MnFe2O4-NH2-HKUST-1, MOF magnetic composite, as a novel sorbent for efficient dye removal: fabrication, characterization and isotherm studies.

Dye in industrial wastewater is one of the most serious environmental concerns due to its potentially harmful effects on human health. Many industrial dyes are carcinogenic, toxic and teratogenic. Removal and recovery of hazardous dyes from the effluents requires efficient adsorbents. In this study, magnetic adsorbent MnFe2O4-NH2-HKUST-1 was synthesized to remove methylene blue and crystal violet dyes from aqueous solutions. The synthesized adsorbent was characterized using FTIR, XRD, BET, VSM, SEM, TGA and Zeta potential techniques. The effect of different parameters such as pH, contact time, and adsorbent dosage on the removal of dyes was investigated. The dye adsorption process was investigated by UV-Vis spectrophotometry. The maximum adsorbent capacity was obtained as 149.25 mg/g for methylene blue and 135.13 mg/g for crystal violet. The adsorption equilibrium isotherm and kinetic models were plotted and results showed that the adsorption process for both dyes is a collection of physical and chemical adsorption based on langmuir and freundlich isotherm models, and follows the pseudo-second-order adsorption kinetics. This study shows that magnetic adsorbent MnFe2O4-NH2-HKUST-1 has a good potential for removal of methylene blue and crystal violet dyes from water in a short time (5 min) and it is easily separated from the solution by a magnetic field due to its magnetic property.

Novel probe based on rhodamine B and quinoline as a naked-eye colorimetric probe for dual detection of nickel and hypochlorite ions.

This work demonstrates the design and straightforward syntheses of several novel probe-based on rhodamine B and 2-mercaptoquinoline-3-carbaldehydes as a naked-eye colorimetric probe, indicating a sensitive and selective recognition towards nickel (II) with a limit of detection 0.30 µmol L-1 (0.02 mg L-1). Further, by employing the oxidation property of hypochlorite (OCl-), this novel probe parallelly has been deployed to detect hypochlorite in laboratory conditions with a limit of detection of 0.19 µmol mL-1 and in living cells. Regarded to negligible cell toxicity toward mammalian cells, this probe has the potential to determine these analytes in in-vivo investigation and foodstuff samples.

Enhanced removal of organic dyes from aqueous solutions by new magnetic HKUST-1: facile strategy for synthesis.

A novel, magnetic HKUST-1 MOF based on MgFe2O4-NH2 was designed and synthesized in two steps and applied effective removal of malachite green (MG), crystal violet (CV), and methylene blue (MB) from water samples. Characterization of the newly synthesized MgFe2O4-NH2-HKUST-1 was performed by various techniques such as Fourier transform infrared spectroscopy, X-ray diffraction, Field emission scanning electron microscopy, Brunauer-Emmett-Teller, Thermal gravimetric analysis, and Vibration sampling magnetometry. Malachite green, crystal violet and methylene blue are toxic and mutagenic dyes that can be released into the water in different ways and cause many problems for human health and the environment. The removal of malachite green, crystal violet, and methylene blue from aqueous solutions was investigated using the magnetic HKUST-1 in this research. The effect of various parameters such as pH, amount of sorbent, dye concentration, temperature, and contact time on dye removal has been studied. The results showed that more than 75% of dyes were removed within 5 min. Adsorption isotherms, Kinetic, and thermodynamic studies were investigated. The results of this study show that adsorption capacity of the magnetic adsorbent is equal to 108.69 mg g-1 for MG, 70.42 mg g-1 for CV, and 156.25 mg g-1 for MB. This study shows the good strategy for the synthesis of the functionalized magnetic form of HKUST-1 and its capability for increasing the efficiency of the removal process of malachite green, crystal violet, and methylene blue from an aqueous solution.

Ln Based Metal-organic Framework for Fluorescence "Turn Off-On" Sensing of Hg2.

A highly luminescent Ln-MOF [La3(NDC)4(DMF)3(H2O)4]n, (NDC = 2, 6 naphthalen dicarboxylic acid) was designed and synthesized. The structure was characterized by x-ray single structure determination, TGA, IR spectra and PXRD and fluorescence spectroscopy. The structure shows high fluorescence intensity based on the presence of lanthanide metal and ligand. In the presence of I-, the emission can be effectively quenched introducing turn off system. Furthermore, the synthesized Ln-MOF can recognize Hg (II) by showing fluorescence turn-on signal because of the high affinity between Hg (II) and I-. Moreover, the high selectivity and sensitivity of the synthesized Ln-MOF makes it quit qualified for determination of the low concentration of mercury (2.00 nM).

The synthesis and efficiency investigation of a boronic acid-modified magnetic chitosan quantum dot nanocomposite in the detection of Cu2+ ions.

We prepared the magnetic chitosan carbon quantum dot nanoparticles (Fe3O4@CQD NPs) via the hydrothermal treatment of chitosan biopolymer and then its magnetization with Fe3O4 nanoparticles. (4-Acetylphenyl)boronic acid compound was utilized for the modification of surface of Fe3O4@CQD nanoparticles via the covalent imine bond formation between NH2 groups of chitosan quantum dot with carbonyl functional of acetyl-substituted arylboronic acid. The synthesized Fe3O4@CQD@AP-B(OH)2 was characterized by FE-SEM, EDS, XRD, VSM and ICP-OES analysis and its fluorescence property was studied. This magnetic multifunctional nanoplatform sensor has shown high potential sensitivity for Cu2+ ions (in the range of 1.0-30.0 µM with limit of detection 0.3 µM) through interaction of cupric ions with the boronic-acid moiety.

Cascade process for direct synthesis of indeno[1,2-b]furans and indeno[1,2-b]pyrroles from diketene and ninhydrin.

Novel and efficient multicomponent reactions (MCRs) involving diketene, ninhydrin (indane-1,2,3-trione) and one primary amine (3CR) or two different primary amines (4CR) were achieved for the successful synthesis of dihydro-4H-indeno[1,2-b]furan-3-carboxamides or tetrahydroindeno[1,2-b]pyrrole-3-carboxamides, respectively. The merits of this method are highlighted by using either commercially available or easily accessible starting materials, operational simplicity, facile workup procedure, efficient usage of all the reactants, tolerance of a variety of functional groups and ability to conduct under un-catalyzed reaction condition. The products were also isolated by just decantation of the solvent, and for the purification column chromatography was non-required.

HKUST-1 metal-organic framework for dispersive solid phase extraction of 2-methyl-4-chlorophenoxyacetic acid (MCPA) prior to its determination by ion mobility spectrometry.

The authors describe a method for the extraction of the herbicide 2-methyl-4-chlorophenoxyacetic acid (MCPA) from agricultural products. The metal organic framework (MOF) HKUST-1 (a copper(II) benzene-1,3,5-tricarboxylate) was used as a sorbent for efficient clean-up and preconcentration of MCPA. The effects of pH value, stirring time, amount of sorbent on extraction were optimized by central composite design. Ultrasonic waves were used for desorption procedure and its advantage was demonstrated for an increase in extraction recovery. Corona discharge ion mobility spectrometry (IMS) was then applied for fast and sensitive determination of MCPA. The method was validated in terms of sensitivity, recovery and reproducibility. Under the optimum conditions the calibration plot is linear between 0.035-0.200 µg. L-1. The detection limit is 10 ng L-1, with relative standard deviations of <5%. Real samples (water, soil and agricultural product) were spiked and then analyzed by this method, and the results revealed efficient solid phase extraction and recovery. Graphical abstract Schematic presentation of a procedure for extraction of an organochlorine pesticide (2-methyl-4-chlorophenoxyacetic acid) from agriculture products using the HKUST-1 metal-organic framework prior to determination by ion mobility spectrometry based on its ionization in drift cell.

Sonochemical synthesis and characterization of a new nano Ce(III) coordination supramolecular compound; highly sensitive direct fluorescent sensor for Cu2.

Micro and nano-structures of a new Ce(III) Coordination supramolecular compound, [Ce (1,5-NDS)1.5(H2O)5]n,1, (1,5-Naphthalenedisulfonic acid), were prepared using hydrothermal and sonochemical approaches, respectively. These new micro and nano structures were characterized by elemental analysis, IR spectra, thermal gravimetric analysis (TGA), scanning electron microscopy (SEM), and powder X-ray diffraction. The X-ray single crystal structure determination of 1 shows that it features a neutral 2D framework based on the [Ce2H20O16S2] clusters as a secondary building unit (SBU) which shows a sql/Shubnikov tetragonal plane net. Moreover by considering the H-bonds, the final structure can be considered as 3D supramolecular network. The influence of ultrasound irradiation time on the morphology and size of the nanostructure 1 was investigated. The results indicated that by increasing the time of ultrasonic radiation, smaller nanostructures form and morphological changes occur. Fluorescent properties of the nanoparticles of 1 were also investigated. Coordination polymer 1 shows high fluorescence intensity and good tendency to copper ion that can be used as an optical sensor for selective and sensitive determination of Cu2+ in aqueous media with detection limit of 3.0µM.

Micelle mediated extraction and simultaneous spectrophotometric determination of vanadium(V) and molybdenum(VI) in plant foodstuff samples.

A micelle-mediated extraction method for preconcentration of trace quantities of V(V) and Mo(VI) as a prior step to their simultaneous spectrophotometric determination has been developed. Bromopyrogallol red, cetyltrimethylammonium bromide (CTAB) (cationic surfactant) and KI were used as chelating, extraction and co-extraction agents, respectively. Mean centering (MC) of ratio spectra has been used for the simultaneous analysis of these metal ions. The optimal reaction and extraction conditions were optimised and the analytical characteristics of the method (e.g., limit of detection, linear range, maximum preconcentration and improvement factor) were obtained. Linearity was obeyed in the range 3.0-50.0ngmL(-1) for V(V) and Mo(VI). The detection limit of the method was 0.5 and 1.0ngmL(-1) for V(V) and Mo(VI), respectively. The method was applied to the simultaneous determination of V(V) and Mo(VI) in several plant foodstuff samples successfully.

Second-order advantage applied to simultaneous spectrofluorimetric determination of paracetamol and mefenamic acid in urine samples.

Second-order advantage of excitation-emission fluorescence measurements was applied to the simultaneous determination of paracetamol (PC) and mefenamic acid (MF) in urine samples. Two drugs were quantified by multivariate curve resolution coupled to alternative least squares (MCR-ALS) in micellar media of sodium dodesyl sulfate (SDS). Experimental conditions including pH and SDS concentration were optimized. Under the optimum conditions, pH 2.0 and 0.05 mol L(-1) of SDS, paracetamol and mefenamic acid were determined in concentration range 4.00-20.00 microg mL(-1) and 0.80-5.00 microg mL(-1), respectively, in urine samples.

Simultaneous spectrofluorimetric determination of levodopa and propranolol in urine using feed-forward neural networks assisted by principal component analysis.

The simultaneous determination of levodopa (LD) and propranolol (PRO) using fluorescence spectrometric technique is described. The method involves measuring the natural fluorescence of these drugs in the micellar media of sodium dodecyl sulfate (SDS) using principal component analysis-feed-forward neural networks (PC-FFNNs). Experimental conditions such as effect of pH and SDS concentration were optimized. Under the optimum conditions, the linear determination ranges of LD and PRO are 2.0 x 10(-8) to 1.0 x 10(-5)mol L(-1) and 3.6 x 10(-9) to 1.8 x 10(-6)mol L(-1), respectively. A set of synthetic binary mixtures of LD and PRO was prepared and their concentrations were predicted by the proposed method. Satisfactory results were obtained by the combination of fluorescence technique with chemometrics methods. The method was successfully applied to the determination of LD and PRO in tap water and in urine samples.