Quantifying the groundwater total contamination risk using an inclusive multi-level modelling strategy.

This paper investigates aggregated risks in aquifers, where risk exposures may originate from different contaminants e.g. nitrate-N (NO3-N), arsenic (As), boron (B), fluoride (F), and aluminium (Al). The main goal is to develop a new concept for the total risk problem under sparse data as an efficient planning tool for management through the following methodology: (i) mapping aquifer vulnerability by DRASTIC and SPECTR frameworks; (ii) mapping risk indices to anthropogenic and geogenic contaminants by unsupervised methods; (iii) improving the anthropogenic and geogenic risks by a multi-level modelling strategy at three levels: Level 1 includes Artificial Neural Networks (ANN) and Support Vector Machines (SVM) models, Level 2 combines the outputs of Level 1 by unsupervised Entropy Model Averaging (EMA), and Level 3 integrates the risk maps of various contaminants (nitrate-N, arsenic, boron, fluoride, and aluminium) modelled at Level 2. The methodology offers new data layers to transform vulnerability indices into risk indices and thereby integrates risks by a heuristic scheme but without any learning as no measured values are available for the integrated risk. The results reveal that the risk indexing methodology is fit-for-purpose. According to the integrated risk map, there are hotspots at the study area and exposed to a number of contaminants (nitrate-N, arsenic, boron, fluoride, and aluminium).

Assessment of groundwater vulnerability using genetic algorithm and random forest methods (case study: Miandoab plain, NW of Iran).

One of the appropriate ways to prevent groundwater contamination is identifying the vulnerable areas of the aquifers. The DRASTIC framework, for assessing the intrinsic vulnerability of the aquifer, is a common method which uses a specific parameter's weight and a uniform distributed contaminant in overall the aquifer. Therefore, it should be calibrated for specific aquifer and contaminant distribution conditions. In this research, random forest (RF) and genetic algorithm (GA) methods were used for DRASTIC framework optimization in Miandoab plain (NW of Iran). In optimizing the basic DRASTIC framework (BDF) using GA, decision variables are the weight of DRASTIC parameters and weight values for each data layer are the outputs of the optimization. The final optimized map (BDF-GA map) was obtained using overlaying the layers with optimized weights based on the GA method. In optimization of BDF using RF, the model is made up of from 1 to 100 trees and the m parameter or split variables was optimized by changing the number of variables between one and the maximum variables of each subset. Also, the feature selection method is used to reduce the dimensions and increase the accuracy of the model. To induct the nitrate contaminant model, raster layer data of 7 BDF parameters, together with the target variable (VI of BDF map), were used. In the final step, variables' importance was identified by the RF method and then, the vulnerability map was obtained based on variable importance. In validation and comparison of methods with CI and ROC methods, the BDF-RF method with the higher CI and ROC values was ranked as the most accurate approach in groundwater vulnerability evaluation. The optimized map using the RF method (BDF-RF map) showed that 14.5, 13, 18, 26.5, and 28% of the plain are located in areas with very low, low, moderate, high, and very high vulnerability categories, respectively.

Mapping groundwater contamination risk of multiple aquifers using multi-model ensemble of machine learning algorithms.

Constructing accurate and reliable groundwater risk maps provide scientifically prudent and strategic measures for the protection and management of groundwater. The objectives of this paper are to design and validate machine learning based-risk maps using ensemble-based modelling with an integrative approach. We employ the extreme learning machines (ELM), multivariate regression splines (MARS), M5 Tree and support vector regression (SVR) applied in multiple aquifer systems (e.g. unconfined, semi-confined and confined) in the Marand plain, North West Iran, to encapsulate the merits of individual learning algorithms in a final committee-based ANN model. The DRASTIC Vulnerability Index (VI) ranged from 56.7 to 128.1, categorized with no risk, low and moderate vulnerability thresholds. The correlation coefficient (r) and Willmott's Index (d) between NO3 concentrations and VI were 0.64 and 0.314, respectively. To introduce improvements in the original DRASTIC method, the vulnerability indices were adjusted by NO3 concentrations, termed as the groundwater contamination risk (GCR). Seven DRASTIC parameters utilized as the model inputs and GCR values utilized as the outputs of individual machine learning models were served in the fully optimized committee-based ANN-predictive model. The correlation indicators demonstrated that the ELM and SVR models outperformed the MARS and M5 Tree models, by virtue of a larger d and r value. Subsequently, the r and d metrics for the ANN-committee based multi-model in the testing phase were 0.8889 and 0.7913, respectively; revealing the superiority of the integrated (or ensemble) machine learning models when compared with the original DRASTIC approach. The newly designed multi-model ensemble-based approach can be considered as a pragmatic step for mapping groundwater contamination risks of multiple aquifer systems with multi-model techniques, yielding the high accuracy of the ANN committee-based model.

Assessment of groundwater vulnerability using supervised committee to combine fuzzy logic models.

Vulnerability indices of an aquifer assessed by different fuzzy logic (FL) models often give rise to differing values with no theoretical or empirical basis to establish a validated baseline or to develop a comparison basis between the modeling results and baselines, if any. Therefore, this research presents a supervised committee fuzzy logic (SCFL) method, which uses artificial neural networks to overarch and combine a selection of FL models. The indices are expressed by the widely used DRASTIC framework, which include geological, hydrological, and hydrogeological parameters often subject to uncertainty. DRASTIC indices represent collectively intrinsic (or natural) vulnerability and give a sense of contaminants, such as nitrate-N, percolating to aquifers from the surface. The study area is an aquifer in Ardabil plain, the province of Ardabil, northwest Iran. Improvements on vulnerability indices are achieved by FL techniques, which comprise Sugeno fuzzy logic (SFL), Mamdani fuzzy logic (MFL), and Larsen fuzzy logic (LFL). As the correlation between estimated DRASTIC vulnerability index values and nitrate-N values is as low as 0.4, it is improved significantly by FL models (SFL, MFL, and LFL), which perform in similar ways but have differences. Their synergy is exploited by SCFL and uses the FL modeling results "conditioned" by nitrate-N values to raise their correlation to higher than 0.9.

Groundwater vulnerability indices conditioned by Supervised Intelligence Committee Machine (SICM).

This research presents a Supervised Intelligent Committee Machine (SICM) model to assess groundwater vulnerability indices of an aquifer. SICM uses Artificial Neural Networks (ANN) to overarch three Artificial Intelligence (AI) models: Support Vector Machine (SVM), Neuro-Fuzzy (NF) and Gene Expression Programming (GEP). Each model uses the DRASTIC index, the acronym of 7 geological, hydrological and hydrogeological parameters, which collectively represents intrinsic (or natural) vulnerability and gives a sense of contaminants, such as nitrate-N, penetrating aquifers from the surface. These models are trained to modify or condition their DRASTIC index values by measured nitrate-N concentration. The three AI-techniques often perform similarly but have differences as well and therefore SICM exploits the situation to improve the modeled values by producing a hybrid modeling results through selecting better performing SVM, NF and GEP components. The models of the study area at Ardabil aquifer show that the vulnerability indices by the DRASTIC framework produces sharp fronts but AI models smoothen the fronts and reflect a better correlation with observed nitrate values; SICM improves on the performances of three AI models and cope well with heterogeneity and uncertain parameters.