1.
Chem Commun (Camb)
; 56(22): 3345-3348, 2020 Mar 17.
Artigo
em Inglês
| MEDLINE
| ID: mdl-32090215
RESUMO
Herein, we disclose the utilisation of iodonium ylides to access a range of boron dienolates. Heating of acyclic iodonium ylides in the presence of different aryl boranes leads to the formation of rare 1,3-carboboration products. This methodology could not be expanded to cyclic iodonium ylides which instead formed a Lewis acid-base adduct. Products proved to be remarkably stable under a wide range of conditions allowing for their long term storage.