred from analyses of genetic effects and variances. We concluded that selection for smalltasseled inbreds could be accomplished most easily through a mass-selection and/or pedigree-selection system. Production of a small-tasseled hybrid would require crossing of two small-tasseled inbreds. We proposed two genetic models to explain unexpected results obtained for two crosses. One model involved five interacting loci and the other employed two loci displaying only additive and additive × additive gene action.