RESUMO
In this study, we investigated the influence of the gamma-irradiation dose and the addition of the cross-linking agent (triallyl isocyanurate (TAIC)) on the thermal, mechanical and tribological properties of plant-derived polyamide 1010 (PA1010). PA1010 and PA1010/TAIC were extruded using a twin screw extruder and injection molded. These specimens were then irradiated with gamma-ray in air with doses of 20 and 50 kGy. After gamma-irradiation, the specimens were heat-treated to remove the free radicals generated in the polymer. The combination of gamma-irradiation and the addition of TAIC significantly changed the crystal structures of PA1010. Glass transition temperature increased with the addition of TAIC and, in particular, with increasing gamma-irradiation dose. Moreover, PA1010/TAIC showed a rubbery plateau originating from cross-links by gamma-irradiation, which was observed in the temperature regions above the melting point in DMA measurements. Mechanical properties such as strength, modulus and hardness, and tribological properties such as frictional coefficient, specific wear rate and limiting pv (pressure p × velocity v) value of PA1010 improved with change in the internal microstructure with the gamma-irradiation and addition of TAIC.
RESUMO
In this study, we investigated the influence of epoxy resin treatment on the mechanical and tribological properties of hemp fiber (HF)-reinforced plant-derived polyamide 1010 (PA1010) biomass composites. HFs were surface-treated using four types of surface treatment methods: (a) alkaline treatment using sodium chlorite (NaClO2) solution, (b) surface treatment using epoxy resin (EP) solution after NaClO2 alkaline treatment, (c) surface treatment using an ureidosilane coupling agent after NaClO2 alkaline treatment (NaClO2 + A-1160), and (d) surface treatment using epoxy resin solution after the (c) surface treatment (NaClO2 + A-1160 + EP). The HF/PA1010 biomass composites were extruded using a twin-screw extruder and injection-molded. Their mechanical properties, such as tensile, bending, and dynamic mechanical properties, and tribological properties were evaluated by the ring-on-plate-type sliding wear test. The strength, modulus, specific wear rate, and limiting pv value of HF/PA1010 biomass composites improved with surface treatment using epoxy resin (NaClO2 + A-1160 + EP). In particular, the bending modulus of NaClO2 + A-1160 + EP improved by 48% more than that of NaClO2, and the specific wear rate of NaClO2 + A-1160 + EP was one-third that of NaClO2. This may be attributed to the change in the internal microstructure of the composites, such as the interfacial interaction between HF and PA1010 and fiber dispersion. As a result, the mode of friction and wear mechanism of these biomass composites also changed.
