Magnetic metal-organic frameworks immobilized enzyme-based nano-biocatalytic systems for sustainable biotechnology.

Nanobiocatalysts, in which enzyme molecules are integrated into/onto multifunctional materials, such as metal-organic frameworks (MOFs), have been fascinating and appeared as a new interface of nanobiocatalysis with multi-oriented applications. Among various nano-support matrices, functionalized MOFs with magnetic attributes have gained supreme interest as versatile nano-biocatalytic systems for organic bio-transformations. From the design (fabrication) to deployment (application), magnetic MOFs have manifested notable efficacy in manipulating the enzyme microenvironment for robust biocatalysis and thus assure requisite applications in several areas of enzyme engineering at large and nano-biocatalytic transformations, in particular. Magnetic MOFs-linked enzyme-based nano-biocatalytic systems offer chemo-regio- and stereo-selectivities, specificities, and resistivities under fine-tuned enzyme microenvironments. Considering the current sustainable bioprocesses demands and green chemistry needs, we reviewed synthesis chemistry and application prospects of magnetic MOFs-immobilized enzyme-based nano-biocatalytic systems for exploitability in different industrial and biotechnological sectors. More specifically, following a thorough introductory background, the first half of the review discusses various approaches to effectively developed magnetic MOFs. The second half mainly focuses on MOFs-assisted biocatalytic transformation applications, including biodegradation of phenolic compounds, removal of endocrine disrupting compounds, dye decolorization, green biosynthesis of sweeteners, biodiesel production, detection of herbicides and screening of ligands and inhibitors.

Metal ferrites-based nanocomposites and nanohybrids for photocatalytic water treatment and electrocatalytic water splitting.

Photocatalytic degradation is one of the most promising technologies available for removing a variety of synthetic and organic pollutants from the environmental matrices because of its high catalytic activity, reduced energy consumption, and low total cost. Due to its acceptable bandgap, broad light-harvesting efficiency, significant renewability, and stability, Fe2O3 has emerged as a fascinating material for the degradation of organic contaminants as well as numerous dyes. This study thoroughly reviewed the efficiency of Fe2O3-based nanocomposite and nanomaterials for water remediation. Iron oxide structure and various synthetic methods are briefly discussed. Additionally, the electrocatalytic application of Fe2O3-based nanocomposites, including oxygen evolution reaction, oxygen reduction reaction, hydrogen evolution reaction, and overall water splitting efficiency, was also highlighted to illustrate the great promise of these composites. Finally, the ongoing issues and future prospects are directed to fully reveal the standards of Fe2O3-based catalysts. This review is intended to disseminate knowledge for further research on the possible applications of Fe2O3 as a photocatalyst and electrocatalyst.

Graphene-based nanocomposites and nanohybrids for the abatement of agro-industrial pollutants in aqueous environments.

Incessant release of a large spectrum of agro-industrial pollutants into environmental matrices remains a serious concern due to their potential health risks to humans and aquatic animals. Existing remediation techniques are unable to remove these pollutants, necessitating the development of novel treatment approaches. Due to its unique structure, physicochemical properties, and broad application potential, graphene has attracted a lot of attention as a new type of two-dimensional nanostructure. Given its chemical stability, large surface area, electron mobility, superior thermal conductivity, and two-dimensional structure, tremendous research has been conducted on graphene and its derived composites for environmental remediation and pollution mitigation. Various methods for graphene functionalization have facilitated the development of different graphene derivatives such as graphene oxide (GO), functional reduced graphene oxide (frGO), and reduced graphene oxide (rGO) with novel attributes for multiple applications. This review provides a comprehensive read on the recent progress of multifunctional graphene-based nanocomposites and nanohybrids as a promising way of removing emerging contaminants from aqueous environments. First, a succinct overview of the fundamental structure, fabrication techniques, and features of graphene-based composites is presented. Following that, graphene and GO functionalization, i.e., covalent bonding, non-covalent, and elemental doping, are discussed. Finally, the environmental potentials of a plethora of graphene-based hybrid nanocomposites for the abatement of organic and inorganic contaminants are thoroughly covered.