Temperature effects on the viscosity and the wavelength-dependent refractive index of imidazolium-based ionic liquids with a phosphorus-containing anion.

A systematic study on the viscosity and refractive index of 1-alkyl-3-methylimidazolium based ionic liquids (alkyl = methyl, butyl and hexyl) combined with three phosphorus containing anions, i.e. dimethylphosphate, methyl methylphosphonate and methylphosphonate, is reported. Experimental measurements account for temperature effects, while the refractive index is determined at multiple wavelengths in the visible and near infrared region. Despite the structural similarity of these anions, significant differences in the physical properties of the resulting ILs are identified, along with the clear trend of viscosity increase - and refractive index decrease - with increasing alkyl chain length on the cation. Ab initio theoretical calculations are carried out to support and rationalise the observed behaviour.

High-harmonic-repetition-rate, 1 GHz femtosecond optical parametric oscillator pumped by a 76 MHz Ti:sapphire laser.

We demonstrate the generation of femtosecond pulses in a synchronously pumped optical parametric oscillator (SPOPO) at the harmonics of pump repetition rate using a SPOPO cavity longer than the fundamental synchronous length. The SPOPO is based on a 1 mm crystal of periodically poled LiNbO(3) and pumped by a Kerr-lens mode-locked Ti:sapphire laser at 76 MHz. By increasing the SPOPO synchronous cavity length we have generated output signal pulses at successive harmonics of the pump repetition rate up to the 13th harmonic at 988 MHz, where average signal powers of 30 mW are still available for 1.45 W of pump power. The generated signal pulses at 988 MHz are near transform limited with average durations of 227 fs and a time-bandwidth product of 0.41 for 185 fs input pump pulses.

Highly versatile confocal microscopy system based on a tunable femtosecond Er:fiber source.

The performance of a confocal microscopy setup based on a single femtosecond fiber system is explored over a broad range of pump wavelengths for both linear and nonlinear imaging techniques. First, the benefits of a laser source in linear fluorescence excitation that is continuously tunable over most of the visible spectrum are demonstrated. The influences of subpicosecond pulse durations on the bleaching behavior of typical fluorophores are discussed. We then utilize the tunable near-infrared output of the femtosecond system in connection with a specially designed prism compressor for dispersion control. Pulses as short as 33 fs are measured in the confocal region. As a consequence, 2 mW of average power are sufficient for two-photon microscopy in an organotypic sample from the mouse brain. This result shows great prospect for deep-tissue imaging in the optimum transparency window around 1100 nm. In a third experiment, we prove that our compact setup is powerful enough to exploit even higher-order nonlinearities such as three-photon absorption that we use to induce spatially localized photodamage in DNA.

Mid-infrared difference-frequency generation of ultrashort pulses tunable between 3.2 and 4.8 microm from a compact fiber source.

We report single-pass difference-frequency generation of mid-infrared femtosecond pulses tunable in the 3.2-4.8 microm range from a two-branch mode-locked erbium-doped fiber source. Average power levels of up to 1.1 mW at a repetition rate of 82 MHz are obtained in the mid infrared. This is achieved via nonlinear mixing of 170 mW, 65 fs pump pulses at a fixed wavelength of 1.58 microm, with 11.5 mW, 40 fs pulses tunable in the near-infrared range between 1.05 and 1.18 microm. These values indicate that the tunable near-infrared input component is downconverted with a quantum efficiency that exceeds 30%.

Multimilliwatt ultrashort pulses continuously tunable in the visible from a compact fiber source.

We report on a single-pass device that efficiently converts the broadband near-infrared output from a femtosecond fiber laser into a narrow spectrum in the visible. With fan-out poled MgO:LiNbO3 we obtain sub-picosecond, continuously tunable pulses in the 520-700 nm range. Conversion efficiencies as high as 30% are observed at typical pump power levels of 30 mW, corresponding to average output powers up to 9.5 mW. The specifications of our device are ideal for applications in confocal microscopy and frequency metrology.

Quasi-phase-matched second-harmonic generation in a GaAs/AlAs superlattice waveguide by ion-implantation-induced intermixing.

We report type I second-harmonic generation by use of first-order quasi-phase matching in a GaAs/AlAs symmetric superlattice structure with femtosecond fundamental pulses at 1.55 microm. Periodic spatial modulation of the bulklike second-order susceptibility chi(zxy)(2) was achieved with quantum-well intermixing for which the group III vacancies were created by As+-ion implantation. A narrow second-harmonic bandwidth of approximately 0.9 nm (FWHM) with an average power of approximately 1.5 microW was detected, corresponding to an internal conversion efficiency of approximately 0.06%, which was considerably limited by the spectral bandwidth of the fundamental.

Efficient second-harmonic generation in birefringently phase-matched GaAs/Al(2)O(3) waveguides.

We report efficient second-harmonic generation of femtosecond pulses in birefringently phase-matched GaAs/Al(2)O(3) waveguides pumped at 2.01mum. By use of pump pulses of ~200-fs duration and type I interaction, practical second-harmonic average powers of up to ~650muW were obtained, with an average input power of ~50muW. Waveguides of four different widths and two different lengths were investigated, and a normalized conversion efficiency of greater than 1000%W(-1)cm(-2) was obtained for a 1-mm waveguide. Measurements of pump and second-harmonic spectra provided clear evidence of phase matching and depletion of the pump spectrum. The measured bandwidth of the second harmonic was ~1.3nm. From the measurements of transmitted pump power at the phase-matching wavelength, pump depletions of more than 80% were recorded.

Quasi phase matching in GaAs--AlAs superlattice waveguides through bandgap tuning by use of quantum-well intermixing.

We report the observation of second-harmonic generation by type I quasi phase matching in a GaAs-AlAs superlattice waveguide. Quasi phase matching was achieved through modulation of the nonlinear coefficient chi((2))(zxy), which we realized by periodically tuning the superlattice bandgap. Second-harmonic generation was demonstrated for fundamental wavelengths from 1480 to 1520 nm, from the third-order gratings with periods from 10.5 to 12.4microm . The second-harmonic signal spectra demonstrated narrowing owing to the finite bandwidth of the quasi-phase-matching grating. An average power of ~110 nW was obtained for the second harmonic by use of an average launched pump power of ?2.3mW .