Experimental determination of energy disposal in the dissociative electron recombinations of CS2(+) and HCS2(+).

Vibronic optical emissions from CS(A1pi --> X1sigma+) and CS(a3pi --> X1sigma+) transitions have been identified from dissociative recombination (DR) of CS2(+) and HCS2(+) plasmas. All of the spectra were taken in flowing afterglow plasmas using an optical monochromator in the UV-visible wavelength region of 180-800 nm. For the CS(A --> X) and CS(a --> X) emissions, the relative vibrational distributions have been calculated for v' < 5 and v' < 3 in both types of plasmas for the CS(A) and CS(a) states, respectively. Both recombining plasmas show a population inversion from the v' = 0 to v' = 1 level of the CS(A) state, similar to other observations of the CS(A) state populations, which were generated using two other energetic processes. The possibility of spectroscopic cascading is addressed, such that transitions from upper level electronic states into the CS(A) and CS(a) states would affect the relative vibrational distribution, and there is no spectroscopic evidence supporting the cascading effect. Additionally, excited-state transitions from neutral sulfur (S(5S(2)0 --> 3P(2)) and S(5S(2)0 --> 3P(1))) and the products of ion-molecule reactions (CS(B1sigma+ --> A1pi), CS(+)(B2sigma+ --> A2pi(i)), and CS2(+) (A2pi(u) --> X2pi(g))) have been observed and are discussed.

A remeasurement of the products for electron recombination of N2H+ using a new technique: no significant NH+N production.

A remeasurement of the product distribution from dissociative electron-ion recombination (DR) of N2H+ has been made using a new technique. The technique employs electron impact to ionize the neutral products prior to detection by a quadrupole mass analyzer. Two experimental approaches, both using pulsed gas techniques, isolate and quantify the DR products. In one approach, an electron-attaching gas is pulsed into a flowing afterglow to transiently quench DR. Results from this approach give an upper limit of 5% for the NH+N product channel. In the second approach, the reagent gas N2 is pulsed. The absolute percentages of products were monitored versus initial N2 concentration. Results from this approach also give an upper limit of 5% for NH+N production. This establishes that N2+H is the dominant channel, being at least between 95 and 100%, and that there is no significant NH production contrary to a recent storage ring measurement that yielded 64% NH+N and 36% N2+H. Possible reasons for this dramatic difference are discussed.