Bioavailable fractions of heavy metals in the road dust during infrastructure construction at urban Coimbatore and its potential health implications, India.

Over the past two decades the Global South is witnessing unprecedented economic transformation and Asian Cities in particular have a remarkable upsurge. Coimbatore, an industrial city in Southern India with an estimated population of 2 million (in 2022) is witnessing a rapid transition in terms of infrastructure development. In this context, the present study attempts to assess the particulate matter (PM10 and PM2.5) emissions at road network construction sites and the heavy metal fractionation in the road dust/sediment samples with a core focus to quantify the bioavailable fraction of metals (Fe, Cu, Cr, Cd, Pb and Ni) and its source apportionment in the road side dust/sediment samples. About 60 composite road dust/sediment samples were collected for heavy metal fractionation analysis in the six arterial roads that undergo core developments like construction of road over bridges, additional road incorporation and street expansions. PM monitoring revealed that 24 h average PM2.5 (47 µg/m3) and PM10 (69 µg/m3) concentrations at many construction sites exceeded 24 h average recommended by WHO guidelines [PM2.5 (15 µg/m3) and PM10 (45 µg/m3), respectively]. The bioavailable fractions of Fe, Cu, Cr and Cd are notably higher in the roadside sediment samples at road construction sites. Health Risk assessment, such as carcinogenic risks (Children-4.41 × 10-2, Adult-3.598 × 10-6) and non-carcinogenic risks, inferred substantial risks at high intensity construction sites with statistical analyses, including PCA and cluster analysis, indicating considerable anthropogenic influences in the heavy metal fractions.

Turn-Off Fluorescence Sensor for the Detection of Ferric Ion in Water Using Green Synthesized Wrightia coccinea Carbon Quantum Dot.

The current study report that the production of carbon quantum dots from Wrightia coccinea (WC) leaves using an eco-friendly, one-pot process. The structural, morphological, and optical characteristics of the CDs made from W. coccinea leaves by hydrothermal treatment at 200 °C for six hours were assessed using a variety of spectroscopic and electron microscopy techniques. The average size of CD was found to be approximately 5 nm using transmission electron microscopy (TEM) and the quantum yield of the produced CD was 15.6%. The synthesized CDs demonstrated extraordinary sensing capacity with a detection limit of 0.511 µM for ferric ion detection. The impact of varying pH levels on the fluorescence behavior of CD was thoroughly investigated. The maximum fluorescence intensity was examined at pH 3. Therefore, to detect Fe3+ ions as best as possible, the pH of the entire solution was adjusted to a value of 3. Furthermore, the pH-dependent fluorescence feature of CDs can be exploited by pH-sensitive fluorescence sensors. In the future, this might provide an added advantage for pH-based fluorescence sensor applications.

Bioaccumulation of heavy metals in a gastropod species at the Kole wetland agroecosystem, a Ramsar site.

Heavy metal concentrations were evaluated in the Pila globosa tissues and the adjacent aquatic environment of the Kole wetland agroecosystem, a Ramsar site, southwest coast of India. Metal concentrations were analyzed to assess the spatial distribution, contamination levels, bioaccumulation potential, and potential risk to the human population and the migratory birds that forage the wetland agroecosystem. The recorded concentrations of heavy metals in P. globosa tissues and the aquatic environment followed the hierarchal order: Fe > Cu > Mn > Cr > Zn > Ni > Cd > Pb mg/kg and Fe > Zn > Ni > Cr > Mn > Pb > Cu > Cd mg/L, respectively. Elevated levels of heavy metals were recorded in the P. globosa tissues than the adjacent aquatic environment thus, highlighting their potential for bioaccumulation. The recorded concentrations of heavy metals in the P. globosa tissues exceeded the permissible limits for Fe, Cu, Mn, Ni, Cr and Cd at several sampling sites. However, in the aquatic environment, the concentrations of all heavy metals were within the permissible limits except for elemental Ni. Inter-elemental correlations between the P. globosa tissues and the aquatic environment recorded antagonistic associations that inhibit metal co-accumulations between the biotic and the abiotic environments. Source identification based on Principle Component Analysis revealed dynamic modes of variability for heavy metals, indicating agro-pesticides and fertilizers as the likely source of heavy metal contamination. Among heavy metals, greater bioaccumulation capacity was recorded for Cu, a moderate for Fe, and comparatively less bioaccumulation for Mn, Zn, Pb, Cr, and Ni. The health risk assessment based on the Target Hazard Quotient and Hazard Index revealed potential toxicity risk to the human population and the migratory birds including the transcontinental migrants that forage the Kole landscapes. Finally, the study emphasizes on long-term monitoring and surveillance programs to identify the multiple stressors most probably, the point sources of contamination and the diffuse sources along the Central Asian flyway for migratory birds to ensure protection of the threatened species and reduce the risk to the human population. Vulnerability to heavy metal toxicity shows that the Kole wetland agroecosystem, a Ramsar site for transcontinental migrants is likely at risk due to heavy metal bioaccumulation in gastropods, hence, requires urgent retrospection. The results of the study highlight that the biosorption potential of P. globosa, can be utilized for bioremediation of metal-contaminated wetlands and agroecosystems.

Monitoring of Neonicotinoid Pesticides in Water-Soil Systems Along the Agro-Landscapes of the Cauvery Delta Region, South India.

The prophylactic use of neonicotinoids in paddy fields has raised concern due to its toxicity to ecological systems and human health. The present study evaluated the concentrations of neonicotinoids such as clothianidin, imidacloprid, thiamethoxam, acetamiprid, and thiacloprid in the water-soil systems of the paddy fields, and their potential discharge into the groundwater along the Cauvery delta region, South India. Though neonicotinoids are extensively sprayed in the paddy fields, the concentration of residues analyzed by QuEChERS, combined with LC-MS/MS found no detectable residues at concentrations above LOD. The LOD and the LOQ values for water and soil were 0.001 ppm and 0.0025 ppm and 0.025 ppm and 0.05 ppm respectively. The results of the study found that neonicotinoids are less persistent in the water-soil systems of the delta region as they are readily exposed to photolysis and undergo rapid microbial degradation. Further, the hydropedological characteristics of the highly saturated delta soil facilitate ready leaching followed by vertical migration and infiltration into the soil aquifers.

Fine particulate phase PAHs in ambient atmosphere of Chennai metropolitan city, India.

BACKGROUND: Airborne fine particulates (PM 2.5) and its associated polycyclic aromatic hydrocarbons (PAHs) are reportedly hazardous in urban environment due to the presence of multiple emission sources. METHODS: In this study, fine particulates collected from fourth largest metropolitan city of India, Chennai, were extracted and analyzed for 11 PAHs by high-performance liquid chromatography equipped with a fluorescence detector. RESULTS: PM 2.5 values varied between 27.2 and 190.2 µg/m(3), while average concentration of particle-associated PAHs determined was in the range from 325.7 to 790.8 ng/m(3), which signaled an alarming pollution level in Chennai. CONCLUSIONS: Factor analysis suggested vehicular emissions inclusive of petrol- and diesel-driven engines as probable sources.

Water quality in select regions of Cauvery Delta River basin, southern India, with emphasis on monsoonal variation.

Delta regions of the Cauvery River basin are one of the significant areas of rice production in India. In spite of large-scale utilization of the river basin for irrigation and drinking purposes, the lack of appropriate water management has seemingly deteriorated the water quality due to increasing anthropogenic activities. To assess the extent of deterioration, physicochemical characteristics of surface water were analyzed monthly in select regions of Cauvery Delta River basin, India, during July 2007 to December 2007. Total dissolved solids, chemical oxygen demand, and phosphate recorded maximum levels of 1,638, 96, and 0.43 mg/l, respectively, exceeding the permissible levels at certain sampling stations. Monsoonal rains in Cauvery River basin and the subsequent increase in river flow rate influences certain parameters like dissolved solids, phosphate, and dissolved oxygen. Agricultural runoff from watershed, sewage, and industrial effluents are suspected as probable factors of water pollution.